Recent Advances in Stimuli‐Responsive Luminescent Supramolecular Lanthanide‐Based Metallogels

The use of lanthanide‐based metallogels presents a promising approach for the engineering of stimuli‐responsive gel materials. Stimuli‐responsive luminescent materials based on lanthanides have promising applications in bio‐applications and optical encoding. Synthetic supramolecular metallogels typically become kinetically trapped and usually do not exhibit time‐variable changes in their material properties. However, such supramolecular metallogels can switch between gel to sol when subjected to different external physical and chemical stimuli. This is because weak noncovalent interactions hold together the gel structure and are also influenced by the coordination dynamics of the metal‐ligand bond. This review summarizes recent research progress on stimuli‐responsive supramolecular lanthanide‐based luminescent metallogels. Chemical, physical, and multiple stimuli‐responsiveness of the metallogels are discussed elaborately based on the external stimulus sources. Finally, the latest challenges and opportunities for developing novel metallogels that respond to stimuli are discussed.

• Publication year

  2024

• Venue

  ChemistrySelect

• Publication date

  2024-01-29

• Fields of study

  Not labeled

• Identifiers
  DOI 10.1002/slct.202304755
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• Molecular dynamics study of low molecular weight gel forming salt-triggered dipeptide

  2023cited by this paper
• Recent Advances in Stimuli-Responsive Metallogels

  2023cited by this paper
• Luminescent lanthanide metallogel as a sensor array to efficiently discriminate various saccharides

  2023cited by this paper
• Multiresponsive Self-Healing Lanthanide Fluorescent Hydrogel for Smart Textiles.

  2023cited by this paper
• Modified Low Molecular Weight Pure and Engineered Gels: A Review of Strategies towards Their Development

  2022cited by this paper
• Complexing Eu3+/Tb3+ in a Nanoscale Postmodified Zr-MOF toward Temperature-Modulated Multispectrum Chromism.

  2022cited by this paper
• Supramolecular Adhesive Hydrogels for Tissue Engineering Applications.

  2022cited by this paper
• Multifunctional self-healing eutectogels induced by supramolecular assembly for smart conductive materials, interface lubrication and dye adsorption

  2022cited by this paper
• Personal Perspective on Understanding Low Molecular Weight Gels

  2022cited by this paper
• A Superstable Luminescent Lanthanide Metal Organic Gel Utilized in an Electrochemiluminescence Sensor for Epinephrine Detection with a Narrow Potential Sweep Range.

  2021cited by this paper
• Building Multi-color Emitters with Tailored Lanthanide-based Supramolecular Metallogels

  2021cited by this paper
• Self-Assembly of Lanthanide-Based Metallogel Nanoplates into Microcubic Blocks as Self-Calibrating Luminescent Methanol Sensors

  2021cited by this paper
• Aggregation‐Induced Emission‐Active Gels: Fabrications, Functions, and Applications

  2021cited by this paper
• Supramolecular structures based on metal-organic cages

  2021cited by this paper
• Supramolecular hydrogel with luminescence tunablility and responsiveness based on co-doped lanthanide and deoxyguanosine complex

  2020cited by this paper
• Luminescent lanthanide metallogels: situ fabrication, self-healing and rheological properties

  2020cited by this paper
• Supramolecular Polymerization: A Conceptual Expansion for Innovative Materials

  2020cited by this paper
• Systematic Design of a Low-Molecular-Weight Gelator and Its Application in the Sensing and Retention of Residual Antibiotics

  2020cited by this paper
• Monoethanolamine and Fe(III) based metallohydrogel: An efficient Schottky barrier diode

  2019cited by this paper
• Supramolecular-based nanofibers.

  2019cited by this paper
• Metallogels: Availability, Applicability, and Advanceability

  2019cited by this paper
• Supramolecular Gel as the Template for Catalysis, Inorganic Superstructure, and Pharmaceutical Crystallization

  2019cited by this paper
• Processable and Luminescent Supramolecular Hydrogels from Complex Coacervation of Polycations with Lanthanide Coordination Polyanions

  2019cited by this paper
• Shaping and structuring supramolecular gels

  2019cited by this paper
• Rationally Developed Metallogelators Derived from Pyridyl Derivatives of NSAIDs Displaying Anti-Inflammatory and Anticancer Activities.

  2018cited by this paper
• Stimuli-Responsive Lanthanide-Based Smart Luminescent Materials for Optical Encoding and Bio-applications

  2018cited by this paper
• Binder driven self-assembly of metal-organic cubes towards functional hydrogels

  2018cited by this paper
• Recent Advances in Supramolecular Gels and Catalysis.

  2018cited by this paper
• Stimuli-Responsive Gels

  2018cited by this paper
• Gel Chemistry: Interactions, Structures and Properties

  2018cited by this paper
• A Multi-Redox Responsive Cyanometalate-Based Metallogel.

  2017cited by this paper
• Coordination Polymer Gels with Modular Nanomorphologies, Tunable Emissions, and Stimuli-Responsive Behavior Based on an Amphiphilic Tripodal Gelator.

  2017cited by this paper
• Luminescence Resonance Energy Transfer in a Multiple-Component, Self-Assembled Supramolecular Hydrogel.

  2017cited by this paper
• Designing Hierarchically Nanostructured Conductive Polymer Gels for Electrochemical Energy Storage and Conversion

  2016cited by this paper
• Enantioselective Recognition by Chiral Supramolecular Gels.

  2016cited by this paper
• Tools for identifying gelator scaffolds and solvents.

  2015cited by this paper
• White-Light-Emitting Lanthanide Metallogels with Tunable Luminescence and Reversible Stimuli-Responsive Properties.

  2015cited by this paper
• Healable luminescent self-assembly supramolecular metallogels possessing lanthanide (Eu/Tb) dependent rheological and morphological properties.

  2015cited by this paper
• Development of low-molecular-weight gelators and polymer-based gelators

  2014cited by this paper
• Functional π-gelators and their applications.

  2014cited by this paper
• Metal-organic gels: From discrete metallogelators to coordination polymers

  2013cited by this paper
• Recent advances in metallogels.

  2013cited by this paper
• Supramolecular gels formed from multi-component low molecular weight species.

  2012cited by this paper
• Multi-responsive self-healing metallo-supramolecular gels based on “click” ligand

  2012cited by this paper
• Europium-directed self-assembly of a luminescent supramolecular gel from a tripodal terpyridine-based ligand.

  2012cited by this paper
• A novel "pro-sensitizer" based sensing of enzymes using Tb(III) luminescence in a hydrogel matrix.

  2012cited by this paper
• π-Conjugated cyanostilbene derivatives: a unique self-assembly motif for molecular nanostructures with enhanced emission and transport.

  2012cited by this paper
• Self-organization of multiple components in a steroidal hydrogel matrix: design, construction and studies on novel tunable luminescent gels and xerogels

  2011cited by this paper
• Protein chemical synthesis by ligation of peptide hydrazides.

  2011cited by this paper
• Metal- and anion-binding supramolecular gels.

  2010cited by this paper
• A self-assembled, luminescent europium cholate hydrogel: a novel approach towards lanthanide sensitization.

  2010cited by this paper
• A three-dimensional porous metal-organic framework constructed from two-dimensional sheets via interdigitation exhibiting dynamic features.

  2009cited by this paper
• Recent developments in the field of supramolecular lanthanide luminescent sensors and self-assemblies

  2008cited by this paper
• Noncovalent interactions

  2008cited by this paper
• Supramolecular gelling agents: can they be designed?

  2008cited by this paper
• Molecular wire encapsulated into pi organogels: efficient supramolecular light-harvesting antennae with color-tunable emission.

  2007cited by this paper
• Rheometry of an androstanol steroid derivative paramagnetic organogel. Methodology for a comparison with a fatty acid organogel

  2007cited by this paper
• Molecular organogels. Soft matter comprised of low-molecular-mass organic gelators and organic liquids.

  2006cited by this paper
• Supramolecular gels: functions and uses.

  2005cited by this paper
• Water gelation by small organic molecules.

  2004cited by this paper
• Multistimuli, multiresponsive metallo-supramolecular polymers.

  2003cited by this paper
• Anatomy of a Gel. Amino Acid Derivatives That Rigidify Water at Submillimolar Concentrations

  2000cited by this paper
• Dendritic Physical Gel: Hierarchical Self-Organization of a Peptide-Core Dendrimer to Form a Micrometer-Scale Fibrous Assembly

  2000cited by this paper
• Low Molecular Mass Gelators of Organic Liquids and the Properties of Their Gels.

  1997cited by this paper
• Liquid-crystalline solvents as mechanistic probes. 24. A novel gelator of organic liquids and the properties of its gels

  1987cited by this paper

• Luminescent lanthanide hybrid materials: from molecular design to anti-counterfeiting application

  2026cites this paper
• Metallogels as Hybrid Metal-Organic Soft Materials: Classification, Fabrication Pathways and Functional Applications.

  2026cites this paper
• Multi-stimuli-responsive lanthanide metallogels with chromic behaviors for time-resolved information encryption and anti-counterfeiting.

  2025cites this paper
• Current developments and future perspectives on the formation of luminescent lanthanide supramolecular self-assembly architectures with a focus on nitrogen-based donor ligands.

  2025cites this paper
• UV ‐Shielding Efficiency of Polymer/ ZnO Nanocomposites: Recent Developments and Prospects

  2025cites this paper
• Carbon Nanotube and Graphene Oxide‐Based Polymer Nanocomposite Membranes for Oil–Water Separation—Recent Advances and Future Prospects

  2025cites this paper
• Efficient antimicrobial applications of two novel supramolecular metallogels derived from a l(+)-tartaric acid low molecular weight gelator

  2024cites this paper
• Light-Emitting Coordination Polymers: Stimuli-Responsive Gels, PMMA-Based Composite Films, and UV-Shielding.

  2024cites this paper
• Supramolecular Co (II) Complex Fabricated From Adenine Derivative: Synthesis, Crystal Structure, Hirshfeld Surface, DFT Optimization, Anticancer, and Molecular Docking Studies

  2024cites this paper
• Ultrathin lanthanide-based 2D-coordination nanosheets: A versatile class of 2D materials

  2024cites this paper