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Fabrication and investigation of novel monochloroacetic acid fortified, tripolyphosphate-crosslinked chitosan for highly efficient adsorption of uranyl ions from radioactive effluents.

Meng Xia,Ran Gao,Guangming Xu,Yue-Hai You,Xindai Li,Junfeng Dou,Fuqiang Fan

Published 2022 in Journal of Hazardous Materials

ABSTRACT

Chitosan crosslinked with potassium tripolyphosphate (CTPP) and monochloroacetic-acid-modified chitosan crosslinked with potassium tripolyphosphate (MCTPP) were synthesized for removing UO22+ from acidic radioactive effluents. The influential factors, operational requirements, and interactive mechanisms of the adsorption process were systematically investigated. The mesh-structured composites adsorbed UO22+ most effectively at pH 5.0. The maximum adsorption capacities for pure chitosan, CTPP, and MCTPP were 374.93, 780.89, and 1487.72 mg/g, respectively. Batch experiments indicated that the pH and adsorbent dose strongly influenced UO22+ adsorption. MCTPP could adsorb most UO22+ within 15 min, and equilibrium was reached by ~1 h. The adsorption isotherms indicated that UO22+ adsorption by MCTPP may be an endothermic single-layer adsorption process. Moreover, common metal ions in single-metal systems only slightly affected this process. The results of instrumental characterization and natural water application suggested that the highly developed pore structure and abundant tripolyphosphate groups in synthesized composites were dominant adsorption contributors besides amino and hydroxyl groups. Successful development of the novel material for efficiently adsorbing UO22+ and identification of the adsorption mechanism will provide valuable guidance to chitosan modification and further remediation practices of radioactive effluents.

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