Digital and green energy transitions are driving an unprecedented demand for Strategic and Critical Raw Materials (S-CRMs), necessitating the identification of alternative sources such as secondary raw materials from exploration and mining residues. This study investigates an integrated, multi-scale approach to map and recover S-CRMs from an abandoned exploration stockpile in Zlatá Baňa, Slovak Republic. A key aspect of the methodology is comprehensive chemical and mineralogical characterization (XRF, PXRD, FTIR, LIBS, and SEM-EDS), which provided scientific validation for the diagnostic absorption features observed in laboratory reflectance spectra. These laboratory-acquired signatures were then used as endmembers to classify Sentinel-2 imagery via the Spectral Angle Mapper (SAM) algorithm. This integration enabled the identification of three distinct residue classes, with classA (jarosite-rich residues) emerging as the most reactive facies. Subsequent bioleaching experiments using Acidithiobacillus ferrooxidans demonstrated that microbial activity more than doubled Zn mobilization compared to abiotic controls. This cross-disciplinary strategy confirms that the synergy between advanced analytical characterization and remote sensing provides a robust, cost-effective pathway for the sustainable recovery of S-CRMs in regions affected by historical and mining activities.
From Mining Residues to Potential Resources: A Cross-Disciplinary Strategy for Raw Materials Recovery and Supply
Stefano Ubaldini,A. Luptáková,Matteo Paciucci,D. Caschera,R. G. Toro,Isabel Nogués,V. Piñon,Magdaléna Bálintová,A. Eštoková,M. Lupták,E. Mačingová,R. Salvatori,Daniela Guglietta
Published 2026 in Metals
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2026
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Metals
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2026-01-23
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