Skeletal reorganization of enynes catalyzed by InCl3.

[reaction: see text] The skeletal reorganization of enynes is achieved by the presence of InCl(3) as the catalyst. The reaction of enynes having a terminal acetylenic moiety proceeds in a stereospecific manner to give 1-vinylcycloalkenes. The reaction of enynes containing an alkyl group on the acetylenic terminal carbon resulted in a new type of skeletal reorganization to give 1-allylcycloalkenes, formation of which involves a double cleavage of the C-C double bond and the triple bond.

• Publication year

  2006

• Venue

  Organic Letters

• Publication date

  2006-04-22

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1021/OL060606DPMID 16671805
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

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