Bamboo-like π-Nanotube with Tunable Helicity and Circularly Polarized Luminescence.

We report the fabrication of an exotic bamboo-like π-nanotube via the hierarchical self-assembly of a dipeptide-substituted naphthalenediimide gelator with tunable helicity and circularly polarized luminescence (CPL). It was found that in the presence of trifluoroacetic acid (TFA) the gelator molecule self-assembled into a bamboo-like nanotube, which is composed of truncated nanocones and CPL active. When defining the diameter ratio of the lower to upper edge of each nanocone as a parameter to express the helicity of different nanotubes, it was found that both the helicity and CPL of these nanotubes can be adjusted by the amount of TFA. Moreover, the helicity of the nanotube can be conveyed to the achiral quantum dots (QDs) and produce a hybrid nanotube/QDs CPL active materials with adjustable dissymmetry factor. This work finds a new type self-assembled bamboo-like nanotube and unveiled their helicity and CPL control.

• Publication year

  2021

• Venue

  Angewandte Chemie

• Publication date

  2021-05-06

• Fields of study

  Physics, Medicine, Materials Science, Chemistry

• Identifiers
  DOI 10.1002/anie.202104843PMID 33960094
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

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