Electrochemical and Spectral Studies of the Interaction of Niflumic Acid with Metavanadate (VO3) Ions

Emine CoŞkun,E. Biçer,I. Bulut

Published 2015 in International Journal of Electrochemical Science

ABSTRACT

The voltammetric behavior of niflumic acid (HNIF) in the presence and absence of vanadium (V) was investigated using square-wave (SW) voltammetry at physiological pH. SW voltammogram of HNIF exhibited only one cathodic peak at –0.998 V. Due to the complex formation between metavanadate (VO3  , abbreviated as MV) and HNIF, a cathodic signal was observed at –1.228 V. According to the electrochemical results, the stoichiometry of V(V) complex was found to be 1:1. The spectroscopic characterization of the synthesized solid powder V(V)-NIF complex was also carried out.

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