CNT/Co3S4@NiCo LDH ternary nanocomposites as battery-type electrode materials for hybrid supercapacitors

Abstract Hybrid supercapacitors with high energy density and power density have been greatly required for electronic devices. However, the development of the battery-type electrode materials with high performance is still a challenge. In this study, a ternary carbon nanotube (CNT)/Co3S4 @NiCo layered double hydroxides (NiCo LDH) nanocomposite has been prepared by first synthesis of hollow and core-shell Co3S4 @NiCo LDH nanocubes and then mixing them physically with commercial CNT. The electrochemical studies show that the specific capacity of Co3S4 @NiCo LDH is superior to that of individual Co3S4 or NiCo LDH due to their synergistic effect and CNT can remarkably improve the specific capacity of Co3S4 @NiCo LDH. At the optimum mass ratio of 3:10, the specific capacity of CNT/Co3S4 @NiCo LDH at 1 A g −1 can be up to 744 C g −1 (or 206.7 mAh g−1), about 1.8 times that of Co3S4 @NiCo LDH. In addition, a hybrid supercapacitor using Co3S4 @NiCo LDH or CNT/Co3S4 @NiCo LDH as the positive electrode and active carbon (AC) as the negative electrode was assembled. The performance of Co3S4 @NiCo LDH//AC, CNT/Co3S4 @NiCo LDH//AC and two CNT/Co3S4 @NiCo LDH//AC in series was investigated, displaying good practicability as the energy storage and supply devices. This work provides not only a highly efficient battery-type electrode material but also an easy and effective method to fabricate ternary electrode materials.

• Publication year

  2020

• Venue

  Journal of Alloys and Compounds

• Publication date

  2020-05-25

• Fields of study

  Materials Science, Chemistry, Engineering

• Identifiers
  DOI 10.1016/j.jallcom.2020.153937
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• Ni-doped cobalt hexacyanoferrate microcubes as battery-type electrodes for aqueous electrolyte-based electrochemical supercapacitors

  2019cited by this paper
• Hierarchical Nanosheets/Walls Structured Carbon‐Coated Porous Vanadium Nitride Anodes Enable Wide‐Voltage‐Window Aqueous Asymmetric Supercapacitors with High Energy Density

  2019cited by this paper
• Facile construction of Co(OH)2@Ni(OH)2 core-shell nanosheets on nickel foam as three dimensional free-standing electrode for supercapacitors

  2019cited by this paper
• MOF-derived hierarchical nanosheet arrays constructed by interconnected NiCo-alloy@NiCo-sulfide core-shell nanoparticles for high-performance asymmetric supercapacitors

  2019cited by this paper
• MOFs-derived Co9S8-embedded graphene/hollow carbon spheres film with macroporous frameworks for hybrid supercapacitors with superior volumetric energy density

  2019cited by this paper
• Tuning the electrochemical performance of NiCo2O4@NiMoO4 core-shell heterostructure by controlling the thickness of the NiMoO4 shell

  2019cited by this paper
• Unique MOF-derived hierarchical MnO2 nanotubes@NiCo-LDH/CoS2 nanocage materials as high performance supercapacitors

  2019cited by this paper
• Intercalation and delamination behavior of Ti3C2Txand MnO2/Ti3C2Tx/RGO flexible fibers with high volumetric capacitance

  2019cited by this paper
• Recent progress in the hybrids of transition metals/carbon for electrochemical water splitting

  2019cited by this paper
• Reagent induced morphological changes in NiCo2O4 electrode material for flexible supercapacitor

  2019cited by this paper
• Facial design and synthesis of CoSx/Ni-Co LDH nanocages with rhombic dodecahedral structure for high-performance asymmetric supercapacitors

  2019cited by this paper
• Free-standing graphene paper for energy application: Progress and future scenarios

  2019cited by this paper
• Preparation of partially-cladding NiCo-LDH/Mn3O4 composite by electrodeposition route and its excellent supercapacitor performance

  2019cited by this paper
• Oxygen vacancy-engineered Fe2O3 nanoarrays as free-standing electrodes for flexible asymmetric supercapacitors.

  2019cited by this paper
• Hierarchically structured Co3O4@glucose-modified LDH architectures for high-performance supercapacitors

  2019cited by this paper
• Synthesis and Operando Sodiation Mechanistic Study of Nitrogen‐Doped Porous Carbon Coated Bimetallic Sulfide Hollow Nanocubes as Advanced Sodium Ion Battery Anode

  2019cited by this paper
• Interlaced nickel phosphide nanoflakes wrapped orthorhombic niobium pentoxide nanowires array for sustainable aqueous asymmetric supercapacitor

  2019cited by this paper
• Synthesis of NiGa2S4-rGO on nickel foam as advanced electrode for flexible solid-state supercapacitor with superior energy density.

  2019cited by this paper
• Achieving Ultrahigh Capacity with Self-Assembled Ni(OH)2 Nanosheet-Decorated Hierarchical Flower-like MnCo2O4.5 Nanoneedles as Advanced Electrodes of Battery-Supercapacitor Hybrid Devices.

  2019cited by this paper
• Three-dimensional coral-like NiCoP@C@Ni(OH)2 core-shell nanoarrays as battery-type electrodes to enhance cycle stability and energy density for hybrid supercapacitors

  2019cited by this paper
• Mesoporous yolk-shell CoS2/nitrogen-doped carbon dodecahedron nanocomposites as efficient anode materials for lithium-ion batteries

  2019cited by this paper
• Review of carbon-based electrode materials for supercapacitor energy storage

  2019cited by this paper
• N-doped-carbon coated Ni2P-Ni sheets anchored on graphene with superior energy storage behavior

  2018cited by this paper
• In situ preparation of MgCo2O4 nanosheets on Ni-foam as a binder-free electrode for high performance hybrid supercapacitors.

  2018cited by this paper
• Design and Mechanisms of Asymmetric Supercapacitors.

  2018cited by this paper
• Formation of Hierarchical Co9S8@ZnIn2S4 Heterostructured Cages as an Efficient Photocatalyst for Hydrogen Evolution.

  2018cited by this paper
• Tungsten Nitride Nanodots Embedded Phosphorous Modified Carbon Fabric as Flexible and Robust Electrode for Asymmetric Pseudocapacitor.

  2018cited by this paper
• (Ni,Co)Se2 /NiCo-LDH Core/Shell Structural Electrode with the Cactus-Like (Ni,Co)Se2 Core for Asymmetric Supercapacitors.

  2018cited by this paper
• Core-shell structured Ni3S2@Co(OH)2 nano-wires grown on Ni foam as binder-free electrode for asymmetric supercapacitors

  2018cited by this paper
• Co3O4@CoNi-LDH core/shell nanosheet arrays for high-performance battery-type supercapacitors

  2018cited by this paper
• Interlaced Ni-Co LDH nanosheets wrapped Co9S8 nanotube with hierarchical structure toward high performance supercapacitors

  2018cited by this paper
• Transition-metal-based layered double hydroxides tailored for energy conversion and storage

  2018cited by this paper
• MXene—Conducting Polymer Asymmetric Pseudocapacitors

  2018cited by this paper
• Synthesis of NiMn-LDH Nanosheet@Ni3S2 Nanorod Hybrid Structures for Supercapacitor Electrode Materials with Ultrahigh Specific Capacitance

  2018cited by this paper
• Rich‐Mixed‐Valence NixCo3−xPy Porous Nanowires Interwelded Junction‐Free 3D Network Architectures for Ultrahigh Areal Energy Density Supercapacitors

  2018cited by this paper
• Self-Templated Formation of Interlaced Carbon Nanotubes Threaded Hollow Co3S4 Nanoboxes for High-Rate and Heat-Resistant Lithium-Sulfur Batteries.

  2017cited by this paper
• Carbon-based supercapacitors for efficient energy storage

  2017cited by this paper
• Battery‐Supercapacitor Hybrid Devices: Recent Progress and Future Prospects

  2017cited by this paper
• In Situ Transformation of MOFs into Layered Double Hydroxide Embedded Metal Sulfides for Improved Electrocatalytic and Supercapacitive Performance

  2017cited by this paper
• Asymmetric Supercapacitor Electrodes and Devices

  2017cited by this paper
• One-Step Electrodeposition of MnO2@NiAl Layered Double Hydroxide Nanostructures on the Nickel Foam for High-Performance Supercapacitors

  2017cited by this paper
• Self-assembled ultrathin NiCo2S4 nanoflakes grown on Ni foam as high-performance flexible electrodes for hydrogen evolution reaction in alkaline solution

  2016cited by this paper
• Recent progress in the development of anodes for asymmetric supercapacitors

  2016cited by this paper
• Sulphur-doped Co3O4 nanowires as an advanced negative electrode for high-energy asymmetric supercapacitors

  2016cited by this paper
• Appropriate methods for evaluating the efficiency and capacitive behavior of different types of supercapacitors

  2015cited by this paper

• Electrochemical Synergistics between MnS-Co3S4 and FeS-FeS2/Nitrogen-Doped Defect-Rich Reduced Graphene Oxide in High-Performance All-Solid-State Asymmetric Pseudocapacitors.

  2026cites this paper
• Bimetallic ZnNi-ZIF/LDH@P composite electrode derived from zif-8 for efficient asymmetric supercapacitor with outstanding capacitive and stability

  2025cites this paper
• Recent progress in bimetallic and monometallic sulfides and their composites with carbon, MOF, and conductive polymers for high-energy supercapacitor

  2025cites this paper
• Microstructure of porous network CoFe2O4@Co3O4/CNT based on zeolitic imidazolate framework as electrode materials for supercapacitors application

  2025cites this paper
• Nanoarchitectonic Grafting of NiCo-Layer Double Hydroxide on Fullerene-Derived Carbon Nanorods for Hybrid Supercapacitors

  2025cites this paper
• Synthesis of hierarchical NiCo-LDH and biphasic Co9S8/Co3S4 core–shell heterostructure for hybrid supercapacitor

  2025cites this paper
• Layered double hydroxide/polypyrrole with neural-like transmission network for high-performance supercapacitor electrode

  2025cites this paper
• Facile preparation NiS/NiCo-LDH via electrodeposition for hybrid supercapacitors

  2025cites this paper
• Self-assembled ZnS@CNT composite nanoparticles for advanced supercapacitor electrode

  2025cites this paper
• Achievements, challenges, and stability of layer double hydroxide and carbon nanotube hybrid electrode materials for clean and sustainable energy storage supercapacitor application: an extensive review

  2024cites this paper
• Advances and significances of carbon nanotube applications: A comprehensive review

  2024cites this paper
• Two birds with one stone: Granulated graphdiyne as durability anode simultaneously support the growing of cathode in asymmetric supercapacitor

  2024cites this paper
• Convenient room-temperature synthesis of sulfur and nitrogen co-doped NiCo-LDH coupled with CNTs on NiCo foam as battery-type electrode for high performance hybrid supercapacitor

  2024cites this paper
• Tailoring the interface in tungsten doped cobalt sulfide positive electrode with ultrathin cobalt oxide atomic layer for high performance energy storage application

  2024cites this paper
• NiFe-LDH/MoS2/MXene Nanocomposites as an Electrode Material for Battery-Type Supercapacitors

  2024cites this paper
• Hierarchical NiCo-LDHs/metal sulfides (V3S4, CuS, Mo2S3) heterostructures with improved electrochemical properties for asymmetric supercapacitors: A comparative study

  2024cites this paper
• Tunable capacitive charge storage of NiCoLDH@rGO for high-energy capacitor: Performance of flexible solid-state capacitor

  2024cites this paper
• Porous NiCo-LDH microspheres obtained by freeze-drying for efficient dye and Cr(VI) adsorption

  2024cites this paper
• Synergistic integration of Ag@Fe0.67Cu0.22Co0.11S core-shell nanostructures and SWCNTs for improved supercapacitor performance

  2024cites this paper
• High Areal Capacitance Nickel-cobalt Transition Metal Hydroxide/reduced Graphene for Structural Supercapacitors

  2023cites this paper
• Controlled Assembly of NiCo-LDH Nanosheets into Diverse superstructures via Concentration-Dependent Solvothermal Method for advanced Supercapacitors

  2023cites this paper
• One-step firmly anchor graphdiyne on NiCo-LDHs as supercapacitor electrode for considerable durability

  2023cites this paper
• Metal–Organic Framework-Derived CoS1.097/Ni9S8 Heterostructure for Hybrid Supercapacitors

  2023cites this paper
• Mesoporous carbon-supported flower-like Mn-doped Ni–Co layered double hydroxides with high cycling capacitance retention for supercapacitors

  2023cites this paper
• Direct growth of cobalt-doped nickel vanadate shelf-like architectures on Ni foam electrodes for solid-state alkaline battery

  2023cites this paper
• Waste Adsorbent-Derived Interconnected Hierarchical Attapulgite@Carbon/NiCo Layered Double Hydroxide Nanocomposites for Advanced Supercapacitors.

  2023cites this paper
• Comparative research of hierarchical CoS2@C and Co3S4@C nanosheet as advanced supercapacitor electrodes

  2023cites this paper
• Cr-doped Ni-MOF nanosheet array structure anchored on nickel foam with specific orientation for high performance supercapacitors

  2023cites this paper
• Ni2P/ZnP2 nanocrystals/rGO decorated on NiO/ZnO nanoflakes as a high-performance cathode for flexible hybrid supercapacitor

  2023cites this paper
• Enhanced electrochemical capacitance of a surfactant modified hierarchical Co(OH)2/TiO2 nanotube array for supercapacitor applications

  2023cites this paper
• Recent advances in flexible supercapacitors

  2022cites this paper
• Novel fabrication strategy of nanostructured NiCo-LDHs monolithic supercapacitor electrodes via inducing electrochemical in-situ growth on etched nickel foams

  2022cites this paper
• Construction of advanced zeolitic imidazolate framework derived cobalt sulfide/MXene composites as high-performance electrodes for supercapacitors.

  2022cites this paper
• Biomass-derived carbon dots regulating nickel cobalt layered double hydroxide from 2D nanosheets to 3D flower-like spheres as electrodes for enhanced asymmetric supercapacitors.

  2022cites this paper
• Self-supported Co-Ni-S@CoNi-LDH electrode with a nanosheet-assembled core-shell structure for a high-performance supercapacitor

  2022cites this paper
• In situ deposition of conducting polymer on metal organic frameworks for high performance hybrid supercapacitor electrode materials

  2022cites this paper
• Facile assembly of cobalt-nickel double hydroxide nanoflakes on nitrogen-doped hollow carbon spheres for high performance asymmetric supercapacitors

  2022cites this paper
• Boosting the performance of nickel–cobalt LDH cathode with phosphorus and selenium co-doping for hybrid supercapacitor

  2022cites this paper
• A regulation strategy using trace copper boosting electrocatalytic activity of bifunctional metallic dihydroxy in hydrogen evolution and methanol oxidation

  2022cites this paper
• Recent progress in stretchable and self-healable supercapacitors: active materials, mechanism, and device construction

  2022cites this paper
• A metal-organic-framework derived NiFe2O4@NiCo-LDH nanocube as high-performance lithium-ion battery anode under different temperatures

  2022cites this paper
• Cobalt–nickel layered double hydroxide on hollow Co3S4/CuS derived from ZIF-67 for efficient overall water splitting

  2022cites this paper
• Electrodeposited cobalt sulfide nanolayer fenced nickel-copper carbonate hydroxide nanowires as an electrode for hybrid supercapacitors: A wind turbine-driven energy storage system for portable applications

  2022cites this paper
• Regulation of morphology and electrochemical properties of Ni-Co LDHs electrode materials by lower saturated monohydric alcohols coordination

  2022cites this paper
• Ni@NC@NiCo-LDH nanocomposites from a sacrificed template Ni@NC@ZIF-67 for high performance supercapacitor

  2022cites this paper
• A sandwich-like CoNiLDH@rGO@CoNi2S4 electrode enabling high mass loading and high areal capacitance for solid-state supercapacitors

  2022cites this paper
• Heterogeneous Mn-Ni(OH)2/NiO@C hierarchical porous nanosheets for high energy density hybrid supercapacitors

  2022cites this paper
• Metal–organic Framework-Derived CoSx/NiS Co-Decorated Heterostructures: Toward Simultaneous Acceleration of Charge Carrier Separation and Catalytic Kinetics

  2022cites this paper
• Novel ZIF67/Mn/MWCNTs decorated with layer double hydroxide supercapacitor electrodes

  2021cites this paper
• In situ growth of hydrophilic nickel-cobalt layered double hydroxides nanosheets on biomass waste-derived porous carbon for high-performance hybrid supercapacitors

  2021cites this paper
• Synthesis of CNTs/CoNiFe-LDH Nanocomposite with High Specific Surface Area for Asymmetric Supercapacitor

  2021cites this paper
• A three-dimensional NiCo-LDH array modified halloysite nanotube composite for high-performance battery-type supercapacitor

  2021cites this paper
• Preparation of Co2Al layered double hydroxide nanosheet/Co2Mn bimetallic hydroxide nanoneedle nanocomposites on nickel foam for supercapacitors

  2021cites this paper
• Neoteric hollow tubular MnS/Co3S4 hybrids as high-performance electrode materials for supercapacitors

  2021cites this paper
• Synthesis of hierarchical porous CoS2/MWCNTs nanohybrids as electrode for high-performance supercapacitors with enhanced rate capability and cycling stability

  2021cites this paper
• Tailoring the Composition of Ternary Layered Double Hydroxides for Supercapacitors and Electrocatalysis

  2021cites this paper
• Integrated Battery-Capacitor Electrodes: Pyridinic N-Doped Porous Carbon-Coated Abundant Oxygen Vacancy Mn-Ni-Layered Double Oxide for Hybrid Supercapacitors.

  2021cites this paper
• Tailored synthesis of nano-corals nickel-vanadium layered double hydroxide@Co2NiO4 on nickel foam for a novel hybrid supercapacitor

  2021cites this paper
• Hierarchical Porous Heterostructured Co(OH)2/CoSe2 nanoarray: A Controllable Design Electrode for Advanced Asymmetrical Supercapacitors

  2021cites this paper
• Hierarchical Ni2P@Ni(OH)2 architectures supported on carbon cloth as battery-type electrodes for hybrid supercapacitors with boosting specific capacitance and cycle stability

  2021cites this paper
• Three dimensional hierarchical porous nickel cobalt layered double hydroxides (LDHs) and nitrogen doped activated biocarbon composites for high-performance asymmetric supercapacitor

  2021cites this paper
• Mesoporous Nanohybrids of 2D Ni‐Cr‐Layered Double Hydroxide Nanosheets Pillared with Polyoxovanadate Anions for High‐Performance Hybrid Supercapacitor

  2021cites this paper
• NiMn Layered Double Hydroxide Nanosheets In-situ Anchored on Ti3C2 MXene via Chemical Bonds for Superior Supercapacitors

  2020cites this paper
• Electrodeposition of Co4S3 on NiCo LDH nanosheet arrays for advanced hydrogen evolution

  2020cites this paper
• Current State and Future Prospects for Electrochemical Energy Storage and Conversion Systems

  2020cites this paper
• Synthesis of reduced graphene oxide supported nickel-cobalt-layered double hydroxide nanosheets for supercapacitors.

  2020cites this paper
• Engineering the Hierarchical Heterostructures of Zn–Ni–Co Nanoneedles Arrays@Co–Ni-LDH Nanosheets Core–Sheath Electrodes for a Hybrid Asymmetric Supercapacitor with High Energy Density and Excellent Cyclic Stability

  2020cites this paper
• Synthesis of Co3S4-SnO2/polyvinylpyrrolidone-cellulose heterojunction as highly performance catalyst for photocatalytic and antimicrobial properties under ultra-violet irradiation.

  2020cites this paper