Chemical grafting of nano-SiO2 onto graphene oxide via thiol-ene click chemistry and its effect on the interfacial and mechanical properties of GO/epoxy composites

Abstract A facile and rapid come close to the manufacture of advanced epoxy nanocomposites by grafting of nano-silicon dioxide (nano-SiO2) onto the graphene oxide (GO) through thiol-ene click reaction was reported. The correlations between surface modification, morphology, dispersion/exfoliation, interfacial interaction of sheets and the corresponding mechanical properties of the composites were methodically explored. It appeared that nano-SiO2 have been grafted onto GO via covalent bonding successfully, which effectively improved the interface compatibility and dispersion in epoxy matrix. The reinforcing mechanisms has been also elaborated. It is demonstrated that the tensile strength and elastic modulus for filler with 0.1 wt% GO-SiO2/epoxy composites increased by 32.18% and 22.86% compared to neat epoxy, respectively. It is believed that the simplistic and effectual method may provide a novel and promising strengthen design strategy for next‐generation advanced nanocomposite structures.

• Publication year

  2019

• Venue

  Composites Science And Technology

• Publication date

  2019-09-29

• Fields of study

  Materials Science, Chemistry

• Identifiers
  DOI 10.1016/J.COMPSCITECH.2019.107751
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• Functionalized graphene as an effective antioxidant in natural rubber

  2018cited by this paper
• Modification of graphene with silica nanoparticles for use in hybrid network formation from epoxy, novolac, and epoxidized novolac resins by sol-gel method: Investigation of thermal properties

  2018cited by this paper
• Interfacial enhancement of carbon fiber composites by growing TiO2 nanowires onto amine-based functionalized carbon fiber surface in supercritical water

  2018cited by this paper
• Covalent grafting of triazine derivatives onto graphene oxide for preparation of epoxy composites with improved interfacial and mechanical properties

  2018cited by this paper
• Surface modification of carbon fibre using graphene–related materials for multifunctional composites

  2018cited by this paper
• Interface engineering for the improvement of mechanical and thermal properties of covalent functionalized graphene/epoxy composites

  2018cited by this paper
• Silica Nanostructures, a Heterogeneous Surface for Dendrimer Functionalization

  2018cited by this paper
• Mechanical and fracture properties of hyperbranched polymer covalent functionalized multiwalled carbon nanotube-reinforced epoxy composites

  2018cited by this paper
• Grafting of silica nanoparticles at the surface of graphene for application in novolac-type phenolic resin hybrid composites

  2018cited by this paper
• Enhanced hydrogen gas barrier performance of diaminoalkane functionalized stitched graphene oxide/polyurethane composites

  2017cited by this paper
• A novel fabrication of a high performance SiO(2)-graphene oxide (GO) nanohybrids: Characterization of thermal properties of epoxy nanocomposites filled with SiO(2)-GO nanohybrids.

  2017cited by this paper
• Grafting poly (amidoamine) dendrimer-modified silica nanoparticles to graphene oxide for preparation of a composite and curing agent for epoxy resin

  2017cited by this paper
• Reversible addition fragmentation chain transfer polymerization of styrene from the edge of graphene oxide nanolayers

  2017cited by this paper
• Thermal and mechanical properties of polypropylene nanocomposites reinforced with nano-SiO2 functionalized graphene oxide

  2017cited by this paper
• Enhanced mechanical and thermal properties of SBR composites by introducing graphene oxide nanosheets decorated with silica particles

  2017cited by this paper
• Preparation and properties of acrylic resin coating modified by functional graphene oxide

  2016cited by this paper
• Wrinkled, rippled and crumpled graphene: an overview of formation mechanism, electronic properties, and applications

  2016cited by this paper
• Fabrication of silica-decorated graphene oxide nanohybrids and the properties of composite epoxy coatings research

  2016cited by this paper
• Effect of Dodecyal Amine Functionalized Graphene on the Mechanical and Thermal Properties of Epoxy‐Based Composites

  2016cited by this paper
• Silicon dioxide@graphene oxide- graft -poly(γ-benzyl- l -glutamate) as an advanced hybrid nanofiller reinforces poly( l -lactide)

  2016cited by this paper
• Monothiolation and Reduction of Graphene Oxide via One-Pot Synthesis: Hybrid Catalyst for Oxygen Reduction.

  2015cited by this paper
• Fabrication of robust superhydrophobic surfaces by modification of chemically roughened fibers via thiol–ene click chemistry

  2015cited by this paper
• Effect of molecular chain length on the properties of amine-functionalized graphene oxide nanosheets/epoxy resins nanocomposites

  2015cited by this paper
• Characterization of covalently-grafted polyisocyanate chains onto graphene oxide for polyurethane composites with improved mechanical properties

  2015cited by this paper
• Interfacial interaction between the epoxidized natural rubber and silica in natural rubber/silica composites

  2015cited by this paper
• Room-temperature cured hydrophobic epoxy/graphene composites as corrosion inhibitor for cold-rolled steel

  2014cited by this paper
• Development of novel SiO2–GO nanohybrid/polysulfone membrane with enhanced performance

  2014cited by this paper
• Effects of surface-modified silica nanoparticles attached graphene oxide using isocyanate-terminated flexible polymer chains on the mechanical properties of epoxy composites

  2014cited by this paper
• Nanofilled Epoxy Adhesive for Structural Aeronautic Materials

  2014cited by this paper
• Enhanced mechanical properties of silanized silica nanoparticle attached graphene oxide/epoxy composites

  2013cited by this paper
• Improved dispersion and interface in the graphene/epoxy composites via a facile surfactant-assisted process

  2013cited by this paper
• An investigation of the mechanism of graphene toughening epoxy

  2013cited by this paper
• Graphene materials with different structures prepared from the same graphite by the Hummers and Brodie methods

  2013cited by this paper
• Mechanical and Thermal Properties of Epoxy Resin Nanocomposites Reinforced with Graphene Oxide

  2012cited by this paper
• The Fabrication, Properties, and Uses of Graphene/Polymer Composites

  2012cited by this paper
• Reinforcement and interphase of polymer/graphene oxide nanocomposites

  2012cited by this paper
• On fracture toughness of nano-particle modified epoxy

  2011cited by this paper
• Thiol-ene click chemistry.

  2010cited by this paper
• Thiol-ene “click” reactions and recent applications in polymer and materials synthesis

  2010cited by this paper
• Covalent polymer functionalization of graphene nanosheets and mechanical properties of composites

  2009cited by this paper
• Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene

  2008cited by this paper
• Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite

  2007cited by this paper
• Bipolar supercurrent in graphene

  2006cited by this paper

• Nanoscale structures with GO “armor” for protecting mechanical properties of EP in cryogenic irradiation environments

  2026cites this paper
• Anti-stacking, recyclable and electron-rich Fe3O4 modified L-glutamic acid functionalized graphene oxide towards Cr(VI) removal by adsorption-reduction behavior

  2025cites this paper
• Enhancing the mechanical and electrochemical properties of reduced graphene oxide composites films through the combined actions of chitosan and polypyrrole

  2025cites this paper
• Friction properties of two surface-modified MoS2 in rapeseed oil

  2025cites this paper
• Performance of Epoxy Resin Composites Reinforced with SiC Modified by Hydroxyl Silane Coupling Agents

  2025cites this paper
• High-efficient toughening and strengthening of epoxy resin with organic–inorganic core–shell nanoparticles

  2025cites this paper
• Tensile properties improvement of a unidirectional-mat flax/epoxy composite via click chemistry, nanocellulose addition and surface refining of short mat fibres

  2025cites this paper
• Enhancement of tensile properties of flax-mat epoxy composites via click chemistry with surface fibrillation and compaction of the fiber preforms

  2025cites this paper
• Collaborative Improvement of Interfacial Properties of Carbon Fiber/Epoxy Resin Composites Through Modulus/Toughness Matching and Gradient Interface

  2025cites this paper
• Progression from graphene and graphene oxide to high-performance epoxy resin-based composite

  2024cites this paper
• The effect of deep-sea pressure during long-term aging on the tribological performance of fabric-reinforced phenolic composites

  2024cites this paper
• Advanced chemical modification technology of inorganic oxide nanoparticles in epoxy resin and mechanical properties of epoxy resin nanocomposites: A review

  2024cites this paper
• Synergistic toughening modification and finite element analysis of carbon fiber/epoxy resin‐reinforced composites

  2024cites this paper
• Click chemistry modifications for the selective crosslinking of wood pulp fibers – effect on the physical and mechanical properties of paper

  2024cites this paper
• Study on strengthening and toughening Al/CFRP hybrid composites with biomimetic interface

  2024cites this paper
• Rationally designed phosphate-doped zinc-cobalt based MOFs wrapped ZnAl-LDH decorated LGO; towards designing epoxy coating with enhanced mechanical & thermal properties

  2024cites this paper
• Construction of 3D structured MXene-h-BN hybrid via thiol-ene click chemistry to enhance thermal and tribological properties of fabric composites

  2024cites this paper
• Effect of curing temperature on shape memory properties of graphene oxide‐carbon fiber hybrid‐reinforced shape memory polymer composites

  2023cites this paper
• Fabrication silver/graphene oxide nanocomposite via UV-induced thiol-ene click reaction and its tribological application

  2023cites this paper
• Preparation of Bi2O3@PCPA‐KH590/chloroprene composites with good mechanical properties under high‐filling

  2023cites this paper
• Preparation of SiO2-decorated GO sheets and their influences on the properties of castor oil-based polyurethane coating film

  2023cites this paper
• Vibration and buckling analysis of agglomerated CNT composite plates via isogeometric analysis using non-polynomial shear deformation theory

  2023cites this paper
• Fabrication of Epoxy-Cuins-Zns Qds- Nanocomposite for Fluorescent, Transparent Toughened Coating Applications

  2023cites this paper
• Dual char-forming strategy driven MXene-based fire-proofing epoxy resin coupled with good toughness.

  2023cites this paper
• 0D-2D nanohybrids based on binary transitional metal oxide decorated boron nitride enabled epoxy resin efficient flame retardant coupled with enhanced thermal conductivity at ultra-low additions

  2023cites this paper
• Mechanistic insights into the roles of graphene oxide and its derivatives in organic transformations – a review

  2023cites this paper
• Influence of temperature on the SMA-PDMS interfacial bond behavior and its modeling with temperature dependent trapezoidal cohesive law

  2023cites this paper
• Self-assembly strengthening-toughening epoxy/Graphene composites through intermolecular π-π interactions with ultralow Graphene content

  2023cites this paper
• Enhancement mechanism of epoxy resin by polyacrylic acid-modified 3D porous graphene: A microscopic and molecular dynamics perspective

  2023cites this paper
• Construction of Ti3C2 MXene based fire resistance nanocoating on flexible polyurethane foam for highly efficient photothermal conversion and solar water desalination.

  2022cites this paper
• Functionalization and Soft Photoreduction of Graphene Oxide Triggered by the Photoinitiator During Thiol-Ene Radical Addition

  2022cites this paper
• Synergistically enhanced thermal control ability and mechanical properties of natural rubber for tires through a graphene/silica with a dot-face structure

  2022cites this paper
• Probing mechanical properties of graphene oxide/epoxy composites based on nano indentation technique

  2022cites this paper
• Difunctional Silicon Dioxide Combined with Graphene Oxide Nanocomposite to Enhance the Anticorrosion Performance of Epoxy Coatings

  2022cites this paper
• Core-double-shell CNTs@SO@PDA and Functionalized BNNS as Nano-hybrids for Synergistically Enhancing Mechanical and Breakdown Performances of Epoxy with Sandwich-like Structure

  2022cites this paper
• High mechanical strength and low ablation rate of phenolic resin composites incorporated with polyhedral oligomeric silsesquioxane‐modified graphene oxide

  2022cites this paper
• Double macromolecules reinforced and toughened GO/epoxy resin composites: The critical role of a rigid-flexible interface

  2022cites this paper
• 2D@0D Multidimensional Nanoparticles for Improving the Fire Safety of Epoxy Resin

  2022cites this paper
• Constructing a fine dispersion and chemical interface based on an electrostatic self-assembly and aqueous phase compound in GO/SiO2/SBR composites to achieve high-wear resistance in eco-friendly green tires

  2022cites this paper
• Gemini ionic liquid modified nacre-like reduced graphene oxide click membranes for ReO4-/TcO4- removal

  2022cites this paper
• Effects of Silicon Dioxide/Graphene Oxide Hybrid Modification on Curing Kinetics of Epoxy Resin

  2022cites this paper
• Self-assembly of Diazonium-modified Boron Nitride Nanosheets and Glass Fibre: A Strategy Synergistically Improving Mechanical, Insulating and Thermal Properties of Glass fibre reinforced polymer Composites

  2022cites this paper
• Effect of core–shell structured SiO 2 @ MoS 2 on the tribological properties of epoxy resin/carboxyl terminated butadiene acrylonitrile composites

  2022cites this paper
• Magnetic field-induced orientation of Fe3O4-GO and toughening effect on epoxy resin

  2022cites this paper
• Constructing a Porous Structure on the Carbon Fiber Surface for Simultaneously Strengthening and Toughening the Interface of Composites.

  2022cites this paper
• Effect of addition of non-functionalized graphene oxide in a commercial epoxy resin used as coating

  2021cites this paper
• Mild temperature-gas separation performance of graphene oxide membranes for extended period: micropore to meso- and macropore readjustments and the fate of membranes under the influence of dynamic graphene oxide changes

  2021cites this paper
• 3D printing nanocomposites with controllable “strength-toughness” transition: Modification of SiO2 and construction of Stereocomplex Crystallites

  2021cites this paper
• Three‐dimensional structured MXene / SiO 2 for improving the interfacial properties of composites by self‐assembly strategy

  2021cites this paper
• Enhanced interfacial adhesion of carbon fiber/epoxy composites by synergistic reinforcement with multiscale “rigid-flexible” structure at interphase

  2021cites this paper
• Attaching SiO2 nanoparticles to GO sheets via amino-terminated hyperbranched polymer for epoxy composites: Extraordinary improvement in thermal and mechanical properties

  2021cites this paper
• Recent advances in the flame retardancy role of graphene and its derivatives in epoxy resin materials

  2021cites this paper
• In situ characterization on macroscale 3D spatial dispersion of MWCNTs in matrix and interfacial phases of quartz fibers/epoxy composites via fluorescence imaging

  2021cites this paper
• Voltage-Stabilizer-Grafted SiO2 Increases the Breakdown Voltage of the Cycloaliphatic Epoxy Resin

  2021cites this paper
• Preparation and Tribological Properties of Modified MoS2/SiC/Epoxy Composites

  2021cites this paper
• Hierarchically porous Co/C nanocomposites for ultralight high-performance microwave absorption

  2021cites this paper
• Graphene oxide nanoplatform surface decoration by spherical zinc-polypyrrole nanoparticles for epoxy coating properties enhancement: Detailed explorations from integrated experimental and electronic-scale quantum mechanics approaches

  2020cites this paper
• Investigation of impediment factors in commercialization of reinforced adhesives

  2020cites this paper
• Preparation and Phase Change Performance of Graphene Oxide and Silica Composite Na2SO4·10H2O Phase Change Materials (PCMs) as Thermal Energy Storage Materials

  2020cites this paper
• Green synthesis of reduced graphene oxide nanosheets decorated with zinc-centered metal-organic film for epoxy-ester composite coating reinforcement: DFT-D modeling and experimental explorations

  2020cites this paper
• One-step generation of silica particles onto graphene oxide sheets for superior mechanical properties of epoxy composite and scale application

  2020cites this paper
• Enhancing mechanical performances of polystyrene composites via constructing carbon nanotube/graphene oxide aerogel and hot pressing

  2020cites this paper
• Nonlocal bending and buckling of agglomerated CNT-Reinforced composite nanoplates

  2020cites this paper
• Synergistic effect of graphene oxide functionalized with SiO2 nanostructures in the epoxy nanocomposites

  2020cites this paper
• Integration of silica with benzoxazine to improve particle dispersion and thermal performance of composites

  2020cites this paper
• Effects of nanomaterials and particles on mechanical properties and fracture toughness of composite materials: a short review

  2019cites this paper
• Hydroxyl-Terminated Triazine Derivatives Grafted Graphene Oxide for Epoxy Composites: Enhancement of Interfacial and Mechanical Properties

  2019cites this paper