Iridium-catalyzed direct C-H amidation of anilines with sulfonyl azides: easy access to 1,2-diaminobenzenes.

No abstract is available for this paper.

• Publication year

  2017

• Venue

  Organic and biomolecular chemistry

• Publication date

  2017-10-11

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1039/c7ob01899aPMID 28933498
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• Recent advances in positional-selective alkenylations: removable guidance for twofold C–H activation

  2017cited by this paper
• A Facile Route to Ortho-Hydroxyanilnes through an IrIII -Catalyzed Direct C-H Amidation of 2-Phenoxypyridines.

  2017cited by this paper
• Cobalt-Catalyzed Selective Synthesis of Isoquinolines Using Picolinamide as a Traceless Directing Group.

  2017cited by this paper
• Iridium(III)-Catalyzed Synthesis of Benzimidazoles via C-H Activation and Amidation of Aniline Derivatives.

  2017cited by this paper
• Rhodium‐Catalyzed Synthesis of Multiaryl‐substituted Naphthols via a Removable Directing Group

  2017cited by this paper
• Transition-metal catalysed C-N bond activation.

  2016cited by this paper
• Iridium(III)-Catalyzed Regioselective C7-Amination of N-Pivaloylindoles with Sulfonoazides.

  2016cited by this paper
• Nickel-Catalyzed C-H Chalcogenation of Anilines.

  2016cited by this paper
• Iridium-Catalyzed Direct ortho-C-H Amidation of Benzaldehydes through N-Sulfonyl Imines as Mask.

  2016cited by this paper
• A General Strategy for the Nickel-Catalyzed C-H Alkylation of Anilines.

  2016cited by this paper
• Mechanochemical Iridium(III)-Catalyzed C-H Bond Amidation of Benzamides with Sulfonyl Azides under Solvent-Free Conditions in a Ball Mill.

  2016cited by this paper
• Nickel-Catalyzed C–H Alkynylation of Anilines: Expedient Access to Functionalized Indoles and Purine Nucleobases

  2016cited by this paper
• Iridium(III)- and rhodium(III)-catalyzed coupling of anilines with α-diazoesters via chelation-assisted C–H activation

  2016cited by this paper
• Catalytic Methods for Aromatic C–H Amination: An Ideal Strategy for Nitrogen-Based Functional Molecules

  2016cited by this paper
• Ir-Catalyzed C-H Amidation of Aldehydes with Stoichiometric/Catalytic Directing Group.

  2016cited by this paper
• Iridium(iii)-catalyzed regioselective C7-sulfonamidation of indoles.

  2016cited by this paper
• Transition Metal-Mediated Direct C-H Amination of Hydrocarbons with Amine Reactants: The Most Desirable but Challenging C-N Bond Formation Approach

  2016cited by this paper
• Multiple Roles of the Pyrimidyl Group in the Rhodium‐Catalyzed Regioselective Synthesis and Functionalization of Indole‐3‐carboxylic Acid Esters

  2016cited by this paper
• Iridium(III)-Catalyzed Regioselective Intermolecular Unactivated Secondary Csp(3) -H Bond Amidation.

  2016cited by this paper
• Iridium(III)-Catalyzed Direct CH Sulfonamidation of 2-Aryl-1,2,3-triazole N-Oxides with Sulfonyl Azides

  2016cited by this paper
• Selective Hydrogenation of Halogenated Nitroaromatics to Haloanilines in Batch and Flow

  2016cited by this paper
• Rhodium(III)-Catalyzed Synthesis of Indole Derivatives From Pyrimidyl-Substituted Anilines and Diazo Compounds

  2016cited by this paper
• A Facile Access to Primary Alkylamines and Anilines via Ir(III)-Catalyzed C–H Amidation Using Azidoformates

  2016cited by this paper
• Palladium(II)-Catalyzed, Heteroatom-Directed, Regioselective C-H Nitration of Anilines Using Pyrimidine as a Removable Directing Group.

  2016cited by this paper
• Rhodium-Catalyzed Selective Mono- and Diamination of Arenes with Single Directing Site "On Water".

  2016cited by this paper
• Efficient and Selective Synthesis of (E)-Enamides via Ru(II)-Catalyzed Hydroamidation of Internal Alkynes

  2016cited by this paper
• Carboxylate-Assisted Iridium-Catalyzed C-H Amination of Arenes with Biologically Relevant Alkyl Azides.

  2016cited by this paper
• A Direct Access to 7-Aminoindoles via Iridium-Catalyzed Mild C-H Amidation of N-Pivaloylindoles with Organic Azides.

  2016cited by this paper
• Reusable directing groups [8-aminoquinoline, picolinamide, sulfoximine] in C(sp3)–H bond activation: present and future

  2015cited by this paper
• Iridium-Catalyzed Direct C-H Sulfamidation of Aryl Nitrones with Sulfonyl Azides at Room Temperature.

  2015cited by this paper
• Iridium(III)‐Catalyzed Benzylic Amine Directed CH Sulfonamidation of Arenes with Sulfonyl Azides

  2015cited by this paper
• N-Acyl Amino Acid Ligands for Ruthenium(II)-Catalyzed meta-C-H tert-Alkylation with Removable Auxiliaries.

  2015cited by this paper
• Direct C-H amidation of benzoic acids to introduce meta- and para-amino groups by tandem decarboxylation.

  2015cited by this paper
• Chemoselective Transfer Hydrogenation of Nitroarenes Catalyzed by Highly Dispersed, Supported Nickel Nanoparticles

  2015cited by this paper
• Transition-metal-catalyzed C-N bond forming reactions using organic azides as the nitrogen source: a journey for the mild and versatile C-H amination.

  2015cited by this paper
• Cobalt(III)-Catalyzed Aryl and Alkenyl C-H Aminocarbonylation with Isocyanates and Acyl Azides.

  2015cited by this paper
• A Cp*CoI2-dimer as a precursor for cationic Co(III)-catalysis: application to C-H phosphoramidation of indoles.

  2015cited by this paper
• In Situ-Generated Co0-Co3O4/N-Doped Carbon Nanotubes Hybrids as Efficient and Chemoselective Catalysts for Hydrogenation of Nitroarenes

  2015cited by this paper
• Reusable and Removable Directing Groups for C(sp2)−H Bond Functionalization of Arenes

  2015cited by this paper
• Copper-catalyzed C(sp2)-H amidation with azides as amino sources.

  2014cited by this paper
• Oxidative C-H amination reactions.

  2014cited by this paper
• Mechanistic studies of the rhodium-catalyzed direct C-H amination reaction using azides as the nitrogen source.

  2014cited by this paper
• Hydrogen-bond-assisted controlled C-H functionalization via adaptive recognition of a purine directing group.

  2014cited by this paper
• Iridium-catalyzed direct C-H amidation with weakly coordinating carbonyl directing groups under mild conditions.

  2014cited by this paper
• Air‐Stable Carbonyl(pentamethylcyclopentadienyl)cobalt Diiodide Complex as a Precursor for Cationic (Pentamethylcyclopentadienyl)cobalt(III) Catalysis: Application for Directed C‐2 Selective CH Amidation of Indoles

  2014cited by this paper
• Arene C-H functionalisation using a removable/modifiable or a traceless directing group strategy.

  2014cited by this paper
• Iridium-catalyzed intermolecular amidation of sp³ C-H bonds: late-stage functionalization of an unactivated methyl group.

  2014cited by this paper
• Orthogonal reactivity of acyl azides in C-H activation: dichotomy between C-C and C-N amidations based on catalyst systems.

  2014cited by this paper
• C-H nitrogenation and oxygenation by ruthenium catalysis.

  2014cited by this paper
• Nanoscale Fe2O3-Based Catalysts for Selective Hydrogenation of Nitroarenes to Anilines

  2013cited by this paper
• Ru(II)-catalyzed intermolecular C-H amidation of weakly coordinating ketones.

  2013cited by this paper
• Expedient C-H amidations of heteroaryl arenes catalyzed by versatile ruthenium(II) catalysts.

  2013cited by this paper
• Rh(III)/Cu(II)-cocatalyzed synthesis of 1H-indazoles through C-H amidation and N-N bond formation.

  2013cited by this paper
• Ruthenium-catalyzed direct C-H amidation of arenes including weakly coordinating aromatic ketones.

  2013cited by this paper
• Sulfoximine directed intermolecular o-C-H amidation of arenes with sulfonyl azides.

  2013cited by this paper
• Ir(III)-catalyzed mild C-H amidation of arenes and alkenes: an efficient usage of acyl azides as the nitrogen source.

  2013cited by this paper
• Developing ligands for palladium(II)-catalyzed C-H functionalization: intimate dialogue between ligand and substrate.

  2013cited by this paper
• Rhodium-catalyzed regioselective amidation of indoles with sulfonyl azides via C-H bond activation.

  2012cited by this paper
• Rhodium-catalyzed direct C-H amination of benzamides with aryl azides: a synthetic route to diarylamines.

  2012cited by this paper
• Cationic ruthenium(II) catalysts for oxidative C-H/N-H bond functionalizations of anilines with removable directing group: synthesis of indoles in water.

  2012cited by this paper
• Rhodium-catalyzed intermolecular amidation of arenes with sulfonyl azides via chelation-assisted C-H bond activation.

  2012cited by this paper
• Synthesis of N-(2-pyridyl)indoles via Pd(II)-catalyzed oxidative coupling.

  2011cited by this paper
• Removable directing groups in organic synthesis and catalysis.

  2011cited by this paper
• Direct amination of aryl halides with ammonia.

  2010cited by this paper
• Ammonia: an environmentally friendly nitrogen source for primary aniline synthesis.

  2010cited by this paper
• Rh(III)-catalyzed oxidative coupling of N-aryl-2-aminopyridine with alkynes and alkenes.

  2010cited by this paper
• Catalytic C-C, C-N, and C-O Ullmann-type coupling reactions.

  2009cited by this paper
• [N,N′-Bis(salicylidene)-1,2-phenylenediamine]metal complexes with cell death promoting properties

  2009cited by this paper
• Biaryl phosphane ligands in palladium-catalyzed amination.

  2008cited by this paper
• Evolution of a fourth generation catalyst for the amination and thioetherification of aryl halides.

  2008cited by this paper
• Copper-mediated coupling reactions and their applications in natural products and designed biomolecules synthesis.

  2008cited by this paper
• The Chemistry of Anilines

  2007cited by this paper
• Parallel and automated library synthesis of 2-long alkyl chain benzoazoles and azole[4,5-b]pyridines under microwave irradiation

  2005cited by this paper
• Amines: Synthesis, Properties and Applications

  2004cited by this paper
• Synthesis of deuterium labelled benomyl and carbendazim residue standards

  2000cited by this paper

• Recent Advances in the Synthesis of Sulfonamides Intermediates

  2023cites this paper
• Recent advances in metal directed C-H amidation/amination using sulfonyl azides and phosphoryl azides.

  2023cites this paper
• Iridium(III)-Catalyzed Branch-Selective C–H Alkenylation of Aniline Derivatives with Alkenes

  2021cites this paper
• Rh(III)-Catalyzed [3 + 2] Annulation of Aniline Derivatives with Vinylsilanes via C–H Activation/Alkene Cyclization: Access to Highly Regioselective Indoline Derivatives

  2021cites this paper
• Pyrimidine-directed metal-free C–H borylation of 2-pyrimidylanilines: a useful process for tetra-coordinated triarylborane synthesis

  2021cites this paper
• The Direct Rh(III)-Catalyzed C-H Amidation of Aniline Derivatives Using a Pyrimidine Directing Group: The Selective Solvent Controlled Synthesis of 1,2-Diaminobenzenes and Benzimidazoles.

  2020cites this paper
• Introducing an α-Keto Ester Functional Group through Pt-Catalyzed Direct C–H Acylation with Ethyl Chlorooxoacetate

  2020cites this paper
• Palladium-catalyzed oxidative homocoupling of 2-arylquinazolinones

  2020cites this paper
• Direct sulfonamidation of (hetero)aromatic C–H bonds with sulfonyl azides: a novel and efficient route to N-(hetero)aryl sulfonamides

  2020cites this paper
• Ligand-Free Palladium(II)-Catalyzed ortho -C-H Chalcogenations of N -Arylsulfonamide via Weak Coordination

  2019cites this paper
• Rh(III)-Catalyzed Sequential C-H Amination/Annulation Cascade Reactions: Synthesis of Multisubstituted Benzimidazoles.

  2019cites this paper
• N-Methoxyamide: An Alternative Amidation Reagent in the Rhodium(III)-Catalyzed C-H Activation.

  2019cites this paper
• A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

  2018cites this paper
• Ir-Catalyzed Intramolecular Transannulation/C(sp2)-H Amination of 1,2,3,4-Tetrazoles by Electrocyclization.

  2018cites this paper
• Iridium(III)‐Catalyzed Regiocontrolled Direct Amidation of Isoquinolones and Pyridones

  2018cites this paper
• Iridium-catalysed direct sulfamidation of quinazolinones

  2018cites this paper
• Synthesis and bioelectrochemical behavior of aromatic amines.

  2017cites this paper