Optimization of reaction parameters for the green synthesis of zero valent iron nanoparticles using pine tree needles

Abstract In the current study, the optimal reaction condition for fabrication of INPs by using pine tree (Pinus eldarica) leaf extract was developed. A fractional factorial design was utilized to screen the effective parameters in the green synthesis reaction, and central composite face design was employed to achieve the optimal reaction condition. Leaf extract and iron precursor concentrations were found to be the most effective parameters for the fabrication of INPs. Physicochemical characteristics of the obtained nanoparticles were evaluated by transmission electron microscopy (TEM), Fourier transform infrared (FTIR) spectroscopy, X-ray diffractometer (XRD), vibrating sample magnetometer (VSM), thermogravimetric analysis (TGA), and derivative thermo gravimetric (DTG). The prepared particles were found to be zero-valent iron nanoparticles without any iron oxide impurities. Nanoparticles were spherical in shape with diameters ranging from 8 nm to 34 nm with a mean particle size of 18 nm. The fabricated particles were amorphous with a low magnetization value of 33 memu/g.

• Publication year

  2019

• Venue

  Green Processing and Synthesis

• Publication date

  2019-01-01

• Fields of study

  Materials Science, Chemistry, Environmental Science

• Identifiers
  DOI 10.1515/gps-2019-0055
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• Plant-Mediated Synthesis and Applications of Iron Nanoparticles

  2018cited by this paper
• Characterization of biogenic Fe (III)‐binding exopolysaccharide nanoparticles produced by Ralstonia sp. SK03

  2018cited by this paper
• Biosynthesis of iron nanoparticles using Trigonella foenum-graecum seed extract for photocatalytic methyl orange dye degradation and antibacterial applications.

  2018cited by this paper
• Green synthesized nanoclusters of ultra-small zero valent iron nanoparticles as a novel dye removing material.

  2017cited by this paper
• Green synthesis and characterization of NaEuTi2O6 nanoparticles and its photocatalyst application

  2017cited by this paper
• Synthesis and characterization of biogenic iron oxide nanoparticles using green chemistry approach and evaluating their biological activities

  2017cited by this paper
• Green Synthesis of Silver Nanoparticles Capped with Natural Carbohydrates Using Ephedra intermedia

  2017cited by this paper
• Green Synthesis of Silver Nanoparticles using Mediterranean Cypress (Cupressus sempervirens) Leaf Extract

  2017cited by this paper
• Physicochemical and biological characteristics of the nanostructured polysaccharide‐iron hydrogel produced by microorganism Klebsiella oxytoca

  2017cited by this paper
• Green synthesis and characterization of silver nanoparticles using Alcea rosea flower extract as a new generation of antimicrobials

  2017cited by this paper
• Reduced biofilm formation in Menaquinone-7 production process by optimizing the composition of the cultivation medium

  2017cited by this paper
• Green synthesis and characterization of zero-valent iron nanoparticles using stinging nettle (Urtica dioica) leaf extract

  2017cited by this paper
• Comparative Study on Characteristics and Cytotoxicity of Bifunctional Magnetic-Silver Nanostructures: Synthesized Using Three Different Reducing Agents

  2016cited by this paper
• Green Synthesis of Iron Oxide Nanoparticles and Their Catalytic and In Vitro Anticancer Activities

  2016cited by this paper
• Synthesis And Characterization Of Silver Nanoparticles With Natural Carbohydrate Capping Using Zataria Multiflora

  2016cited by this paper
• Biogenic Fabrication of Iron/Iron Oxide Nanoparticles and Their Application

  2016cited by this paper
• Comparative evaluation of five plant extracts and juices for nanoiron synthesis and application for hexavalent chromium reduction.

  2016cited by this paper
• Plant-mediated synthesis of highly active iron nanoparticles for Cr (VI) removal: Investigation of the leading biomolecules.

  2016cited by this paper
• Cytotoxic effects of Pinus eldarica essential oil and extracts on HeLa and MCF-7 cell lines

  2016cited by this paper
• Biomimetic synthesis of silver nanoparticles using microalgal secretory carbohydrates as a novel anticancer and antimicrobial

  2016cited by this paper
• Template free synthesis of natural carbohydrates functionalised fluorescent silver nanoclusters.

  2016cited by this paper
• Loss of outer membrane integrity in Gram-negative bacteria by silver nanoparticles loaded with Camellia sinensis leaf phytochemicals: plausible mechanism of bacterial cell disintegration

  2016cited by this paper
• SYNTHESIS OF GREEN ZERO-VALENT IRON USING POLYPHENOLS FROM DRIED GREEN TEA EXTRACT

  2015cited by this paper
• Anti-hyperlipidemic and anti-atherosclerotic effects of Pinus eldarica Medw. nut in hypercholesterolemic rabbits

  2015cited by this paper
• Extracellular Production of Recombinant l-Asparaginase II in Escherichia coli: Medium Optimization Using Response Surface Methodology

  2015cited by this paper
• Magnetic immobilization of Bacillus subtilis natto cells for menaquinone-7 fermentation

  2015cited by this paper
• Procedure optimization for green synthesis of silver nanoparticles by aqueous extract of Eucalyptus oleosa.

  2015cited by this paper
• Biosynthesis of hematite nanoparticles and its cytotoxic effect on HepG2 cancer cells.

  2015cited by this paper
• Magnetic Nanoparticles : Magnetic Nanotechnology Using Biomedical Applications and Future Prospects

  2015cited by this paper
• Synthesis and Application of Amine Functionalized Iron Oxide Nanoparticles on Menaquinone-7 Fermentation: A Step towards Process Intensification

  2015cited by this paper
• Characterization of green zero-valent iron nanoparticles produced with tree leaf extracts.

  2015cited by this paper
• The mechanism for degrading Orange II based on adsorption and reduction by ion-based nanoparticles synthesized by grape leaf extract.

  2015cited by this paper
• Green synthesized iron nanoparticles by green tea and eucalyptus leaves extracts used for removal of nitrate in aqueous solution

  2014cited by this paper
• Green synthesis of iron nanoparticles by various tea extracts: comparative study of the reactivity.

  2014cited by this paper
• Green synthesis of Fe nanoparticles using eucalyptus leaf extracts for treatment of eutrophic wastewater.

  2014cited by this paper
• Biosynthesis of stable iron oxide nanoparticles in aqueous extracts of Hordeum vulgare and Rumex acetosa plants.

  2014cited by this paper
• Synthesis of iron-based nanoparticles using oolong tea extract for the degradation of malachite green.

  2014cited by this paper
• Bio-inspired green synthesis of Fe3O4 spherical magnetic nanoparticles using Syzygium cumini seed extract

  2014cited by this paper
• Dye removal using iron–polyphenol complex nanoparticles synthesized by plant leaves

  2014cited by this paper
• Impacts of Iron Oxide Nanoparticles on the Invasion Power of Listeria monocytogenes

  2014cited by this paper
• Characterization of Iron–Polyphenol Nanoparticles Synthesized by Three Plant Extracts and Their Fenton Oxidation of Azo Dye

  2014cited by this paper
• Impacts of Amine Functionalized Iron Oxide Nanoparticles on HepG2 Cell Line

  2014cited by this paper
• Facile fabrication of uniform hollow silica microspheres using a novel biological template.

  2014cited by this paper
• Iron Complex Nanoparticles Synthesized by Eucalyptus Leaves

  2013cited by this paper
• Green Synthesis of Silver Nanoparticles Using Pinus eldarica Bark Extract

  2013cited by this paper
• Preparation of novel magnetic fluorescent nanoparticles using amino acids.

  2013cited by this paper
• Heterogeneous Fenton-like oxidation of monochlorobenzene using green synthesis of iron nanoparticles.

  2013cited by this paper
• Application of green zero-valent iron nanoparticles to the remediation of soils contaminated with ibuprofen.

  2013cited by this paper
• Green production of zero-valent iron nanoparticles using tree leaf extracts.

  2013cited by this paper
• Green synthesis of superparamagnetic Fe3O4 nanoparticles with maltose: Its magnetic investigation

  2013cited by this paper
• Synthesis, Characterization and Anti-Listeria monocytogenes Effect of Amino Acid Coated Magnetite Nanoparticles

  2012cited by this paper
• Thermal Analysis of Magnetic Nanoparticles Modified with Dextran

  2012cited by this paper
• Impact of Amino-Acid Coating on the Synthesis and Characteristics of Iron-Oxide Nanoparticles (IONs)

  2012cited by this paper
• Efficient media for high menaquinone-7 production: response surface methodology approach.

  2011cited by this paper
• Synthesis, characterization and role of zero-valent iron nanoparticle in removal of hexavalent chromium from chromium-spiked soil

  2011cited by this paper
• Screening and Isolation of Extracellular Protease Producing Bacteria from the Maharloo Salt Lake

  2011cited by this paper
• Synthesis, characterization and size control of zerovalent iron nanoparticles anchored on montmorillonite

  2010cited by this paper
• Halotolerant Amylase Production by a Novel Bacterial Strain, Rheinheimera aquimaris

  2010cited by this paper
• Studies on Effect of TiO2 Nanoparticles on Growth and Membrane Permeability of Escherichia coli, Pseudomonas aeruginosa, and Bacillus subtilis

  2010cited by this paper
• Synthesis and characterization of kaolinite-supported zero-valent iron nanoparticles and their application for the removal of aqueous Cu2+ and Co2+ ions

  2009cited by this paper
• Statistical Optimization of Condition for Synthesis Lead Sulfide Nanoparticles

  2009cited by this paper
• Essential Oil Constituents of Leaves and Fruits of Pinus eldarica Medw

  2005cited by this paper
• Synthesis and Characterization of Silica-Coated Iron Oxide Nanoparticles in Microemulsion: The Effect of Nonionic Surfactants

  2001cited by this paper

• Impacts of the Herbal Antimicrobial Compounds on the Antimicrobial Potency of Green Synthesized Copper Nanoparticles.

  2026cites this paper
• Enhanced antibacterial activity and photocatalytic degradation by Clitoria ternatea flower extract-based green CeO2 nanoneedles for wastewater and antibacterial applications

  2026cites this paper
• Phytochemical-Mediated Synthesis of Zinc Oxide Nanoparticles with Enhanced Antimicrobial Properties.

  2025cites this paper
• Salvia sclarea L. mediated green synthesis of gold nanoparticles (AuNPs) and evaluation of their antibacterial, anticandidal, and scolicidal properties

  2025cites this paper
• Fluorometric Zn2+ detection with gallic acid passivated Fe-Ag bimetallic nanocomposites

  2025cites this paper
• Green synthesis of Alginate-nZVIs biosorbent spheres for removal of Rhodamine B and Methylene Blue in aqueous media

  2025cites this paper
• Phyto-Fabrication Tribulus terrestris Mediated Iron Oxide Nanoparticles: A Promising Approach of Antioxidant and Anticancer Activities via in vitro and in silico Studies.

  2025cites this paper
• Metal Nanoparticles Produced Using Autotrophs and Their Bioproducts: A Comparative Overview between Photosynthesizing Taxonomic Groups

  2025cites this paper
• Influence of pH and Annealing Temperature on Hematite (α-Fe2O3) Nanoparticle Synthesis with Pine Needle Extract and Investigation of Structural, Magnetic, and Dielectric Properties

  2025cites this paper
• Agar Cell Diffusion, a Novel Technique to Evaluate Antimicrobial Potency of Nanoparticles in the Powder State

  2025cites this paper
• Green synthesis and analysis of iron oxide nanoparticles for methylene blue degradation by Fenton-like process: Antimicrobial properties and integrated AI-GA modeling

  2025cites this paper
• Experimental Immobilization of Clostridium histolyticum Collagenases on Green-Synthesized CuO Nanoparticles Supported by Bioinformatics Analysis.

  2025cites this paper
• Phase structure transformation and growth mechanism for iron oxide nanoparticles synthesized by mechanochemical method: A mini-review

  2024cites this paper
• Salvia sclarea L. (Clary Sage) Flower Extract-Mediated Green Synthesis of Silver Nanoparticles and Their Characterization, Antibacterial, Antifungal, and Scolicidal Activities against Echinococcus granulosus

  2024cites this paper
• Biogenic Nano Zinc Oxide Particle Production and Their Antimicrobial Potentials: A Review

  2024cites this paper
• In situ green synthesis of iron nanoparticles on PVA nanofiber and its application in adsorptive removal methylene blue

  2024influential citation
• Optimizing CuO Nanoparticle Synthesis via Walnut Green Husk Extract Utilizing Response Surface Methodology

  2024cites this paper
• Alginic acid-functionalized silver nanoparticles: A rapid monitoring tool for detecting the technology-critical element tellurium.

  2023cites this paper
• Green Synthesized Iron-Coated Silver Nanoparticles: Economic Bimetallic Nanoparticles Potential Against Methicillin-Resistance Staphylococcus aureus

  2023cites this paper
• Green Synthesis of Copper Oxide Nanoparticles Using Sesbania grandiflora Leaf Extract and Their Evaluation of Anti-Diabetic, Cytotoxic, Anti-Microbial, and Anti-Inflammatory Properties in an In-Vitro Approach

  2023cites this paper
• A novel green synthesized magnetic biochar from white tea residue for the removal of Pb(II) and Cd(II) from aqueous solution: Regeneration and sorption mechanism.

  2023cites this paper
• Assessment on the photocatalytic and phytotoxic activities using ecobenevolently synthesized iron oxide nanoparticles from the root extracts of Glycyrrhiza glabra

  2023cites this paper
• Investigation of factors affecting removal of arsenic from polluted water using iron-based particles: Taguchi optimization design

  2023cites this paper
• Paper based colorimetric sensor using novel green magnetized nanocomposite of pinus for hydrogen peroxide detection in water and milk

  2023cites this paper
• A narrative review of the synthesis, characterization, and applications of iron oxide nanoparticles

  2023cites this paper
• Potential applications of green-synthesized iron oxide NPs for environmental remediation

  2023cites this paper
• Superior Performance of Iron-Coated Silver Nanoparticles and Cefoxitin as an Antibiotic Composite Against Methicillin-Resistant  Staphylococcus aureus (MRSA): A Population Study

  2023cites this paper
• Green Synthesis of Iron Oxide Nanoparticles Using Ceratonia Siliqua L. Aqueous Extract: Optimization, Characterization, Stabilization and Evaluation of Its Antibacterial Activity Against Gram-Positive and Gram-Negative Bacteria

  2022cites this paper
• Green Synthesis of a novel eco-friendly hydrochar from Pomegranate peels loaded with iron nanoparticles for the removal of copper ions and methylene blue from aqueous solutions

  2022cites this paper
• Evaluating the biological activities of functionalized magnetic iron oxide nanoparticles with different concentrations of aqueous pine leaves extract

  2022cites this paper
• Green synthesis of iron oxide nanoparticles using Ceratonia siliqua L. aqueous extract: improvement of colloidal stability by optimizing synthesis parameters, and evaluation of antibacterial activity against Gram-positive and Gram-negative bacteria

  2022cites this paper
• Structural and spectroscopic analysis of thermally stable Dy3+ activated Na4Ca4Si6O18 phosphor for optoelectronic device applications

  2022cites this paper
• A new nano-delivery system for cisplatin using green-synthesized iron oxide nanoparticles

  2022cites this paper
• Biosynthesis of zerovalent iron nanoparticles for catalytic reduction of 4‐nitrophenol and decoloration of textile dyes

  2022cites this paper
• One step green synthesis of Cu nanoparticles by the aqueous extract of Juglans regia green husk: assessing its physicochemical, environmental and biological activities

  2022cites this paper
• Biogenic α-Fe2O3 Nanoparticles Enhance the Biological Activity of Trichoderma against the Plant Pathogen Sclerotinia sclerotiorum

  2021cites this paper
• Water vapor dehumidification using thin-film nanocomposite membranes by the in situ formation of ultrasmall size iron-chelated nanoparticles

  2021cites this paper
• Biological Synthesis of Nanoparticles: Gymnosperms

  2021cites this paper
• Characteristics of the Polyphenolic Profile and Antioxidant Activity of Cone Extracts from Conifers Determined Using Electrochemical and Spectrophotometric Methods

  2021cites this paper
• PHYTOPRODUCTION OF IRON NANOPARTICLES FOR METHYL ORANGE REMOVAL AND ITS OPTIMIZATION STUDIES

  2021cites this paper
• Magnetic Nanoparticles: From Synthesis to Theranostic Applications

  2021cites this paper
• Structural characterization of green synthesized magnetic mesoporous Fe3O4NPs@ME

  2021cites this paper
• Kinetically controlled selective synthesis of Cu2O and CuO nanoparticles toward enhanced degradation of methylene blue using ultraviolet and sun light

  2020cites this paper
• Plant Archives

  2020cites this paper
• Conifer-Derived Metallic Nanoparticles: Green Synthesis and Biological Applications

  2020cites this paper