Highly active and selective photochemical reduction of CO2 to CO using molecular-defined cyclopentadienone iron complexes.

Herein, we report highly active (cyclopentadienone)iron-tricarbonyl complexes for CO2 photoreduction using visible light with an Ir complex as photosensitizer and TEOA as electron/proton donor. Turnover numbers (TON) of ca. 600 (1 h) with initial turnover frequencies (TOF) up to 22.2 min(-1) were observed. Operando FTIR measurements allowed for the proposal of a plausible mechanism for catalyst activation.

• Publication year

  2016

• Venue

  Chemical Communications

• Publication date

  2016-06-28

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1039/c6cc01671ePMID 27301351
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

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