In this paper we demonstrate the feasibility and utility of an augmented version of the Gibbs ensemble Monte Carlo method for computing the phase behavior of systems with strong, extremely short-ranged attractions. For generic potential shapes, this approach allows for the investigation of narrower attractive widths than those previously reported. Direct comparison to previous self-consistent Ornstein-Zernike approximation calculations is made. A preliminary investigation of out-of-equilibrium behavior is also performed. Our results suggest that the recent observations of stable cluster phases in systems without long-ranged repulsions are intimately related to gas-crystal and metastable gas-liquid phase separation.
Systematic characterization of thermodynamic and dynamical phase behavior in systems with short-ranged attraction.
Patrick Charbonneau,D. Reichman
Published 2006 in Physical review. E, Statistical, nonlinear, and soft matter physics
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PUBLICATION RECORD
- Publication year
2006
- Venue
Physical review. E, Statistical, nonlinear, and soft matter physics
- Publication date
2006-04-18
- Fields of study
Medicine, Physics
- Identifiers
- External record
- Source metadata
Semantic Scholar, PubMed
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