Stereoselective construction of all-carbon quaternary stereocenters by allylboration of chiral aldehydes: synthesis of a fragment of (+)-vibsanin A

No abstract is available for this paper.

• Publication year

  2016

• Venue

  Tetrahedron

• Publication date

  2016-09-01

• Fields of study

  Chemistry

• Identifiers
  DOI 10.1016/J.TET.2016.07.030
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• Synthetic Strategies toward Natural Products Containing Contiguous Stereogenic Quaternary Carbon Atoms.

  2016cited by this paper
• Enantioselective Organocatalytic Construction of Spiroindane Derivatives by Intramolecular Friedel-Crafts-Type 1,4-Addition.

  2016cited by this paper
• Natural Product Vibsanin A Induces Differentiation of Myeloid Leukemia Cells through PKC Activation.

  2016cited by this paper
• Synthesis of Adjacent Quaternary Stereocenters by Catalytic Asymmetric Allylboration.

  2015cited by this paper
• Total Synthesis of Hyperforin.

  2015cited by this paper
• Total synthesis of (+)-vibsanin A.

  2015cited by this paper
• Highly diastereoselective and enantiospecific allylation of ketones and imines using borinic esters: contiguous quaternary stereogenic centers.

  2014cited by this paper
• New acylphloroglucinol derivatives with diverse architectures from Hypericum henryi.

  2014cited by this paper
• Copper(I)-catalyzed enantioselective synthesis of α-chiral linear or carbocyclic (E)-(γ-alkoxyallyl)boronates.

  2014cited by this paper
• Total syntheses of hyperforin and papuaforins A-C, and formal synthesis of nemorosone through a gold(I)-catalyzed carbocyclization.

  2014cited by this paper
• Catalytic enantioselective synthesis of quaternary carbon stereocentres

  2014cited by this paper
• All-carbon quaternary stereogenic centers in acyclic systems through the creation of several C-C bonds per chemical step.

  2014cited by this paper
• Enantioselective total synthesis of hyperforin.

  2013cited by this paper
• The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total Synthesis.

  2013cited by this paper
• Diastereoselective allylation of carbonyl compounds and imines: application to the synthesis of natural products.

  2013cited by this paper
• Stereoselective total synthesis of (±)-hyperforin via intramolecular cyclopropanation

  2013cited by this paper
• Asymmetric Construction of All-Carbon Quaternary Stereocenters by Chiral-Auxiliary-Mediated Claisen Rearrangement and Total Synthesis of (+)-Bakuchiol

  2012cited by this paper
• Catalytic enantioselective 1,2-diboration of 1,3-dienes: versatile reagents for stereoselective allylation.

  2012cited by this paper
• Ni- and Pd-catalyzed synthesis of substituted and functionalized allylic boronates.

  2012cited by this paper
• Construction of All‐Carbon Quaternary Stereocenters by Zinc‐Mediated Barbier‐Type Allylation in Aqueous Media.

  2012cited by this paper
• Enantioselective synthesis of all-carbon quaternary stereogenic centers in acyclic systems.

  2011cited by this paper
• Enantioselective construction of all-carbon quaternary centers by branch-selective Pd-catalyzed allyl-allyl cross-coupling.

  2011cited by this paper
• Direct enantio-convergent transformation of racemic substrates without racemization or symmetrization

  2010cited by this paper
• Catalytic asymmetric total synthesis of ent-hyperforin.

  2010cited by this paper
• Metal-catalyzed asymmetric conjugate addition reaction: formation of quaternary stereocenters.

  2010cited by this paper
• CHEMITSRY AND BIOLOGICAL ACTIVITIES OF VIBSANE-TYPE DITERPENOIDS

  2010cited by this paper
• The first catalytic asymmetric total synthesis of ent-hyperforin

  2010cited by this paper
• Enantioselective Synthesis of a 3,5,5‐Trialkylated Tetronic Acid Derivative.

  2009cited by this paper
• Organocatalytic formation of quaternary stereocenters

  2009cited by this paper
• Enantioselective Catalytic Formation of Quaternary Stereogenic Centers

  2007cited by this paper
• A practical and enantiospecific conversion of d-galactose to a substituted α,β-unsaturated δ-lactone synthon

  2007cited by this paper
• Creation of quaternary stereocenters in carbonyl allylation reactions.

  2007cited by this paper
• Chiral phosphoramide-catalyzed enantioselective addition of allylic trichlorosilanes to aldehydes. Preparative studies with bidentate phosphorus-based amides.

  2006cited by this paper
• Catalytic Enantioselective Construction of All‐Carbon Quaternary Stereocenters

  2006cited by this paper
• Stereoselective Construction of Quaternary Stereocenters

  2005cited by this paper
• Stereoselective Formation of Quaternary Carbon Centers and Related Functions

  2003cited by this paper
• A new reaction manifold for the Barton radical intermediates: synthesis of N-heterocyclic furanosides and pyranosides via the formation of the C(1)-C(2) bond.

  2003cited by this paper
• Platinum-catalyzed tandem diboration/asymmetric allylboration: access to nonracemic functionalized 1,3-diols.

  2003cited by this paper
• Novel Isomerically Pure Tetrasubstituted Allylboronates: Stereocontrolled Synthesis of α-Exomethylene γ-Lactones as Aldol-Like Adducts with a Stereogenic Quaternary Carbon Center

  2002cited by this paper
• Asymmetric construction of quaternary centers by enantioselective allylation: application to the synthesis of the serotonin antagonist LY426965.

  2002cited by this paper
• Enantioselective Construction of Quaternary Stereocenters.

  2001cited by this paper
• Catalytic, enantioselective addition of substituted allylic trichlorosilanes using a rationally-designed 2,2'-bispyrrolidine-based bisphosphoramide.

  2001cited by this paper
• The Catalytic Enantioselective Construction of Molecules with Quaternary Carbon Stereocenters.

  1998cited by this paper
• Enantioselective Synthesis of Quaternary Carbon in Homoallylic Alcohols by the Reaction of Tartrate Ester Derivatives of 3,3-Disubstituted Allylborane with Aldehydes

  1996cited by this paper
• 4,6-O-benzylidene-D-glucopyranose and its sodium salt: new data on their preparation and properties.

  1995cited by this paper
• Stereoselective synthesis of alcohols, XLI. Chirality transfer to generate quaternary stereogenic centers by an allylboration reaction

  1991cited by this paper
• Synthese von erythro‐Sphingosinen über die Azidoderivate

  1988cited by this paper
• Stereochemistry of the reactions of substituted allylboronates with chiral aldehydes. Factors influencing aldehyde diastereofacial selectivity

  1986cited by this paper
• Oraganometallic Compounds for Stereoregulated Synthesis of Acyclic Systems. Their Application to the Synthesis of the Prelog-Djerassi Lactonic Acid

  1982cited by this paper
• Diastereogenic Addition of Crotylmetal Compounds to Aldehydes

  1982cited by this paper
• Total synthesis of (R)-glycerol acetonide and the antiepileptic and hypotensive drug (-)-gamma-amino-beta-hydroxybutyric acid (GABOB): use of vitamin C as a chiral starting material

  1980cited by this paper
• The structure of hyperforin

  1975cited by this paper
• Sulfuranes. VI. Reactions involving the alkoxy ligands of dialkoxydiarylsulfuranes. Formation of olefins and ethers

  1972cited by this paper
• [Antibiotic hyperforin from Hypericum perforatum L].

  1971cited by this paper
• Reaction of Ammonia with Some Acetylated and Benzoylated Monosaccharides. IX. The Migration of Benzoyl Groups in the Ammonolysis of 1,2,3,4,6-Penta-O-benzoyl-D-galactoses1

  1964cited by this paper

• Highly Diastereodivergent Green Synthesis of Cyclohexanones via Double Michael Addition of Malononitrile to Dibenzalacetone

  2025cites this paper
• Discovery of the Caged-Vibsane Norditerpenoids with Unprecedented Chemical Architectures and Exploration of Their Various Acid Tolerances.

  2023cites this paper
• Stereoselective Synthesis of the Tricyclic Core of (-)-Callophycoic Acid A.

  2020cites this paper
• Total Synthesis of Natural Products Using Intramolecular Nozaki–Hiyama–Takai–Kishi Reactions

  2020cites this paper