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Ionic Liquid-Derived Organic-Inorganic Cocrystal: Synthesis, Crystal Structure, and Its Applications toward Dye Removal and Antidiabetic Activities.

Bibaswan Sen,Sangita Das,Arnob Chakrovorty,Dipali Karmakar,Magdalena Małecka,A. Samadder,Sk Jahir Abbas,N. Sepay,Ranga Rao Gangavarapu,Sk Imran Ali

Published 2025 in Inorganic Chemistry

ABSTRACT

This research focuses on the synthesis of an organic-inorganic cocrystal, i.e., [BmIm]3[PW12O40], utilizing Keggin-type polyoxometalates and single crystals were grown. It highlights the distinctive properties and methods for synthesizing cocrystals, as well as their physicochemical properties and effects on various types of applications. A detailed structural characterization was conducted using single-crystal X-ray diffraction data. All distinct types of intermolecular interactions, encompassing both organic-inorganic and organic-organic interactions were discussed in detail. The cocrystal exhibited a remarkable adsorption capacity of 93 mg/g for methylene blue dye, maintaining approximately 80% efficiency over five consecutive adsorption-desorption cycles, suggesting promising applications in wastewater treatment. Electronic band structure calculations confirm a bandgap energy of 2.1 eV. Furthermore, the cocrystal exhibited antidiabetic effects in animal models, effectively regulating glucose levels at a low dosage of 0.1 mg/g body weight. This treatment not only reduced reactive oxygen species but also enhanced the expression of DNA repair protein p53. PXRD analysis confirms the phase purity; FESEM and TEM analyses exhibit spherical-shaped morphology with particle sizes of ∼30-50 nm. Overall, these findings indicate that [BmIm]3[PW12O40] holds significant potential for both environmental and biomedical applications.

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