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Crystalline stability of cellulose III nanocrystals in the hydrothermal treatment and NaOH solution.

Qiqi Wu,Junxin Xu,Shiyun Zhu,Yishan Kuang,Bin Wang,W. Gao

Published 2020 in Carbohydrate Polymers

ABSTRACT

To better understand the system and conversion of cellulose allomorphs, cellulose III nanocrystals (CNC-III) were used to investigate the crystalline stability of cellulose III in the hydrothermal condition and a lower concentrated NaOH-water system. It was shown that H2O or alkali played an important role in the process of polymorphic transformation. The CNC-III allomorph turned back to cellulose I with an extremely low crystallinity (∼4.18 %) during hydrothermal process at 90-95 °C, or cellulose II when the temperature excessed boiling point (≥100 °C). Furthermore, CNC-III could be rapidly dissolved in an aqueous NaOH (∼7 wt.%) without a pre-cooled treatment to obtain its stable solution. Afterwards, cellulose II with a steady average crystallite size (∼34) was acquired after the regeneration process via dialysis with distilled water. The polymorphic transformation was also analyzed by X-ray diffraction (XRD), solid-state 13C nuclear magnetic resonance (13C NMR).

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