The structure and in situ synthesis investigation of isomorphic mononuclear molecular metal phenylphosphonates.

We describe a fast and effective synthesis for molecular metal phosphonates. Isomorphic compounds [M(ii)(HO3PPh)2(H2O3PPh)2(H2O)2] (M = Mn (1), Co (2), Ni (3); Ph = C6H5) were obtained by grinding. The complexes are mononuclear compounds containing neutral and monodeprotonated phenylphosphonic acid and water as ligands. The crystal structures were determined using powder X-ray diffraction (PXRD) data and validated by extended X-ray absorption fine structure (EXAFS) data. Combined synchrotron XRD measurements and Raman spectroscopy were conducted for investigating the reactions in situ. Based on these data, the intermediates were characterized and the formation mechanism was derived.

• Publication year

  2016

• Venue

  Dalton Transactions

• Publication date

  2016-06-07

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1039/c6dt00787bPMID 27188480
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

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