Preparation of hybrids of wood sawdust with 3-aminopropyl-triethoxysilane. Application as an adsorbent to remove Reactive Blue 4 dye from wastewater effluents

Abstract Background Biomass-based materials present low sorption capacity. In order to overcome this disadvantage, chemical modification of these materials is required. Methods Hybrids of biomass-based materials were obtained by reacting (25%-200% weight) 3-aminopropyl-triethoxysilane (APTES) with the biomass Ayous wood sawdust (AW), obtaining the hybrid materials AW@APTES-0.25, AW@APTES-0.50, AW@APTES-1.0, AW@APTES-1.5, and AW@APTES-2.0, that were characterized by hydrophobic/hydrophilic balance, CHN elemental analysis, surface area, TGA, FTIR, and pHpzc. Significant findings For screening purposes, the five materials were tested as adsorbents to remove reactive blue 4 (RB-4) from water. The results showed that AW@APTES-0.5 attained the maximum removal of RB-4. The kinetics and equilibrium data were suitably fitted by the nonlinear General-order kinetic (GO) and Liu equilibrium adsorption models. The maximum amount adsorbed of RB-4 dye was 415.1 mg g − 1 using AW@APTES-0.5 (50 °C). An increase in the Qmax value of AW@APTES-0.5 concerning unmodified AW attained up to 21.6 times. The ΔG° and ΔH° indicated that the adsorption processes of RB-4 onto adsorbents are endothermic and spontaneous, and the magnitude of enthalpy of adsorption (25.10 kJ mol−1) is compatible with the electrostatic attraction mechanism. The adsorbents’ applicability for treating simulated dye effluents showed an excellent efficiency attaining 98.66% removal of the effluent.

• Publication year

  2021

• Venue

  Journal of the Taiwan Institute of Chemical Engineers / Elsevier

• Publication date

  2021-06-20

• Fields of study

  Materials Science, Chemistry, Environmental Science

• Identifiers
  DOI 10.1016/j.jtice.2021.06.007
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• Complex interior and surface modified alginate reinforced reduced graphene oxide-hydroxyapatite hybrids: Removal of toxic azo dyes from the aqueous solution.

  2021cited by this paper
• Green synthesis of poly(pyrrole methane) for enhanced adsorption of anionic and cationic dyes from aqueous solution.

  2021cited by this paper
• Nitrogen-rich covalent triazine frameworks for high-efficient removal of anion dyes and the synergistic adsorption of cationic dyes.

  2021cited by this paper
• Electrospun chitosan/polyvinyl alcohol nanocomposite holding polyaniline/silica hybrid nanostructures: An efficient adsorbent of dye from aqueous solutions

  2021cited by this paper
• Synthesis of Schiff's base magnetic crosslinked chitosan-glyoxal/ZnO/Fe3O4 nanoparticles for enhanced adsorption of organic dye: Modeling and mechanism study

  2021cited by this paper
• Design and fabrication of core-shell magnetic and non-magnetic supported carbonaceous metal organic framework nanocomposites for adsorption of dye

  2021cited by this paper
• Evaluation of toxicity and mutagenicity of a synthetic effluent containing azo dye after Advanced Oxidation Process treatment.

  2021cited by this paper
• Single-step pyrolysis for producing magnetic activated carbon from tucumã (Astrocaryum aculeatum) seed and nickel(II) chloride and zinc(II) chloride. Application for removal of nicotinamide and propanolol.

  2020cited by this paper
• Comparison of the nonlinear and linear forms of the van't Hoff equation for calculation of adsorption thermodynamic parameters (∆S° and ∆H°)

  2020cited by this paper
• One-step silanization and amination of lignin and its adsorption of Congo red and Cu(II) ions in aqueous solution.

  2020cited by this paper
• Hybrid coagulation-flocculation and anaerobic-aerobic biological treatment for industrial textile wastewater: pilot case study

  2020cited by this paper
• Efficient adsorbent based on construction and demolition wastes functionalized with 3-aminopropyltriethoxysilane (APTES) for the removal ciprofloxacin from hospital synthetic effluents

  2020cited by this paper
• Is one performing the treatment data of adsorption kinetics correctly?

  2020cited by this paper
• Textile dyes Maxilon blue 5G and Reactive blue 203 induce acute toxicity and DNA damage during embryonic development of Danio rerio.

  2020cited by this paper
• Investigation of chromate and nitrate removal by adsorption at the surface of an amine-modified cocoa shell adsorbent

  2020cited by this paper
• Polysulfone metal-activated carbon magnetic nanocomposites with enhanced CO2 capture

  2020cited by this paper
• Augmented Biodegradation of Textile Azo Dye Effluents by Plant Endophytes: A Sustainable, Eco-Friendly Alternative

  2020cited by this paper
• Utilization of Biomass Fly Ash for Improving Quality of Organic Dye-Contaminated Water

  2020cited by this paper
• Functionalization of corn stover with 3-aminopropyltrietoxysilane to uptake Reactive Red 141 from aqueous solutions

  2019cited by this paper
• A critical review of the estimation of the thermodynamic parameters on adsorption equilibria. Wrong use of equilibrium constant in the Van't Hoof equation for calculation of thermodynamic parameters of adsorption

  2019cited by this paper
• Synthesis of a novel CoFe2O4/chitosan magnetic composite for fast adsorption of indigotine blue dye.

  2019cited by this paper
• Silane modified epoxy coatings with low surface tension to achieve self-healing of wide damages

  2019cited by this paper
• Degradation of Textile Dyes Employing Advanced Oxidative Processes: Kinetic, Equilibrium Modeling, and Toxicity Study of Seeds and Bacteria

  2019cited by this paper
• Preparation, characterization of titanate nanosheet–pozzolan nanocomposite and its use as an adsorbent for removal of diclofenac from simulated hospital effluents

  2019cited by this paper
• Synthesis and characterization of Schiff-base based chitosan-g-glutaraldehyde/NaMMTNPs-APTES for removal Pb2+ and Hg2+ ions.

  2019cited by this paper
• Chemical modification of cellulose with zwitterion moieties used in the uptake of red Congo dye from aqueous media

  2019cited by this paper
• Efficient acetaminophen removal from water and hospital effluents treatment by activated carbons derived from Brazil nutshells

  2019cited by this paper
• Synthesis and characterization of biopolymers functionalized with APTES (3–aminopropyltriethoxysilane) for the adsorption of sunset yellow dye

  2019cited by this paper
• Magnetic activated carbon nanocomposite from Nigella sativa L. waste (MNSA) for the removal of Coomassie brilliant blue dye from aqueous solution: Statistical design of experiments for optimization of the adsorption conditions

  2018cited by this paper
• Production of porous activated carbons from Caesalpinia ferrea seed pod wastes: Highly efficient removal of captopril from aqueous solutions

  2018cited by this paper
• Synthesis and characterization of a novel organic-inorganic hybrid clay adsorbent for the removal of acid red 1 and acid green 25 from aqueous solutions

  2018cited by this paper
• Grafting of Amine functional group on silicate based material as adsorbent for water purification: A short review

  2018cited by this paper
• Microwave-activated carbons from tucumã (Astrocaryum aculeatum) seed for efficient removal of 2-nitrophenol from aqueous solutions

  2018cited by this paper
• Estimation of the dimension of micropores and mesopores in single walled carbon nanotubes using the method Horvath–Kawazoe, Saito and Foley and BJH equations

  2017cited by this paper
• Efficient removal of amoxicillin and paracetamol from aqueous solutions using magnetic activated carbon

  2017cited by this paper
• Hybrid adsorbents of tannin and APTES (3-aminopropyltriethoxysilane) and their application for the highly efficient removal of acid red 1 dye from aqueous solutions

  2017cited by this paper
• Alternative treatments to improve the potential of rice husk as adsorbent for methylene blue.

  2017cited by this paper
• Synthesis of grafted natural pozzolan with 3-aminopropyltriethoxysilane: preparation, characterization, and application for removal of Brilliant Green 1 and Reactive Black 5 from aqueous solutions

  2017cited by this paper
• Adsorption of Alizarin Red S Dye by Carbon Nanotubes: An Experimental and Theoretical Investigation

  2016cited by this paper
• Microwave-assisted activated carbon obtained from the sludge of tannery-treatment effluent plant for removal of leather dyes

  2016cited by this paper
• Preparation of novel adsorbents based on combinations of polysiloxanes and sewage sludge to remove pharmaceuticals from aqueous solutions

  2016cited by this paper
• Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report)

  2015cited by this paper
• Kinetic and Equilibrium Models of Adsorption

  2015cited by this paper
• Mutagenic activation and carcinogenicity of aminoazo dyes ortho-aminoazotoluene and 3′-methyl-4-dimethylaminoazobenzene in experiments on suckling mice

  2014cited by this paper
• Adsorption of Procion Blue MX-R dye from aqueous solutions by lignin chemically modified with aluminium and manganese.

  2014cited by this paper
• Application of Aqai Stalks as Biosorbents for the Removal of the Dye Procion Blue MX-R from Aqueous Solution

  2012cited by this paper
• Ionic silica based hybrid material containing the pyridinium group used as an adsorbent for textile dye.

  2012cited by this paper
• Guidelines and legislation for dye house effluents.

  2007cited by this paper
• Mutagenic and carcinogenic potential of a textile azo dye processing plant effluent that impacts a drinking water source.

  2007cited by this paper
• Comparison of DFT characterization methods based on N2, Ar, CO2, and H2 adsorption applied to carbons with various pore size distributions

  2004cited by this paper
• Evaluation of Rh, Ir, Ru, W–Rh, W–Ir and W–Ru as permanent modifiers for the determination of lead in ashes, coals, sediments, sludges, soils, and freshwaters by electrothermal atomic absorption spectrometry

  2003cited by this paper
• NOVEL REACTIVE RED DYES

  2003cited by this paper
• An approach to estimate the energy of the intramolecular hydrogen bond

  2002cited by this paper
• The use of tungsten–rhodium permanent chemical modifier for cadmium determination in decomposed samples of biological materials and sediments by electrothermal atomic absorption spectrometry

  2000cited by this paper
• Tungsten-rhodium permanent chemical modifier for lead determination in digests of biological materials and sediments by electrothermal atomic absorption spectrometry

  1999cited by this paper
• Electrochemical behaviour of [Ru(4,4′-Me2bpy)2(PPh3)(H2O)](ClO4)2 in homogeneous solution and incorporated into a carbon paste electrode. Application to oxidations of benzylic compounds

  1998cited by this paper

• Application of graphene-based nanoadditives in mineral insulating oil for use in electrical equipment

  2026cites this paper
• Removal of Reactive Blue 4 Dye from Aqueous Solution with Magnetic Fe3O4@Nd/Alg Beads

  2026cites this paper
• Exploring wood-based strategies for dye removal: A comprehensive literature review

  2025cites this paper
• CWPO mechanism for toxic dye degradation in the presence of Cu@FbHAp catalyst: DFT study, performance analysis, response surface methodology, regeneration, and cost estimation

  2025cites this paper
• Magnetic double-layer MOF nanocomposites Fe3O4@ZIF-8@ZIF-67 for efficient adsorptive removal of organic dye and antibiotic

  2025cites this paper
• STRATEGIC ENGINEERING AND FUNCTIONAL MECHANISM ELUCIDATION OF ADVANCED MATERIALS IN DETOXIFICATION OF CONTAMINATED WATER MATRICES

  2025cites this paper
• Production of magnetic carbon adsorbents from hemp hurd: adsorption and kinetics of methylene blue dye removal

  2025cites this paper
• Hybrid nanocellulose material as an adsorbent to remove reactive yellow 2 dye

  2024cites this paper
• Morphology and structure of sawdust waste after adding magnetic nanoparticles

  2024cites this paper
• Machine learning and modelling approach for removing methylene blue from aqueous solutions: Optimization, kinetics and thermodynamics studies

  2024cites this paper
• Removal of methylparaben from aqueous effluents using biobased carbon material. Experimental and DFT calculations

  2024cites this paper
• Synthesis of sustainable mesoporous sulfur-doped biobased carbon with superior performance sodium diclofenac removal: Kinetic, equilibrium, thermodynamic and mechanism.

  2024cites this paper
• Green and sustainable synthesis of mesoporous silica from agricultural biowaste and functionalized with TiO2 nanoparticles for highly photoactive performance

  2024cites this paper
• MgO-modified biochar for the removal of dissolved humus from water and its potential application as a fertilizer

  2024cites this paper
• Intercalation of organosilane in clay mineral for the removal of Procion red MX-5B: Investigational and theoretical studies

  2024cites this paper
• Environmental risk mitigation of lambda-cyhalothrin using tryptophan-modified magnetic nanoparticles: A sustainable emergency response strategy

  2024cites this paper
• Modified Buckwheat Husk as a Filler for Urea–Formaldehyde Resin in Plywood Production

  2024cites this paper
• Potential interaction of metals tolerant bacterial strain (Bacillus cereus) with Para grass (Brachiaria mutica) for remediation of metal contaminated soil

  2024cites this paper
• Characteristics of Removal of Lead, Cadmium and Chromium from Soil Using Biosorbent and Biochar

  2024cites this paper
• Optimization and prediction of dye adsorption utilising cross-linked chitosan-activated charcoal: Response Surface Methodology and machine learning

  2024cites this paper
• Sweet lime peel biomass derived nano-cellulose for dye removal: Kinetics, thermodynamics, optimization and toxicity studies

  2024cites this paper
• Comparative study of the physicochemical properties of metal organic frameworks in the adsorption of textile dyes

  2024cites this paper
• Development and utilization of raw and NaOH-modified peanut hull as potential adsorbents for crystal violet dye removal from wastewater

  2023cites this paper
• Renewable terpene-based highly porous polymer monoliths for the effective removal of persistent pharmaceuticals of tetracycline and ibuprofen

  2023cites this paper
• The production of activated biochar using Calophyllum inophyllum waste biomass and use as an adsorbent for removal of diuron from the water in batch and fixed bed column

  2023influential citation
• Simultaneous adsorption and catalytic degradation of methylene blue dye over recyclable Mn4(P2O7)3 nanoflakes: Mechanism and efficiency

  2023cites this paper
• Powdered and beaded sawdust materials modified iron (III) oxide-hydroxide for adsorption of lead (II) ion and reactive blue 4 dye

  2023cites this paper
• Pomegranate peel-derived biochar as ecofriendly adsorbent of aniline-based dyes removal from wastewater

  2023cites this paper
• Synthesis of green magnetic hybrid adsorbents and their application for reactive red methyl 4 BL dye removal

  2023cites this paper
• Removal of organic and inorganic effluents from wastewater by using degradation and adsorption properties of transition metal-doped nickel ferrite

  2023cites this paper
• Statistical analysis by using soft computing methods for seawater biodegradability using ZnO photocatalyst.

  2023cites this paper
• Reactive blue 4 adsorption efficiencies on bagasse and bagasse fly ash beads modified with titanium dioxide (TiO2), magnesium oxide (MgO), and aluminum oxide (Al2O3)

  2023cites this paper
• Comprehensive adsorption and spectroscopic studies on the interaction of carbon nanotubes with diclofenac anti-inflammatory

  2023cites this paper
• Comparative study for removal of cationic and anionic dyes using alginate-based hydrogels filled with citric acid-sawdust/UiO-66-NH2 hybrid.

  2023cites this paper
• Green synthesis of porous carbon cross-linked Y zeolite nanocrystals material and its performance for adsorptive removal of a methyl violet dye from water

  2023cites this paper
• Wood waste-based functionalized natural hydrochar for the effective removal of Ce(III) ions from aqueous solution

  2023cites this paper
• Preparation of highly porous nitrogen-doped biochar derived from birch tree wastes with superior dye removal performance

  2023cites this paper
• Adsorption of yttrium (Y3+) and concentration of rare earth elements from phosphogypsum using chitin and chitin aerogel

  2023cites this paper
• Nickel-Aluminium layered double hydroxide as an efficient adsorbent to selectively recover praseodymium and samarium from phosphogypsum leachate

  2023cites this paper
• Employ a Clay@TMSPDETA hybrid material as an adsorbent to remove textile dyes from wastewater effluents

  2023cites this paper
• Application of Taguchi Methodology in adsorption of Malachite Green dye using chemically enhanced Bambusa Tulda (Indian Timber Bamboo)

  2023cites this paper
• Surface modification of natural clay with H2O2 for high adsorption of acid Red 114: Experimental and modelling studies

  2023cites this paper
• Zero-Valent Ni/NiO Core-Shell Nanosheets Supported on Graphene for Highly Efficient Dye Adsorption: Isotherm, Kinetic and Thermodynamic Study

  2023cites this paper
• Uptake the rare earth elements Nd, Ce, and La by a commercial diatomite: kinetics, equilibrium, thermodynamic and adsorption mechanism

  2023cites this paper
• Construction of a polyoxoniobate compound in strong alkaline medium and adsorption behavior for cationic dyes

  2023cites this paper
• Comprehensive adsorption and spectroscopic studies on the interaction of magnetic biochar from black wattle sawdust with beta-blocker metoprolol.

  2023cites this paper
• Elucidating the black-box nature of data-driven models in the adsorption of reactive red M-2BE on activated carbon and multi-walled carbon nanotubes through SHapley Additive exPlanations

  2023cites this paper
• Polydopamine-functionalized electrospun poly(vinyl alcohol)/chitosan nanofibers for the removal and determination of Cu(II).

  2023cites this paper
• Mesoporous carbon material prepared from sewage sludge hydrochar using Pluronic F127 as template for efficient removal of phenolic compounds: Experimental study and mechanism interpretation via advanced statistical physics model.

  2022cites this paper
• Bio-fuel additive synthesized from levulinic acid using ionic liquid-furfural based carbon catalyst: Kinetic, thermodynamic and mechanism studies

  2022cites this paper
• Process Parameters Optimization, Characterization, and Application of KOH-Activated Norway Spruce Bark Graphitic Biochars for Efficient Azo Dye Adsorption

  2022cites this paper
• Modelling and Understanding Deposit Formation of Hydrocarbon Fuels from the Coke Characteristics

  2022cites this paper
• Sustainable microalgal biomass valorization to bioenergy: Key challenges and future perspectives.

  2022cites this paper
• Mangrove forest: An important coastal ecosystem to intercept river microplastics.

  2022cites this paper
• Ultrasonication Assisted Catalytic Transesterification of Ceiba Pentandra (Kapok) Oil Derived Biodiesel Using Immobilized Iron Nanoparticles

  2022cites this paper
• A comparative study of chemical treatment by MgCl2, ZnSO4, ZnCl2, and KOH on physicochemical properties and acetaminophen adsorption performance of biobased porous materials from tree bark residues

  2022cites this paper
• Comparative analysis of conventional to biomass-derived adsorbent for wastewater treatment: a review

  2022cites this paper
• Functionalized microspheres with co-participated lignin hybrids as a novel sorbents for toxic C.I. Basic Yellow 2 and C.I. Basic Blue 3 dyes removal from textile sewage

  2022cites this paper
• N-doped activated carbon for high-efficiency ofloxacin adsorption

  2022cites this paper
• Heavy metals in leathers, artificial leathers, and textiles in the context of quality and safety of use

  2022cites this paper
• Fabrication of calcium/cupric crosslinked alginate electrospun nanofibers for enhancing fluoroquinolones adsorption

  2022cites this paper
• Improving the toughness and flame retardancy of poly (lactic acid) with phosphorus‐containing core‐shell particles

  2022cites this paper
• Efficient demethylation of lignin for polyphenol production enabled by low- cost bifunctional protic ionic liquid under mild and halogen-free conditions

  2022cites this paper
• Salt Removal by Chemically Modified Graphene in Capacitive Deionization (CDI)

  2022cites this paper
• Adsorption of p-benzoquinone at low concentrations from aqueous media using biosolid-based activated carbon.

  2022cites this paper
• Unary and binary adsorption of anionic dye and toxic metal from wastewater using 3-aminopropyltriethoxysilane functionalized porous cellulose acetate microspheres

  2022cites this paper
• Influence of alkali metal Na on coal-based soot production

  2022cites this paper
• 3-Aminopropyl-triethoxysilane-Functionalized Tannin-Rich Grape Biomass for the Adsorption of Methyl Orange Dye: Synthesis, Characterization, and the Adsorption Mechanism

  2022cites this paper
• Composite of methyl polysiloxane and avocado biochar as adsorbent for removal of ciprofloxacin from waters

  2022influential citation
• Activated Sawdust-Based Adsorbent for the Removal of Basic Blue 3 and Methylene Green from Aqueous Media

  2022cites this paper
• Highly effective and selective adsorption of Au(III) from aqueous solution by poly(ethylene sulfide) functionalized chitosan: Kinetics, isothermal adsorption and thermodynamics

  2022cites this paper
• Chitosan modified sugarcane bagasse biochar for the adsorption of inorganic phosphate ions from aqueous solution

  2022cites this paper
• Fabrication of PANI@Fe–Mn–Zr hybrid material and assessments in sono-assisted adsorption of methyl red dye: Uptake performance and response surface optimization

  2022cites this paper
• Simultaneous removal of cationic dyes from simulated industrial wastewater using sulfated alginate microparticles

  2022cites this paper
• Fabrication of eco-friendly calcium crosslinked alginate electrospun nanofibres for rapid and efficient removal of Cu(II).

  2022cites this paper
• Computational and Theoretical Study of B-Doped Achiral Single-Walled Carbon Nanotube: A Nonresonant Polarized Raman Analysis

  2022cites this paper
• Egg-derived porous plasma modified clay composite for wastewater remediation

  2022cites this paper
• Lanthanum uptake from water using chitosan with different configurations

  2022cites this paper
• Application of mesoporous zeolite Socony Mobil-5 (ZSM-5) as an adsorbent material for the removal of naphthenic acid present in oil-produced water

  2022cites this paper
• Modified Beaded Materials from Recycled Wastes of Bagasse and Bagasse Fly Ash with Iron(III) Oxide-Hydroxide and Zinc Oxide for the Removal of Reactive Blue 4 Dye in Aqueous Solution

  2022cites this paper
• Chicken and duck eggshell beads modified with iron (III) oxide-hydroxide and zinc oxide for reactive blue 4 dye removal

  2022cites this paper
• Construction of imide-functionalized aromatic conjugation tetracarboxylate frameworks and adsorption behavior for iodine and selective cationic dyes

  2022cites this paper
• Graphitic carbon nitride nanosheets as promising candidates for the detection of hazardous contaminants of environmental and biological concern in aqueous matrices

  2022cites this paper
• Effect of simulated acid rain on plant growth behaviour of Solanum melongena Linn. and Vigna unguiculata ssp cylindrica (L.) Walp.

  2022cites this paper
• Fe3O4 Nanoparticles Loaded Bentonite/Sawdust Interface for the Removal of Methylene Blue: Insights into Adsorption Performance and Mechanism via Experiments and Theoretical Calculations

  2022cites this paper
• Simultaneous removal of Basic blue and Toluidine blue O dyes by Magnetic Fe3O4@polydopamine nanoparticle as an efficient adsorbent using derivative spectrophotometric determination and central composite design optimization

  2022cites this paper
• Amphiphilic hypercrosslinked β-cyclodextrin polymers with rigid networks for efficient acteoside separation

  2022cites this paper
• Direct consolidated bioprocessing for D-glucaric acid production from lignocellulose under subcritical water pretreatment

  2022cites this paper
• Cadmium/lead tolerance of six Dianthus species and detoxification mechanism in Dianthus spiculifolius.

  2022cites this paper
• Porous Spherical Cu2O Supported by Wood-based Biochar Skeleton for the Adsorption-Photocatalytic Degradation of Methyl Orange

  2022cites this paper
• Preparation and Application of Efficient Biobased Carbon Adsorbents Prepared from Spruce Bark Residues for Efficient Removal of Reactive Dyes and Colors from Synthetic Effluents

  2021cites this paper
• Green remediation potential of immobilized oxidoreductases to treat halo-organic pollutants persist in wastewater and soil matrices - A way forward.

  2021cites this paper
• Highly-efficient treated oil shale ash adsorbent for toxic dyes removal: kinetics, isotherms, regeneration, cost analysis and optimization by experimental design

  2021cites this paper