Thermodynamics of water

Abstract Systems at the surface of the Earth are continually responding to energy inputs derived from solar radiation or from the radiogenic heat in the interior. These energy inputs drive plate movements and erosion, exposing metastable mineral phases at the surface and, in addition, these energy fluxes are harvested and transformed by living organisms. As long as these processes persist, chemical disequilibrium at the surface of the Earth will be perpetuated. Chemical disequilibrium is also driven by human activities related to production of food, extraction of water and energy resources, and burial of wastes. To understand how the surface of the Earth will change over time, it is necessary to understand the rates at which reactions occur and the chemical feedbacks that relate these reactions across extreme temporal and spatial scales. This book addresses fundamental and applied questions concerning the rates of water-rock interactions driven by tectonic, climatic, and anthropogenic forces. In particular, this chapter presents the current understanding the thermodynamics of water through an understanding of hydrogen bonding in liquid water.

• Publication year

  2020

• Venue

  Unknown venue

• Publication date

  Unknown publication date

• Fields of study

  Geology, Physics, Environmental Science

• Identifiers
  DOI 10.1016/b978-0-12-803810-9.00004-8
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• Activity of Supercooled Water on the Ice Curve and Other Thermodynamic Properties of Liquid Water up to the Boiling Point at Standard Pressure

  2018cited by this paper
• On the accuracy of the MB-pol many-body potential for water: Interaction energies, vibrational frequencies, and classical thermodynamic and dynamical properties from clusters to liquid water and ice.

  2016cited by this paper
• Molecular properties of aqueous solutions: a focus on the collective dynamics of hydration water.

  2016cited by this paper
• On the existence of two states in liquid water: impact on biological and nanoscopic systems

  2016cited by this paper
• Anomalous thermodynamic properties of ice XVI and metastable hydrates

  2016cited by this paper
• The structural origin of anomalous properties of liquid water

  2015cited by this paper
• Erratum: “Thermodynamic properties of bulk and confined water” [J. Chem. Phys. 141, 18C504 (2014)]

  2014cited by this paper
• Thermodynamic properties of bulk and confined water.

  2014cited by this paper
• The structure of water around the compressibility minimum.

  2014cited by this paper
• Synthesis, biological evaluation, hydration site thermodynamics, and chemical reactivity analysis of α-keto substituted peptidomimetics for the inhibition of Plasmodium falciparum.

  2014cited by this paper
• The molecular charge distribution, the hydration shell, and the unique properties of liquid water.

  2014cited by this paper
• Anomalous properties of water predicted by the BK3 model

  2014cited by this paper
• Water networks contribute to enthalpy/entropy compensation in protein-ligand binding.

  2013cited by this paper
• From anomalies in neat liquid to structure, dynamics and function in the biological world

  2012cited by this paper
• Testing recent charge-on-spring type polarizable water models. I. Melting temperature and ice properties.

  2012cited by this paper
• The hydrogen bond properties of water from 273 K to 573 K; equations for the prediction of gas-water partition coefficients.

  2012cited by this paper
• Hydrogen Bond Interactions Between Water Molecules in Bulk Liquid, Near Electrode Surfaces and Around Ions

  2011cited by this paper
• Hydrogen-bond networks in water clusters (H2O)20: an exhaustive quantum-chemical analysis.

  2010cited by this paper
• Vibrational spectroscopy as a probe of structure and dynamics in liquid water.

  2010cited by this paper
• Near and supercritical water. Part II: Oxidative processes

  2009cited by this paper
• Static and Dynamical Properties of Liquid Water from First Principles by a Novel Car-Parrinello-like Approach.

  2009cited by this paper
• Effect of hydrogen bond cooperativity on the behavior of water

  2008cited by this paper
• Structural dynamics of aqueous salt solutions.

  2008cited by this paper
• Hydrogen-bond network and local structure of liquid water: An atoms-in-molecules perspective.

  2008cited by this paper
• Vibrational and relaxational properties of crystalline and amorphous ices

  2007cited by this paper
• Hydroxide ion hydration in aqueous solutions.

  2007cited by this paper
• Thermodynamics of a pure substance at the triple point

  2007cited by this paper
• Subcritical and supercritical water: a universal medium for chemical reactions

  2005cited by this paper
• Hydrogen bonds in liquid water are broken only fleetingly.

  2005cited by this paper
• Bonding Properties of the Water Dimer: A Comparative Study of Density Functional Theories

  2004cited by this paper
• DNA structure: Revisiting the Watson-Crick double helix

  2003cited by this paper
• An ab initio study of the properties of some hydride dimers

  2003cited by this paper
• Hydrogen bonding in water.

  2003cited by this paper
• How ions affect the structure of water.

  2002cited by this paper
• The IAPWS Formulation 1995 for the Thermodynamic Properties of Ordinary Water Substance for General and Scientific Use

  2002cited by this paper
• Water clusters: Untangling the mysteries of the liquid, one molecule at a time

  2001cited by this paper
• Water: Structure and Properties

  2001cited by this paper
• Water: From Clusters to the Bulk.

  2001cited by this paper
• A new measure of hydrogen bonding strength – ab initio and atoms in molecules studies

  2001cited by this paper
• The Strength of Hydrogen Bonds in Liquid Water and Around Nonpolar Solutes

  2000cited by this paper
• Hydrogen bond thermodynamic properties of water from dielectric constant data

  2000cited by this paper
• Effects of ion atmosphere on hydrogen-bond dynamics in aqueous electrolyte solutions

  2000cited by this paper
• Temperature and pressure effects on the structure of liquid water

  1999cited by this paper
• Standard Reference Data for the Thermal Conductivity of Water

  1995cited by this paper
• Hydrogen bonds in small water clusters: A theoretical point of view.

  1995cited by this paper
• Properties of liquid water : origin of the density anomalies

  1994cited by this paper
• Water Revisited

  1980cited by this paper
• Thermodynamic and Transport Properties of Fluid Water

  1972cited by this paper
• Structure of Water and Hydrophobic Bonding in Proteins. IV. The Thermodynamic Properties of Liquid Deuterium Oxide

  1964cited by this paper
• Molecular Structure of Nucleic Acids: A Structure for Deoxyribose Nucleic Acid

  1953cited by this paper

• Macroscopic quantum effects in the brain: new insights into the fundamental principle underlying conscious processes

  2025cites this paper
• A review of carbon fiber surface modification methods for tailor-made bond behavior with cementitious matrices

  2022cites this paper
• Insoluble chitosan complex as a potential adsorbent for aflatoxin B1 in poultry feed

  2022cites this paper
• The Function of Organic Additives in Enhancing the Q-values for Peat Pellet Biofuel

  2021cites this paper
• Natural freezing-thawing and its impact on dewaterability and anaerobic digestibility of pulp and paper mill biosludge

  year unknowncites this paper