A kinetic model for the diffusion-controlled annealing of excess vacancies under the experimentally relevant, non-isothermal condition of time-linear heating is presented and applied to dilatometry. The evolution of the vacancy concentration with time is quantitatively analyzed, considering as ideal sinks either dislocations or grain boundaries of spherical- or cylindrical-shaped crystallites. The validity of the model is tested using dilatometry data that were obtained for ultrafine-grained Ni prepared by high-pressure torsion. The entire two-stage annealing curve of the dilatometric length change can be analyzed by combining the present kinetic model of vacancy annealing at grain boundaries with established non-isothermal kinetics of recrystallization.
Kinetics of vacancy annealing upon time-linear heating applied to dilatometry
R. Enzinger,C. Neubauer,J. Kotzurek,W. Sprengel,R. Würschum
Published 2017 in Journal of Materials Science
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- Publication year
2017
- Venue
Journal of Materials Science
- Publication date
2017-11-09
- Fields of study
Medicine, Materials Science, Physics
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Semantic Scholar, PubMed
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