Reaction Medium as the Installing Reservoir for Key Functionalities in the Molecules

No abstract is available for this paper.

• Publication year

  2019

• Venue

  Asian Journal of Organic Chemistry

• Publication date

  2019-06-01

• Fields of study

  Chemistry

• Identifiers
  DOI 10.1002/AJOC.201900223
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• Acetonitrile as a Building Block and Reactant

  2018cited by this paper
• Cesium carbonate promoted cascade reaction involving DMF as a reactant for the synthesis of dihydropyrrolizino[3,2-b]indol-10-ones

  2018cited by this paper
• Iron(II)-catalyzed C-2 cyanomethylation of indoles and pyrroles via direct oxidative cross-dehydrogenative coupling with acetonitrile derivatives

  2018cited by this paper
• Dimethyl Sulfoxide Serves as a Dual Synthon: Construction of 5‐Methyl Pyrimidine Derivatives via Four Component Oxidative Annulation

  2018cited by this paper
• Visible-Light-Promoted Tandem Annulation of N-(o-Ethynylaryl)acrylamides with CH2Cl2.

  2018cited by this paper
• Transition Metal-Free Cross-Dehydrogenative Coupling Reaction of Coumarins with Acetonitrile or Acetone.

  2018cited by this paper
• Non-toxic cyanide sources and cyanating agents.

  2018cited by this paper
• A reusable cyanide sensor via activation of C-H group: trifluoromethylcarbinol-directed meta-C-H cyanomethylation of naphthalimide.

  2018cited by this paper
• Chloroform as a carbon monoxide source in palladium-catalyzed synthesis of 2-amidoimidazo[1,2-a]pyridines.

  2018cited by this paper
• Direct Synthesis of Quinolines via Co(III)-Catalyzed and DMSO-Involved C-H Activation/Cyclization of Anilines with Alkynes.

  2018cited by this paper
• Copper-catalyzed synthesis of α-amino nitriles through methyl transfer from DMF to aromatic amines.

  2018cited by this paper
• DMSO as a Switchable Alkylating Agent in Heteroarene C-H Functionalization.

  2018cited by this paper
• Beyond a solvent: triple roles of dimethylformamide in organic chemistry

  2018cited by this paper
• Silver-Mediated Cyanomethylation of Cinnamamides by Direct C(sp3)-H Functionalization of Acetonitrile.

  2018cited by this paper
• Electrochemical synthesis of methyl sulfoxides from thiophenols/thiols and dimethyl sulfoxide

  2018cited by this paper
• Nickel and Copper‐Catalyzed Carbonylation Reaction of Organoboranes

  2018cited by this paper
• Photoinduced N‐Methylation and N‐Sulfonylation of Azobenzenes with DMSO Under Mild Reaction Conditions

  2018cited by this paper
• Copper-Mediated Cyanation of Aryl C-H Bond with Removable Bidenate Auxiliary Using Acetonitrile as the Cyano Source

  2018cited by this paper
• Pd/C-Catalyzed Domino Synthesis of Urea Derivatives Using Chloroform as the Carbon Monoxide Source in Water

  2018cited by this paper
• Ni‐Catalyzed Synthesis of Methylenebisamides: Dual Role of DMSO Both as Methylene Source and Oxidant

  2017cited by this paper
• Carbon annulation of ortho-vinylanilines with dimethyl sulfoxide to access 4-aryl quinolines.

  2017cited by this paper
• Visible-light-induced and iron-catalyzed methylation of N-arylacrylamides with dimethyl sulphoxide: a convenient access to 3-ethyl-3-methyl oxindoles.

  2017cited by this paper
• Transition metal-free C(sp3)-H bond coupling among three methyl groups.

  2017cited by this paper
• Acid Promoted Direct Cross-Coupling of Methyl Ketones with Dimethyl Sulfoxide: Access to Ketoallyl Methylsulfides and -sulfones.

  2017cited by this paper
• Copper-Catalyzed Cyclization for Access to 6H-Chromeno[4,3-b]quinolin-6-ones Employing DMF as the Carbon Source.

  2017cited by this paper
• Palladium Catalyzed Carbonylative Coupling for Synthesis of Arylketones and Arylesters Using Chloroform as the Carbon Monoxide Source.

  2017cited by this paper
• Dimethyl Sulfoxide Involved One-Pot Synthesis of Quinoxaline Derivatives.

  2017cited by this paper
• Oxidative Annulations Involving DMSO and Formamide: K2S2O8 Mediated Syntheses of Quinolines and Pyrimidines.

  2017cited by this paper
• Copper-Catalyzed Oxidative Cross-Dehydrogenative Coupling/Oxidative Cycloaddition: Synthesis of 4-Acyl-1,2,3-Triazoles.

  2017cited by this paper
• Direct cyanomethylation of aliphatic and aromatic hydrocarbons with acetonitrile over a metal loaded titanium oxide photocatalyst

  2017cited by this paper
• Palladium catalyzed aroylation of NH-sulfoximines with aryl halides using chloroform as the CO precursor

  2017cited by this paper
• Selective and Efficient Formylation of Indoles (C3) and Pyrroles (C2) Using 2,4,6‐Trichloro‐1,3,5‐Triazine/Dimethylformamide (TCT/DMF) Mixed Reagent

  2017cited by this paper
• A Four-Component Reaction Strategy for Pyrimidine Carboxamide Synthesis.

  2017cited by this paper
• A Method to Access Symmetrical Tetrasubstituted Pyridines via Iodine and Ammonium Persulfate Mediated [2+2+1+1]‐Cycloaddition Reaction

  2017cited by this paper
• N‐Heterocyclic Carbene‐Catalyzed Mannich Reaction for the Synthesis of β‐Amino Ketones: N,N‐Dimethylformamide as Carbon Source

  2017cited by this paper
• Application of DMSO in the Synthesis of 1,4‐Disubstituted (But‐1‐en‐3‐ynyl)methylthioethers

  2017cited by this paper
• Synthesis of Quinazolinones, Imidazo[1,2‐c]quinazolines and Imidazo[4,5‐c]quinolines through Tandem Reductive Amination of Aryl Halides and Oxidative Amination of C(sp3)–H Bonds

  2017cited by this paper
• Metal‐Free, TBHP‐Mediated, [3+2+1]‐Type Intermolecular Cycloaddition Reaction: Synthesis of Pyrimidines from Amidines, Ketones, and DMF through C(sp3)−H Activation

  2017cited by this paper
• Transition‐Metal‐Free Oxidative Cross‐Coupling of Methylhetarenes with Imidazoheterocycles towards Efficient C(sp2)−H Carbonylation

  2017cited by this paper
• Recent Advances in the Synthesis of Aryl Nitrile Compounds

  2017cited by this paper
• Copper(I)-catalyzed alkyl- and arylsulfenylation of 3,4-dihalo-2(5H)-furanones (X=Br, Cl) with sulfoxides under mild conditions

  2017cited by this paper
• Acid-promoted oxidative methylenation of 1,3-dicarbonyl compounds with DMSO: application to the three-component synthesis of Hantzsch-type pyridines

  2017cited by this paper
• Metal‐Free Activation of DMF by Dioxygen: A Cascade Multiple‐Bond‐Formation Reaction to Synthesize 3‐Acylindoles from 2‐Alkenylanilines

  2017cited by this paper
• One-pot synthesis of benzimidazole using DMF as a multitasking reagent in presence CuFe 2 O 4 as catalyst

  2017cited by this paper
• Palladium-catalyzed aminocarbonylation of halo-substituted 7-azaindoles and other heteroarenes using chloroform as a carbon monoxide source.

  2017cited by this paper
• Iron-Catalyzed Dehydrogenative sp3-sp2 Coupling via Direct Oxidative C-H Activation of Acetonitrile.

  2017cited by this paper
• Palladium-catalyzed ligand-promoted site-selective cyanomethylation of unactivated C(sp3)–H bonds with acetonitrile† †Electronic supplementary information (ESI) available: Experimental details including characterization data, copies of 1H, 13C NMR and NOESY spectra. See DOI: 10.1039/c5sc04066c

  2016cited by this paper
• Vanadyl Acetylacetonate Catalyzed Methylenation of Imidazo[1,2-a]pyridines by Using Dimethylacetamide as a Methylene Source: Direct Access to Bis(imidazo[1,2-a]pyridin-3-yl)methanes

  2016cited by this paper
• H2O2/DMSO-Promoted Regioselective Synthesis of 3,3'-Bisimidazopyridinylmethanes via Intermolecular Oxidative C(sp(2))-H Bond Activation of Imidazoheterocycles.

  2016cited by this paper
• The Applications of Dimethyl Sulfoxide as Reagent in Organic Synthesis

  2016cited by this paper
• Catalyst-Free Three-Component Tandem CDC Cyclization: Convenient Access to Isoindolinones from Aromatic Acid, Amides, and DMSO by a Pummerer-Type Rearrangement.

  2016cited by this paper
• Aerobic iron(III)-catalyzed direct formylation of imidazo[1,2-a]pyridine using DMSO as carbon source

  2016cited by this paper
• One‐Pot Synthesis of Hantzsch Pyridines via NH4I Promoted Condensation of 1,3‐Dicarbonyl Compounds with DMSO and NH4OAc

  2016cited by this paper
• Visible light catalyzed methylsulfoxidation of (het)aryl diazonium salts using DMSO.

  2016cited by this paper
• N,N-Dimethylacetamide (DMA) as a Methylene Synthon for Regioselective Linkage of Imidazo[1,2-a]pyridine

  2016cited by this paper
• Advances in C–CN Bond Formation via C–H Bond Activation

  2016cited by this paper
• Metal-free synthesis of 3-methylthiofurans from homopropargylic alcohols and DMSO via a tandem sulfenylation/cyclization reaction in a one-pot manner

  2016cited by this paper
• Iron-catalyzed carbonylation of aryl halides with arylborons using stoichiometric chloroform as the carbon monoxide source

  2016cited by this paper
• N,N‐Dimethylformamide as a Methylenating Reagent: Synthesis of Heterodiarylmethanes via Copper‐Catalyzed Coupling between Imidazo[1,2‐a]pyridines and Indoles/N,N‐Dimethylaniline

  2016cited by this paper
• An Efficient Synthesis of Polysubstituted Pyridines via C sp 3H Oxidation and CS Cleavage of Dimethyl Sulfoxide

  2016cited by this paper
• Dimethyl Sulfoxide as a Synthon in Organic Chemistry

  2016cited by this paper
• A facile and efficient method for the synthesis of alkynone by carbonylative Sonogashira coupling using CHCl3 as the CO source

  2016cited by this paper
• Copper-catalysed cyanoalkylative cycloetherification of alkenes to 1,3-dihydroisobenzofurans: development and application to the synthesis of citalopram.

  2016cited by this paper
• Synthesis of symmetrical methylene-bridged imidazoheterocycles using DMSO as methylene source under metal-free conditions.

  2016cited by this paper
• CO/O2 assisted oxidative carbon–carbon and carbon–heteroatom bond cleavage for the synthesis of oxosulfonates from DMSO and olefins† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc04480h Click here for additional data file.

  2016cited by this paper
• Cyanomethylation and Cyclization of Aryl Alkynoates with Acetonitrile under Transition-Metal-Free Conditions: Synthesis of 3-Cyanomethylated Coumarins.

  2016cited by this paper
• Copper-Catalyzed N-Arylation of Azoles and Mannich-Type Coupling of Ketones and Azoles under Metal-Free Conditions.

  2016cited by this paper
• Radical trideuteromethylation with deuterated dimethyl sulfoxide in the synthesis of heterocycles and labelled building blocks.

  2016cited by this paper
• Method for Direct Synthesis of α-Cyanomethyl-β-dicarbonyl Compounds with Acetonitrile and 1,3-Dicarbonyls.

  2016cited by this paper
• Regioselective Copper-Catalyzed Dicarbonylation of Imidazo[1,2-a]pyridines with N,N-Disubstituted Acetamide or Acetone: An Approach to 1,2-Diketones Using Molecular Oxygen.

  2015cited by this paper
• Syntheses and Structures of [CH2(NCnH2n)2]Mo(CO)4 (n = 4,5) Complexes with Bis(cycloamine) Ligands Easily Prepared from CH2Cl2

  2015cited by this paper
• C–H Bond Cleavage of Acetonitrile by Iridium Complexes Bearing PNP-Pincer-Type Phosphaalkene Ligands

  2015cited by this paper
• Cu-Catalyzed Cyanation of Arylboronic Acids with Acetonitrile: A Dual Role of TEMPO.

  2015cited by this paper
• Pd-catalyzed Heck cyclization and in situ hydrocarboxylation or hydromethenylation via a hydrogen borrowing strategy

  2015cited by this paper
• Direct Aerobic Carbonylation of C(sp²)-H and C(sp³)-H Bonds through Ni/Cu Synergistic Catalysis with DMF as the Carbonyl Source.

  2015cited by this paper
• Connecting Neutral and Cationic Pathways in Nickel-Catalyzed Insertion of Benzaldehyde into a C-H Bond of Acetonitrile

  2015cited by this paper
• Cascade arylalkylation of activated alkenes: synthesis of chloro- and cyano-containing oxindoles.

  2015cited by this paper
• Acetonitrile as a cyanating reagent: Cu-catalyzed cyanation of arenes.

  2015cited by this paper
• Cu-Catalyzed Cyanation of Indoles with Acetonitrile as a Cyano Source.

  2015cited by this paper
• Chloroform as a Carbon Monoxide Precursor: In or Ex Situ Generation of CO for Pd-Catalyzed Aminocarbonylations.

  2015cited by this paper
• Palladium‐Catalyzed Aminocarbonylation Reaction to Access 1,3,4‐Oxadiazoles using Chloroform as the Carbon Monoxide Source

  2015cited by this paper
• A novel straightforward synthesis of 2,4-disubstituted-1,3,5-triazines via aerobic copper-catalyzed cyclization of amidines with DMF.

  2014cited by this paper
• Copper-catalyzed aerobic oxidative coupling of aromatic alcohols and acetonitrile to β-ketonitriles.

  2014cited by this paper
• DMF as carbon source: Rh-catalyzed α-methylation of ketones.

  2014cited by this paper
• CH2Cl2 as reagent in the synthesis of methylene-bridged 3,3′-bis(oxazolidin-2-one) derivatives under ambient conditions

  2014cited by this paper
• Copper-catalysed oxidative Csp(3)-H methylenation to terminal olefins using DMF.

  2014cited by this paper
• Copper-catalyzed α-methylenation of benzylpyridines using dimethylacetamide as one-carbon source.

  2014cited by this paper
• Visible-light-induced photocatalytic formyloxylation reactions of 3-bromooxindoles with water and DMF: the scope and mechanism

  2014cited by this paper
• Copper-catalysed oxidative C-H/N-H cross-coupling between formamides and amides through chelation-assisted N-H activation.

  2013cited by this paper
• Copper-catalyzed aromatic C-H bond cyanation by C-CN bond cleavage of inert acetonitrile.

  2013cited by this paper
• Copper-mediated direct C2-cyanation of indoles using acetonitrile as the cyanide source.

  2013cited by this paper
• Synthesis of esters from aldehydes or carboxylic acids with dichloromethane, dichloroethane or dichloropropane under mild conditions

  2013cited by this paper
• N,N-dimethylformamide: a multipurpose building block.

  2012cited by this paper
• Reaction of dichloromethane with pyridine derivatives under ambient conditions.

  2010cited by this paper

• Blueshift of the CN stretching vibration of acetonitrile in solution: computational and experimental study

  2024cites this paper
• Catalytic Methylene Insertion between Amines and Terminal Alkynes via C-N Bond Cleavage of N,N-Dimethylacetamide: A Unique Route to Propargylic Amines.

  2023cites this paper
• Advances in the Application of Acetonitrile in Organic Synthesis since 2018

  2023cites this paper
• Catalytic Direct Cyanomethylenation of C(sp3)-H Bonds via a One-Step Double C-C Bond Formation.

  2022cites this paper
• Oxone-DMSO Triggered Methylene Insertion and C(sp2)-C(sp3)-H-C(sp2) Bond Formation to Access Functional Bis-Heterocycles.

  2020cites this paper
• Transition metal-free synthesis of quinazolinones using dimethyl sulfoxide as a synthon.

  2019cites this paper