SCIENCE@home

Tunable Piezoresistivity from Magnetically Aligned Ni(Core)@Ag(Shell) Particles in an Elastomer Matrix.

Fang Peng,Keke Chen,Armen Yildirim,Xuhui Xia,B. Vogt,M. Cakmak

Published 2019 in ACS Applied Materials and Interfaces

ABSTRACT

Core-shell (Ni@Ag) particles are aligned through the thickness of a poly(dimethylsiloxane) (PDMS) film using a magnetic field in a continuous roll-to-roll process. The alignment of the particles dramatically decreases the percolation threshold for electrical conductivity through the thickness of the film by nearly an order of magnitude from 28 vol % without the field to ≈1 vol % with a 52 mT magnetic field during curing. However, the magnetic forces lead to rough surface topography for intermediate Ni@Ag loadings, but confining the Ni@Ag/PDMS composite by a glass constraint provides a smooth surface. This difference in geometry changes the morphology of the vertically aligned "chains" of Ni@Ag particles where the chains are more aggregated when the film is unconstrained. As the Ni@Ag concentration is decreased below 3.6% for the constrained film, breaks in the aligned particles evident from X-ray tomography lead to pressure sensitive resistance across that film with a large decrease in resistance above a threshold pressure. The threshold pressure is demonstrated to be controllable from ≈15 to ≈290 kPa through the loading of aligned Ni@Ag in the PDMS, but this threshold pressure decreases on cyclic loading. These magnetically aligned composites represent a facile route to mechanically responsive films that could be used in a variety of applications where cyclic loading above and below the threshold pressure is not required, such as disposable pressure sensors for ensuring reliability of products through transportation and embedded structural health monitoring for identifying critical displacements.

PUBLICATION RECORD

CITATION MAP

EXTRACTION MAP

CLAIMS

  • No claims are published for this paper.

CONCEPTS

  • No concepts are published for this paper.

REFERENCES

Showing 1-44 of 44 references · Page 1 of 1

CITED BY

Showing 1-14 of 14 citing papers · Page 1 of 1