Application of Terminalia arjuna as potential adsorbent for the removal of Pb(II) from aqueous solution: thermodynamics, kinetics and process design

AbstractThe present work explored the adsorption properties of Terminalia arjuna fruit powder for the removal of Pb(II) from aqueous solution. Effect of concentration, contact time, pH, adsorbent dose, and temperature were studied using batch process to optimize conditions for maximum adsorption of Pb(II). Kinetic data showed that the pseudo-second-order model was the best fit for the experimental data over a wide range of concentrations. Thermodynamic parameters (∆H° and ∆G°) suggested endothermic and spontaneous nature of adsorption. Mean free energies at different temperatures were in between 10.1 and 14.3 kJ mol−1 indicating chemical nature of adsorption process. Equilibrium isotherm data were analyzed using Langmuir, Freundlich, Temkin and Dubinin–Radushkevich (D–R) isotherms models at 30, 40, and 50°C. The breakthrough and exhaustive capacities were found to be 5 and 15 mg g−1, respectively. Desorption studies were carried out by column method and 84% of Pb(II) ions were recovered when 0.05 N HCl wa...

• Publication year

  2016

• Venue

  Desalination and Water Treatment

• Publication date

  2016-08-14

• Fields of study

  Chemistry, Environmental Science

• Identifiers
  DOI 10.1080/19443994.2015.1087878
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

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