Key factor for the anti-Arrhenius low-temperature heterogeneous catalysis induced by H+ migration: H+ coverage over support.

Kota Murakami,Yuta Tanaka,Ryuya Sakai,Yudai Hisai,Sasuga Hayashi,Y. Mizutani,Takuma Higo,Shuhei Ogo,J. Seo,H. Tsuneki,Yasushi Sekine

Published 2020 in Chemical Communications

ABSTRACT

Low-temperature heterogeneous catalytic reaction in an electric field is anticipated as a novel approach for on-demand and small-scale catalytic processes. This report quantitatively reveals the important role of proton coverage on the catalyst support for catalytic ammonia synthesis in an electric field, which shows an anti-Arrhenius behaviour.

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