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Robust and Multifunctional 3D Graphene-Based Aerogels Reinforced by Hydroxyapatite Nanowires for Highly Efficient Organic Solvent Adsorption and Fluoride Removal.

Yehai Yan,Li Lu,Yuzhen Li,Wenqing Han,Ailin Gao,Shuai Zhao,J. Cui,Guangfa Zhang

Published 2022 in ACS Applied Materials and Interfaces

ABSTRACT

In view of the serious perniciousness and complex diversity of actual wastewater systems, exploiting a robust and multifunctional adsorbent material featuring high sorption efficiency, broad-spectrum applicability, and excellent recyclability in treating multifarious pollutants in water (such as oils and fluoride ions) is highly required; however, it is still a daunting goal to pursue to date. In this work, novel mechanically robust and exceptional graphene oxide/hydroxyapatite nanowire (GO/HAPNW) aerogels (RGHAs/polydopamine (PDA)@RGHAs) with adjustable surface wettability were developed through a facile sol-gel self-assembly technology and subsequently optional bioinspired hydrophilic modification. Thanks to the reinforcing effect of HAPNWs with higher aspect ratio, a remarkably improved mechanical robustness (including superior compressibility and superelasticity) was acquired for the resulting aerogels. Based on the cooperative effect of the favorable selective wetting properties (i.e., hydrophobic/oleophilic for RGHAs) and the excellent mechanic stability, the aerogels displayed an outstanding sorption performance for diverse oils/organic solvents accompanied with a prominent recyclability. Specifically, a fairly high adsorption capacity of as high as 191 times of its own mass (for pump oil) was achieved based on a fast adsorption kinetic process. More importantly, superamphiphilic three-dimensional (3D) PDA@RGHAs revealed an extraordinary removal capability for water-soluble fluoride ions, exhibiting a superior equilibrium adsorption capacity (qe, 9.93 mg/g), which is distinctly superior to those of low-dimensional fluorine adsorbent materials recently reported. Accordingly, the as-prepared 3D aerogels combining both superior oil/organic solvent adsorption and excellent defluorination capability reveal a competitive application prospect toward effective intricate oily wastewater purification.

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