Highly Efficient Photocatalytic CO2-to-CO Conversion Catalyzed by a Surface Ligand-Removed and Cd-Rich CdSe Quantum Dots.

Wu Xia,Jin Wu,Jun‐Chao Hu,Shanshan Sun,Ming-De Li,Hongfang Liu,Minhuan Lan,Feng Wang

Published 2019 in ChemSusChem

ABSTRACT

A surface ligand-removed and Cd-rich CdSe quantum dots as a sole photocatalyst exhibits exceptional activity on CO2-to-CO conversion. The CO production rate up to 789 mmol g-1 h-1 was achieved in TEA/DMF mixture solution under visible light irradiation. Mechanism studies revealed that improving Cd/Se stoichiometric ratio and exposing more active surface Cd atom significantly enhance activity of CdSe QDs on CO2 photoreduction.

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