One-pot beta-substitution of enones with alkyl groups to beta-alkyl enones.

No abstract is available for this paper.

• Publication year

  2005

• Venue

  Chemical Communications

• Publication date

  2005-05-05

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1039/b502134kPMID 15877141
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• One-pot dehydrogenation of carboxylic acid derivatives to α,β-unsaturated carbonyl compounds under mild conditions

  2005cited by this paper
• Palladium‐Catalyzed Vinylation of Organic Halides

  2005cited by this paper
• New Oxidations Using Sulfinimidoyl Chlorides

  2004cited by this paper
• Structural revision and total synthesis of azaspiracid-1, part 2: definition of the ABCD domain and total synthesis.

  2004cited by this paper
• Formal total synthesis of (±)-magellanine

  2003cited by this paper
• The asymmetric intramolecular Heck reaction in natural product total synthesis.

  2003cited by this paper
• A new method for oxidation of various alcohols to the corresponding carbonyl compounds by using N-T-butylbenzenesulfinimidoyl chloride

  2002cited by this paper
• Cobalt-catalyzed Heck-type reaction of alkyl halides with styrenes.

  2002cited by this paper
• Oxidation of silyl enol ethers by using IBX and IBX.N-oxide complexes: a mild and selective reaction for the synthesis of enones.

  2002cited by this paper
• A Mild and Efficient Oxidation of Alcohols with N-tert-Butylphenylsulfinimidoyl Chloride in the Coexistence of Zinc Oxide

  2001cited by this paper
• Oxidative Deamination of Various Primary Amines to the Corresponding Carbonyl Compounds by Using N-tert-Butylphenylsulfinimidoyl Chloride

  2001cited by this paper
• Oxidation of Various Secondary Amines to Imines with N-tert-Butylphenylsulfinimidoyl Chloride

  2001cited by this paper
• A convenient method for the synthesis of nitrones by oxidation of N,N-disubstituted hydroxylamines with N-tert-butylphenylsulfinimidoyl chloride

  2001cited by this paper
• A New and Efficient Method for Oxidation of Various Alcohols by Using N-tert-Butyl Phenylsulfinimidoyl Chloride

  2000cited by this paper
• A New and One-Pot Synthesis of α,β-Unsaturated Ketones by Dehydrogenation of Various Ketones with N-tert-Butyl Phenylsulfinimidoyl Chloride

  2000cited by this paper
• Palladium-Catalyzed Coupling Reactions of 1-Bromoadamantane with Styrenes and Arenes

  1998cited by this paper
• Higher order, mixed cyanocuprates derived from n-lithio-imidazole and pyrrole: New “dummy” ligand alternatives in organocopper chemistry

  1992cited by this paper
• Cobaloxime-catalyzed radical alkyl-styryl cross couplings

  1991cited by this paper
• Alkyl-alkenyl cross coupling via alkyl cobaloxime radical chemistry.An alkyl equivalent to the heck reaction compatible with common organic functional groups

  1988cited by this paper
• Condensation of organic bromides with vinyl compounds catalysed by nickel complexes in the presence of zinc

  1988cited by this paper
• 2-thienyl(cyano)copper lithium. A lower order, stable “cuprate in a bottle” precursor to higher order reagents

  1987cited by this paper
• Phosphoniosilylation: an efficient and practical method for the β-functionalization of enones

  1986cited by this paper
• Reaction of β-halo α, β-unsaturated ketones with cuprate reagents. Efficient syntheses of β, β-dialkyl ketones and β-alkyl α,β-unsaturated ketones. A synthesis of (Z)-jasmone

  1982cited by this paper
• Lewis acid induced conjugate addition of alkenes to .alpha.,.beta.-unsaturated ketones or aldehydes

  1980cited by this paper
• Palladium-catalyzed reactions of organic halides with olefins

  1979cited by this paper
• Organoselenium chemistry. Conversion of ketones to enones by selenoxide syn elimination

  1975cited by this paper
• Reaction of cyclic .beta.-halo .alpha.,.beta.-unsaturated ketones with cuprate reagents. New, efficient synthesis of .beta.-alkyl .alpha.,.beta.-unsaturated ketones

  1975cited by this paper
• Regiospecific alkylation of cyclic .beta.-diketone enol ethers. General synthesis of 4-alkylcyclohexenones

  1973cited by this paper
• Arylation of Olefin with Aryl Iodide Catalyzed by Palladium

  1971cited by this paper
• The stability of cyclopropyllithium in diethyl ether and in tetrahydrofuran

  1963cited by this paper

• Total Synthesis and Biological Evaluation of Leptosphaerone B and Derivatives of Microketide A.

  2026cites this paper
• Total Synthesis of (-)-Xylogranatopyridine B via a Palladium-Catalyzed Oxidative Stannylation of Enones.

  2018cites this paper
• Development of a β-C-H Bromination Approach toward the Synthesis of Jerantinine E.

  2017cites this paper
• Enantioselective Synthesis of Quaternary α-Amino Acids via l-tert-Leucine-Derived Squaramide-Catalyzed Conjugate Addition of α-Nitrocarboxylates to Enones.

  2016cites this paper
• Synthesis of β-Substituted Cyclic Enones via Phosphonium Salt-Activated, Palladium-Catalyzed Cross-Coupling of Cyclic 1,3-Diones.

  2016cites this paper
• Organocatalytic enantioselective formal C(sp(2))-H alkylation.

  2015cites this paper
• Experimental Studies on the Selective β-C-H Halogenation of Enones.

  2015cites this paper
• Aerobic double dehydrogenative cross coupling between cyclic saturated ketones and simple arenes.

  2014cites this paper
• Aerobic oxidative Heck/dehydrogenation reactions of cyclohexenones: efficient access to meta-substituted phenols.

  2013cites this paper
• Catalytic carbon insertion into the β-vinyl C-H bond of cyclic enones with alkyl diazoacetates.

  2013cites this paper
• Exploiting the facile release of trifluoroacetate for the α-methylenation of the sterically hindered carbonyl groups on (+)-sclareolide and (-)-eburnamonine.

  2011cites this paper
• Palladium-catalyzed preparation of Weinreb amides from boronic acids and N-methyl-N-methoxycarbamoyl chloride.

  2010cites this paper
• One-pot oxidative carbon–carbon bond formation of 3-benzylic and 3-allylic indoles with carbon nucleophiles

  2008cites this paper
• Highly efficient methods for the one-pot synthesis of beta-substituted enones.

  2006cites this paper
• A mild and convenient synthesis of N-carbobenzyloxy ketimines.

  2006cites this paper
• Biosynthesis of the (2S,3R)-3-methyl glutamate residue of nonribosomal lipopeptides.

  2006cites this paper
• Direct and efficient one-pot preparation of ketones from aldehydes using N-tert-butylphenylsulfinimidoyl chloride.

  2006cites this paper
• One-Pot β-Substitution of Enones with Alkyl Groups to β-Alkyl Enones.

  2005cites this paper