Synthesis of NPN-Coordinated Tantalum Alkyl Complexes and Their Hydrogenolysis: Isolation of a Terminal Tantalum Hydride Incorporating a Doubly Cyclometalated NPN Scaffold.

No abstract is available for this paper.

• Publication year

  2017

• Venue

  Inorganic Chemistry

• Publication date

  2017-04-20

• Fields of study

  Medicine, Materials Science, Chemistry

• Identifiers
  DOI 10.1021/acs.inorgchem.7b00277PMID 28425699
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• Dinitrogen activation by group 4 and group 5 metal complexes supported by phosphine-amido containing ligand manifolds

  2017cited by this paper
• Synthesis and reactivity of Li and TaMe3 complexes supported by N,N'-bis(2,6-diisopropylphenyl)-o-phenylenediamido ligands.

  2016cited by this paper
• Transition-Metal Hydride Radical Cations.

  2016cited by this paper
• Closely Related Benzylene-Linked Diamidophosphine Scaffolds and Their Zirconium and Hafnium Complexes: How Small Changes of the Ligand Result in Different Complex Stabilities and Reactivities

  2016cited by this paper
• Anionic tantalum dihydride complexes: heterobimetallic coupling reactions and reactivity toward small-molecule activation.

  2015cited by this paper
• Synthesis and reactivity of cyclometalated triamidophosphine complexes of niobium and tantalum.

  2015cited by this paper
• Hydrogenolysis of Tantalum Hydrocarbyl Complexes: Intermediates on the Road to a Dinuclear Tantalum Tetrahydride Derivative

  2015cited by this paper
• Efficient access to titanaaziridines by C-H activation of N-methylanilines at ambient temperature.

  2015cited by this paper
• Homolytic H2 cleavage by a mercury-bridged Ni(I) pincer complex [{(PNP)Ni}2{μ-Hg}].

  2015cited by this paper
• Carbon–Carbon Bond Forming Reactions with Tantalum Diamidophosphine Complexes That Incorporate Alkyne Ligands

  2014cited by this paper
• Group 5 hydride and borohydride complexes supported by cyclopentadienyl-imido ligand sets.

  2014cited by this paper
• Generation of low-valent tantalum species by reversible C-H activation in a cyclometallated tantalum hydride complex.

  2014cited by this paper
• Reduction of carbon dioxide promoted by a dinuclear tantalum tetrahydride complex.

  2013cited by this paper
• Insertion Reactions in Ta–H and Ta–Me Bonds in Complexes Containing Tridentate κ3O,S,O-Type Ligands

  2013cited by this paper
• Terminal phosphinidene formation via tantalaziridine complexes.

  2012cited by this paper
• Tantallaaziridines: from synthesis to catalytic applications.

  2012cited by this paper
• Cleavage of Carbon Monoxide Promoted by a Dinuclear Tantalum Tetrahydride Complex

  2012cited by this paper
• Tantalum Complexes Containing a Tridentate [NSN]-Type Ligand: Unusual Reactivity of a Dihydride Complex with an Isocyanide to Give an Azatantallaziridine Moiety

  2011cited by this paper
• Access to new Janus head ligands: linking sulfur diimides and phosphanes for hemilabile tripodal scorpionates.

  2011cited by this paper
• Insertion and reduction chemistry of isocyanide with a cyclometalated ditantalum hydride complex.

  2011cited by this paper
• The hydride route to the preparation of dinitrogen complexes.

  2010cited by this paper
• Cyclometalation using d-block transition metals: fundamental aspects and recent trends.

  2010cited by this paper
• Carbon dioxide reduction by terminal tantalum hydrides: formation and isolation of bridging methylene diolate complexes.

  2010cited by this paper
• Complete disassembly of carbon disulfide by a ditantalum complex.

  2010cited by this paper
• Metalation and Transmetalation Studies on Ph2PN(iPr)P(Ph)N(iPr)H for Selective Ethene Trimerization to 1-Hexene⊥

  2010cited by this paper
• Syntheses, Crystal Structure and Reactivity of Tin(II) Bis[N‐(diphenylphosphanyl)(2‐pyridylmethyl)amide]

  2009cited by this paper
• Reductive coupling of six carbon monoxides by a ditantalum hydride complex.

  2009cited by this paper
• First-row transition metal-halide complexes supported by a monoanionic [N(2)P(2)] ligand.

  2008cited by this paper
• Silyl Hydrides of Tantalum Supported by Cyclopentadienyl-imido Ligand Sets: Syntheses, X-ray, NMR, and DFT Studies

  2008cited by this paper
• Synthesis, reactivity, and DFT studies of tantalum complexes incorporating diamido-N-heterocyclic carbene ligands. Facile endocyclic C-H bond activation.

  2006cited by this paper
• Synthesis and coordination chemistry of the diamido-arsine ligand [NAsN] (NAsN = PhAs(CH2SiMe2NPh)2))

  2006cited by this paper
• Synthesis of the Tantalum Hydride Complex (R,R)-[Ta(O2C20H10{SiMe3}2-3,3‘)2(H)] and Reactivity with Aldehydes, Ketones, Acetylenes, and Related Substrates: A Reagent for the Asymmetric Hydrogenation of Prochiral Carbonyl Species†

  2005cited by this paper
• Cleavage of hydrazine and 1,1-dimethylhydrazine by dinuclear tantalum hydrides: formation of imides, nitrides, and N,N-dimethylamine.

  2005cited by this paper
• Activation and cleavage of alkynes by the dinuclear tantalum complexes ([NPN]Ta)2(µ-H)4 and ([NPN]Ta)2(µ-η1:η2-N2)(µ-H)2 (where NPN = PhP(CH2SiMe2NPh)2)

  2005cited by this paper
• A New Arene-Bridged Diamidophosphine Ligand and Its Coordination Chemistry with Zirconium(IV)

  2005cited by this paper
• Preparation, Structural Characterization, and Reactions of Tantalum-Alkyne Complexes TaCl3(R1C⋮CR2)L2 (L2 = DME, Bipy, and TMEDA; L = Py)

  2003cited by this paper
• Aryl-oxygen bond cleavage by a trihydride-bridging ditantalum complex.

  2003cited by this paper
• Vanadium and niobium diamidophosphine complexes and their reactivity

  2003cited by this paper
• Early transition metal hydride complexes: synthesis and reactivity

  2002cited by this paper
• Structure-spectroscopy correlation in distorted five-coordinate Cu(II) complexes: a case study with a set of closely related copper complexes of pyridine-2,6-dicarboxamide ligands.

  2001cited by this paper
• New mode of coordination for the dinitrogen ligand: formation, bonding, and reactivity of a tantalum complex with a bridging N(2) unit that is both side-on and end-on.

  2001cited by this paper
• Reaction of [P(2)N(2)]Ta==CH(2)(Me) with ethylene: synthesis of [P(2)N(2)]Ta(C(2)H(4))Et, a neutral species with a beta-agostic ethyl group in equilibrium with an alpha-agostic ethyl group ([P(2)N(2)] = PhP(CH(2)SiMe(2)CH(2))(2)PPh).

  2001cited by this paper
• Synthesis and Bonding in the Diamagnetic Dinuclear Tantalum(IV) Hydride Species ([P2N2]Ta)2(μ-H)4 and the Paramagnetic Cationic Dinuclear Hydride Species {([P2N2]Ta)2(μ-H)4}+I- ([P2N2] = PhP(CH2SiMe2NSiMe2CH2)2PPh): The Reducing Ability of a Metal−Metal Bond

  2000cited by this paper
• Ditantalum Hydride Complexes with Bridging (2,6-iPr2C6H3)NSiHPh Silanimine Ligands Resulting from PhSiH3-Imido Ligand Coupling. A Combined Spectroscopic and Theoretical Investigation

  2000cited by this paper
• Reactions of Alkynes and Olefins with Tantalum Hydrides Containing Aryloxide Ancillary Ligation: Relevance to Catalytic Hydrogenation†

  1999cited by this paper
• Advances in the chemistry of bis-cyclopentadienyl hydride derivatives of niobium and tantalum

  1999cited by this paper
• NEW MODE OF COORDINATION FOR THE DINITROGEN LIGAND : A DINUCLEAR TANTALUM COMPLEX WITH A BRIDGING N2 UNIT THAT IS BOTH SIDE-ON AND END-ON

  1998cited by this paper
• Coordination behaviour of LiBEt4 towards (η5-C5H5)2ReH, (η5-C5H5)2WH2 and (η5-C5H5)2TaH3. Solid state structure of [(η5-C5H5)2TaH · A1H2(OCH2CH2CH2CH3)]2

  1997cited by this paper
• Preparation of the First Ditantalum(III) Complex Containing a Ta−Ta Bond without Bridging Ligands

  1996cited by this paper
• A WONDERFUL BOND THAT WASN'T THERE : REFORMULATION OF A COMPOUND CONTAINING A TA-TA BOND WITHOUT BRIDGING LIGANDS AS (CY2N)2CITA(MU -H)2

  1996cited by this paper
• Reactivity of Tantalum Hydride Aryloxide Complexes toward Organic Isocyanide Reagents

  1996cited by this paper
• Synthesis and Characterization of a Series of Mononuclear Tantalum(V) Hydride Compounds Containing Aryloxide Ligation

  1995cited by this paper
• Reaction pathways for the oligomerization of organic isocyanides by tantalum hydride reagents

  1993cited by this paper
• Syntheses, carbonylations, and dihydrogen exchange studies of monomeric and dimeric silox ([sup 1]Bu[sub 3]SiO[sup [minus]]) hydrides of tantalum. Structure of [(silox)[sub 2]TaH[sub 2]][sub 2]

  1993cited by this paper
• Oxo-hydrido and imido-hydrido derivatives of permethyltantalocene. Structures of (.eta.5-C5Me5)2Ta(:O)H and (.eta.5-C5Me5)2Ta(:NC6H5)H: doubly or triply bonded tantalum oxo and imido ligands?

  1992cited by this paper
• Crystal and molecular structure of [Ta(H)2(OC6H3Pri2-2,6)3(PMe2Ph)]: a distorted six-coordinate tantalum dihydride

  1992cited by this paper
• Cyclometalation chemistry of aryl oxide ligation

  1988cited by this paper
• Kinetics and mechanism of the insertion of olefins into niobium- and tantalum-hydride bonds: a study of the competition between steric and electronic effects

  1988cited by this paper
• CO Hydrogenation, Deoxygenation, and C‐C Coupling Promoted by ((silox)2TaH2)2.

  1988cited by this paper
• Carbon Monoxide Cleavage by (silox)3Ta (silox: tBu3SiO-).

  1987cited by this paper
• SYNTHESIS AND CHARACTERIZATION OF BINUCLEAR TANTALUM HYDRIDE COMPLEXES

  1987cited by this paper
• Carbon monoxide hydrogenation, deoxygenation, and carbon-carbon coupling promoted by [(silox)2TaH2]2

  1987cited by this paper
• Silox hydrides [silox = (Me3C)3SiO-] of Group 5: Do [(Me3C)3SiO]2MH2]2 (M = Nb, Ta) contain unbridged M-M bonds?

  1986cited by this paper
• Carbon monoxide cleavage by (silox)3Ta (silox = tert-Bu3SiO-)

  1986cited by this paper
• Transition-metal polyhydride complexes

  1985cited by this paper
• Electron spin resonance spectra of some paramagnetic hydride complexes of niobium(IV) and tantalum(IV)

  1984cited by this paper
• Reduction of carbon monoxide by binuclear tantalum hydride complexes

  1983cited by this paper
• X-ray crystal structure determination of [.eta.5-C5(CH3)5]Ta[P(CH3)3]2H4 and high-field NMR studies of phosphine derivatives of (pentamethylcyclopentadienyl)tantalum(V) hydrides

  1983cited by this paper
• Development of low-valent tantalum chemistry: syntheses and x-ray structures of dichlorotetrakis(trimethylphosphine)tantalum [TaCl2(PMe3)4], dichlorodihydrotetrakis(trimethylphosphine)tantalum [TaCl2H2(PMe3)4] and chlorodihydrotetrakis(trimethylphosphine)tantalum [TaClH2(PMe3)4]

  1983cited by this paper
• X-RAY CRYSTAL STRUCTURE DETERMINATION OF (η5-C5(CH3)5)TA(P(CH3)3)2H4 AND HIGH-FIELD NMR STUDIES OF PHOSPHINE DERIVATIVES OF (PENTAMETHYLCYCLOPENTADIENYL)TANTALUM(V) HYDRIDES

  1983cited by this paper
• Reduction of nitriles by a binuclear tantalum hydride complex. Structural study of [(.eta.5-C5Me4Et)TaCl2](.mu.-.eta.1-N,.eta.2-C,N-NCHMe)(.mu.-Cl)(.mu.-H)[.eta.5-C5Me4Et)TaCl]

  1982cited by this paper
• Binuclear tantalum hydride complexes

  1982cited by this paper
• Tantalum-neopentylidene hydride and tantalum-neopentylidyne hydride complexes

  1980cited by this paper
• Multiple metal-carbon bonds. 7. Preparation and characterization of Ta(.eta.5-C5H5)2(CH2)(CH3), a study of its decomposition, and some simple reactions

  1978cited by this paper
• The preparation of NbH5(Me2PCH2CH2Me2)2 and NbHL2(Me2PCH2CH2PMe2)2 (L = CO or C2H4)

  1976cited by this paper
• SYNTHESIS OF A TANTALUM PENTAHYDRIDE COMPLEX

  1973cited by this paper
• 31P-31P spin-spin coupling in complexes containing two phosphorus ligands

  1970cited by this paper
• 955. The di-π-cyclopentadienyl hydrides of tantalum, molybdenum, and tungsten

  1961cited by this paper

• Synthesis and characterization of Bis(imino)phosphine [NPN] ligands and their copper(I) halide complexes

  2024cites this paper
• Reductive Hydrogenation of Sulfido-Bridged Tantalum Alkyl Complexes: A Mechanistic Insight

  2023cites this paper
• Organometallic Complexes of Group 5 Metals With Metal-Carbon Sigma and Multiple Bonds

  2021cites this paper
• Pitfalls and Limitations in Group 6 Triamidophosphane Chemistry: Cage‐Closure Restrictions in Square‐Pyramidal Nitrido Complexes and Degradation via Spiro‐[4.4]‐λ5‐Amidophosphorane Formation

  2017cites this paper
• Synthetic and Computational Studies on the Thermal and Photochemical Reactions of [NPN]TaMe3 (NPN = PhP(CH2SiMe2NPh)2) and [MesNPN]TaMe3 (MesNPN = PhP(CH2SiMe2N(2,4,6-Me3C6H2))2)

  2017cites this paper