Nonvolatile Me(3)P-like P-donor ligand: synthesis and properties of 4-phenyl-1-phospha-4-silabicyclo[2.2.2]octane.

No abstract is available for this paper.

• Publication year

  2003

• Venue

  Organic Letters

• Publication date

  2003-06-20

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1021/OL0349099PMID 12868886
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• Quantifying the electronic effect of substituted phosphine ligands via molecular electrostatic potential.

  2002cited by this paper
• SYNTHESIS OF 9, 10-DIMETALLATRIPTYCENES CONTAINING GROUP 15 ELEMENTS FROM ortho-PHENYLENEMAGNESIUM

  1999cited by this paper
• A practical synthesis of chiral and achiral phosphonium salts from phosphine borane complexes

  1997cited by this paper
• PH bond activation of primary phosphine-boranes: Access to α-hydroxy and α,α′-dihydroxyphosphine-borane adducts by uncatalyzed hydrophosphination of carbonyl derivatives

  1997cited by this paper
• Phospha-alkynes, RCP: new building blocks in inorganic and organometallic chemistry

  1996cited by this paper
• Phosphaalkynes and phosphaalkenes

  1990cited by this paper
• A general synthesis of optically active phosphines, phosphinites and thiophosphinites from alkylthio(alkylseleno)phosphonium salts and tris(dimethylamino)phosphine as a thiophilic agent

  1984cited by this paper
• Hydroboration. 61. Diisopinocampheylborane of high optical purity. Improved preparation and asymmetric hydroboration of representative cis-disubstituted alkenes

  1982cited by this paper
• 1-phosphabicyclo[2.2.1]heptane 1-oxide and 1-phosphabicyclo[2.2.2]octane 1-oxide. Syntheses and some properties relative to their monocyclic and acyclic analogs

  1974cited by this paper
• MICROWAVE SPECTRA, STRUCTURES, AND DIPOLE MOMENTS OF TRIMETHYLPHOSPHINE-- BORANE AND METHYLPHOSPHINE--BORANE.

  1972cited by this paper
• 569. Triethylenediphosphine (1 : 4-diphosphabicyclo[2 : 2 : 2]-octane)

  1959cited by this paper

• Ir-Catalyzed ortho-C-H Borylation of Aromatic C(sp2)-H Bonds of Carbocyclic Compounds Assisted by N-Bearing Directing Groups

  2024cites this paper
• Dioxaphosphabicyclooctanes: small caged phosphines from tris(hydroxymethyl)phosphine.

  2023cites this paper
• Cage-Shaped Phosphites Having C3-Symmetric Chiral Environment: Steric Control of Lewis Basicity and Application as Chiral Ligands in Rhodium-Catalyzed Conjugate Additions.

  2023cites this paper
• Regioselective Ir-catalyzed C8-H borylation of 4-quinolones via transient O-borylated quinolines.

  2023cites this paper
• A comprehensive review of caged phosphines: synthesis, catalytic applications, and future perspectives

  2021cites this paper
• phosphabarrelene

  2020cites this paper
• Direct immobilization of triphenylphosphine palladium complexes on the external surface of zeolite β

  2019cites this paper
• Synthesis, Properties, and Catalytic Application of a Triptycene-Type Borate-Phosphine Ligand

  2018cites this paper
• Water-Soluble Phosphine Capable of Dissolving Elemental Gold: The Missing Link between 1,3,5-Triaza-7-phosphaadamantane (PTA) and Verkade's Ephemeral Ligand.

  2015cites this paper
• Silica-Supported Triptycene-Type Phosphine. Synthesis, Characterization, and Application to Pd-Catalyzed Suzuki–Miyaura Cross-Coupling of Chloroarenes

  2015cites this paper
• Stereoselective C-H borylations of cyclopropanes and cyclobutanes with silica-supported monophosphane-Ir catalysts.

  2014cites this paper
• Tripod immobilization of triphenylphosphane on a silica-gel surface to enable selective mono-ligation to palladium: application to Suzuki-Miyaura cross-coupling reactions with chloroarenes.

  2014cites this paper
• High-density monolayers of metal complexes: preparation and catalysis.

  2014cites this paper
• Bicyclic bridgehead phosphoramidite (briphos) ligands with tunable π-acceptor ability and catalytic activity in the rhodium-catalyzed conjugate additions.

  2014cites this paper
• Site-selective C-H borylation of quinolines at the C8 position catalyzed by a silica-supported phosphane-iridium system.

  2014cites this paper
• Recent Developments in the Chemistry of Pyridyl-functionalized, Low-coordinate Phosphorus Heterocycles

  2014cites this paper
• Synthesis and Redox Properties of PNP Pincer Complexes Based onN-Methyl-4,4′-bipyridinium: Synthesis and Properties of PNP Pincer Complexes

  2014cites this paper
• Synthesis of primary and secondary alkylboronates through site-selective C(sp3)-H activation with silica-supported monophosphine-Ir catalysts.

  2013cites this paper
• Conjugate Reduction of α,β‐Unsaturated Carbonyl and Carboxyl Compounds with Poly(methylhydrosiloxane) Catalyzed by a Silica‐Supported Compact Phosphane–Copper Complex

  2012cites this paper
• Rh-catalyzed borylation of N-adjacent C(sp3)-H bonds with a silica-supported triarylphosphine ligand.

  2012cites this paper
• Rh-catalyzed ortho-selective C-H borylation of N-functionalized arenes with silica-supported bridgehead monophosphine ligands.

  2011cites this paper
• Palladium-catalyzed borylation of sterically demanding aryl halides with a silica-supported compact phosphane ligand.

  2011cites this paper
• Ester-directed regioselective borylation of heteroarenes catalyzed by a silica-supported iridium complex.

  2010cites this paper
• Synthesis and photophysical properties of 2,3,5,6,7,8-hexasilabicyclo〔2.2.2〕octan-1-yl-substituted arenes

  2010cites this paper
• Directed ortho borylation of phenol derivatives catalyzed by a silica-supported iridium complex.

  2010cites this paper
• Directed ortho borylation of functionalized arenes catalyzed by a silica-supported compact phosphine-iridium system.

  2009cites this paper
• Hydrogenation of hindered ketones catalyzed by a silica-supported compact phosphine-Rh system.

  2008cites this paper
• Self-assembled monolayers of compact phosphanes with alkanethiolate pendant groups: remarkable reusability and substrate selectivity in Rh catalysis.

  2008cites this paper
• Unique Effects of 2,3,5,6,7,8-Hexasilabicyclo[2.2.2]octan-1-yl Moiety on Photophysical Properties of π-Conjugated System

  2007cites this paper
• Comparisons of phosphorus ligation properties in P(CH2NR)3P.

  2007cites this paper
• Monocoordinating, compact phosphane immobilized on silica surface: application to rhodium-catalyzed hydrosilylation of hindered ketones.

  2007cites this paper
• Electronically Tunable Compact Trialkylphosphines: SMAPs-bridged Bicyclic Phosphines

  2006cites this paper
• Heterocyclic compounds with a silicon atom and another non-adjacent different heteroatom

  2006cites this paper
• Phosphabarrelenes as ligands in rhodium-catalyzed hydroformylation of internal alkenes essentially free of alkene isomerization.

  2006cites this paper
• Dihydroboronium derivatives of (S,S)-1,2-bis(t-butylmethylphosphino)ethane as convenient chiral ligand precursors

  2004cites this paper