Diisobutylaluminum hydride promoted cyclization of o-(trimethylsilylethynyl)styrenes to indenes.

No abstract is available for this paper.

• Publication year

  2014

• Venue

  Journal of Organic Chemistry

• Publication date

  2014-08-15

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1021/jo501383vPMID 25093271
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• A multicomponent Ni-, Zr-, and Cu-catalyzed strategy for enantioselective synthesis of alkenyl-substituted quaternary carbons.

  2014cited by this paper
• Acylsilanes in rhodium(III)-catalyzed directed aromatic C-H alkenylations and siloxycarbene reactions with C-C double bonds.

  2014cited by this paper
• FeCl3 catalyzed Prins-type cyclization for the synthesis of highly substituted indenes: application to the total synthesis of (±)-jungianol and epi-jungianol.

  2013cited by this paper
• Cu-catalyzed formal methylative and hydrogenative carboxylation of alkynes with carbon dioxide: efficient synthesis of α,β-unsaturated carboxylic acids.

  2013cited by this paper
• Drawing from a pool of radicals for the design of selective enyne cyclizations.

  2013cited by this paper
• Copper-catalyzed asymmetric conjugate addition of alkenyl- and alkylalanes to α,β-unsaturated lactams.

  2013cited by this paper
• Formation of five- and seven-membered rings enabled by the triisopropylsilyl auxiliary group.

  2012cited by this paper
• Gold for the generation and control of fluxional barbaralyl cations.

  2012cited by this paper
• How big is a Cp? Cycloheptatrienyl zirconium complexes with bulky cyclopentadienyl and indenyl ligands.

  2012cited by this paper
• Synthesis of indenes via Brønsted acid catalyzed cyclization of diaryl- and alkyl aryl-1,3-dienes.

  2012cited by this paper
• Regiodivergent synthesis of functionalized indene derivatives via Pt-catalyzed Rautenstrauch reaction of propargyl carbonates.

  2012cited by this paper
• Dialkylaluminum hydride-promoted cyclodimerization of silylated 1,3-enynes via skeletal rearrangement.

  2011cited by this paper
• Enantioselective rhodium(I)-catalyzed [3+2] annulations of aromatic ketimines induced by directed C-H activations.

  2011cited by this paper
• Stereoselective palladium-catalyzed α-arylation of 3-aryl-1-indanones: an asymmetric synthesis of (+)-pauciflorol F.

  2011cited by this paper
• Potassium tert-butoxide promoted intramolecular arylation via a radical pathway.

  2011cited by this paper
• Palladium(II)-catalyzed synthesis of functionalized indenes from o-alkynylbenzylidene ketones.

  2011cited by this paper
• Formation of vinyl-, vinylhalide- or acyl-substituted quaternary carbon stereogenic centers through NHC-Cu-catalyzed enantioselective conjugate additions of Si-containing vinylaluminums to β-substituted cyclic enones.

  2011cited by this paper
• Platinum-catalyzed cycloisomerization of 1,4-enynes via 1,2-alkenyl rearrangement.

  2011cited by this paper
• A combined mechanistic and computational study of the gold(I)-catalyzed formation of substituted indenes.

  2011cited by this paper
• Iron(III)-catalyzed cyclization of alkynyl aldehyde acetals: experimental and computational studies.

  2010cited by this paper
• Group 4 Transition Metal Sandwich Complexes: Still Fresh after Almost 60 Years†

  2010cited by this paper
• Photoenolization-induced oxirane ring opening in 2,5-dimethylbenzoyl oxiranes to form pharmaceutically promising indanone derivatives.

  2010cited by this paper
• Stereoisomerically pure trisubstituted vinylaluminum reagents and their utility in copper-catalyzed enantioselective synthesis of 1,4-dienes containing Z or E alkenes.

  2010cited by this paper
• syn-Selective rhodium(I)-catalyzed allylations of ketimines proceeding through a directed C-H activation/allene addition sequence.

  2010cited by this paper
• A tandem catalytic approach to methyleneindenes: mechanistic insights into gem-dibromoolefin reactivity.

  2010cited by this paper
• Rapid access to 1-methyleneindenes via palladium-catalyzed tandem reactions of 1-(2,2-dibromovinyl)-2-alkynylbenzenes with arylboronic acids.

  2010cited by this paper
• The taiwaniaquinoids: a review.

  2010cited by this paper
• Iodine/Et3SiH: a novel reagent system for the synthesis of 3-aryl-1H-indenes from 1,3-diaryl propargyl alcohols

  2010cited by this paper
• Facile synthesis of benzofulvene derivatives from Baylis–Hillman adducts: In-mediated Barbier reaction combined with Pd(0)-catalyzed intramolecular Heck-elimination cascade

  2010cited by this paper
• Synthesis of 1-methyleneindenes via palladium-catalyzed tandem reactions.

  2009cited by this paper
• Platinum and ruthenium chloride-catalyzed cycloisomerization of 1-alkyl-2-ethynylbenzenes: interception of pi-activated alkynes with a benzylic C-H bond.

  2009cited by this paper
• Synthesis of functionalized indenes via cascade reaction of aziridines and propargyl alcohols.

  2009cited by this paper
• One-pot synthesis of benzo[b]thiophenes and benzo[b]selenophenes from o-halo-substituted ethynylbenzenes: convenient approach to mono-, bis-, and tris-chalcogenophene-annulated benzenes.

  2009cited by this paper
• Catalytic enantioselective allyl- and crotylboration of aldehydes using chiral diol x SnCl4 complexes. optimization, substrate scope and mechanistic investigations.

  2008cited by this paper
• Triggering of the Bergman cyclization by photochemical ring contraction. Facile cycloaromatization of benzannulated cyclodeca-3,7-diene-1,5-diynes.

  2007cited by this paper
• Potent and selective cathepsin K inhibitors.

  2006cited by this paper
• Synthesis, structure, and ethene polymerisation catalysis of 1- or 2-silyl substituted bis[indenyl]zirconium(IV) dichlorides.

  2004cited by this paper
• Synthesis and characterization of 5,10-bis(2-thienyl)indeno

  2000cited by this paper
• Organometallic compounds of Group III. XXX. Kinetic, stereochemical, and molecular association factors in the hydralumination of Group IV substituted alkynes. Role of p.pi.-d.pi. conjugation in the addition of diisobutylaluminum hydride to trimethyl(phenylethynyl)silane

  1975cited by this paper
• Organometallic compounds of Group III. XIX. Regiospecificity and stereochemistry in the hydralumination of unsymmetrical acetylenes. Controlled cis or trans reduction of 1-alkynyl derivatives

  1971cited by this paper
• Organometallic reaction mechanisms. IV. Mechanism of ketone reduction by aluminum alkyls

  1970cited by this paper
• Stereochemistry and Orientation in the Reactions of 1-Phenylpropyne with Diisobutylaluminum Hydride1

  1966cited by this paper

• Regiospecific Methylalumination of Silacyclopropenes: The Access to Z-1-Silyl-2-Aluminyl-Disubstituted Olefins.

  2024cites this paper
• An attempt to consider cooperativity in helical-sense preferences induced in fused macrocycles.

  2023cites this paper
• Uncatalyzed Carbometallation Involving Group 13 Elements: Carboboration and Carboalumination of Alkenes and Alkynes

  2022cites this paper
• Gold(i)-catalyzed diastereoselective synthesis of 1-α-oxybenzyl-1H-indenes.

  2018cites this paper
• Diisobutylaluminum hydride-promoted cyclization of silylated 1,3-dien-5-ynes: Application to total synthesis of a 20-norabietane derivative

  2017cites this paper
• Structures and Photophysical Properties of a 1,8-Anthrylene–Ethenylene Cyclic Tetramer

  2017cites this paper
• Diisobutylaluminum hydride-promoted cyclization of o-(trimethylsilylethynyl)styrenes to substituted naphthalenes

  2016cites this paper
• 1,3-Dien-5-ynes: Versatile Building Blocks for the Synthesis of Carbo- and Heterocycles.

  2016cites this paper
• Diisobutylaluminum hydride-promoted cyclization of benzyl and phenylsilyl ethers bearing a 2-(trimethylsilyl)ethynyl group: syntheses of indenes and benzosiloles

  2016cites this paper
• 1,2,3-Triazoles as inhibitors of indoleamine 2,3-dioxygenase 2 (IDO2).

  2016cites this paper
• Negishi Cross-Coupling Is Compatible with a Reactive B-Cl Bond: Development of a Versatile Late-Stage Functionalization of 1,2-Azaborines and Its Application to the Synthesis of New BN Isosteres of Naphthalene and Indenyl.

  2015cites this paper
• Diisobutylaluminum Hydride Promoted Cyclization of o‐(Trimethylsilylethynyl)styrenes to Indenes.

  2015cites this paper