A highly enantioselective approach towards 2-substituted 3-bromopyrrolidines.

No abstract is available for this paper.

• Publication year

  2012

• Venue

  Organic and biomolecular chemistry

• Publication date

  2012-04-24

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1039/c2ob25327ePMID 22437158
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• An enantioselective approach toward 3,4-dihydroisocoumarin through the bromocyclization of styrene-type carboxylic acids.

  2012cited by this paper
• Enantioselective bromocycloetherification by Lewis base/chiral Brønsted acid cooperative catalysis.

  2012cited by this paper
• Organocatalytic asymmetric halogenation/semipinacol rearrangement: highly efficient synthesis of chiral α-oxa-quaternary β-haloketones.

  2011cited by this paper
• Enantioselective bromoaminocyclization using amino-thiocarbamate catalysts.

  2011cited by this paper
• Catalytic asymmetric chloroamination reaction of α,β-unsaturated γ-keto esters and chalcones.

  2011cited by this paper
• Aminothiocarbamate-catalyzed asymmetric bromolactonization of 1,2-disubstituted olefinic acids.

  2011cited by this paper
• Enantioselective haloetherification by asymmetric opening of meso-halonium ions.

  2011cited by this paper
• A catalytic asymmetric chlorocyclization of unsaturated amides.

  2011cited by this paper
• Organocatalyzed enantioselective fluorocyclizations.

  2011cited by this paper
• Current methods for asymmetric halogenation of olefins.

  2011cited by this paper
• Enantioselective bromocyclization of olefins catalyzed by chiral phosphoric acid.

  2011cited by this paper
• Stereospecific ring expansion of chiral vinyl aziridines.

  2011cited by this paper
• Highly enantioselective arylation of N-tosylalkylaldimines catalyzed by rhodium-diene complexes.

  2011cited by this paper
• Asymmetric bromolactonization using amino-thiocarbamate catalyst.

  2010cited by this paper
• Enantioselective bromolactonization of conjugated (Z)-enynes.

  2010cited by this paper
• Pyrrolidine amides of pyrazolodihydropyrimidines as potent and selective KV1.5 blockers.

  2010cited by this paper
• Asymmetric bromolactonization catalyzed by a C3-symmetric chiral trisimidazoline.

  2010cited by this paper
• Catalytic asymmetric bromoamination of chalcones: highly efficient synthesis of chiral alpha-bromo-beta-amino ketone derivatives.

  2010cited by this paper
• Biaryl phosphite-oxazoline ligands from the chiral pool: highly efficient modular ligands for the asymmetric Pd-catalyzed Heck reaction.

  2010cited by this paper
• Enantioselective halocyclization reactions for the synthesis of chiral cyclic compounds.

  2010cited by this paper
• Tertiary aminourea-catalyzed enantioselective iodolactonization.

  2010cited by this paper
• An organocatalytic asymmetric chlorolactonization.

  2010cited by this paper
• A new entry into cis-3-amino-2-methylpyrrolidines via ring expansion of 2-(2-hydroxyethyl)-3-methylaziridines.

  2009cited by this paper
• A dramatic switch of enantioselectivity in asymmetric heck reaction by benzylic substituents of ligands.

  2008cited by this paper
• Design of translactam HCMV protease inhibitors as potent antivirals

  2005cited by this paper
• Catalytic hydroamination of alkynes and norbornene with neutral and cationic tantalum imido complexes.

  2004cited by this paper
• Iodine electrophiles in stereoselective reactions: recent developments and synthetic applications.

  2004cited by this paper
• Highly regio- and enantioselective Heck reaction of N-methoxycarbonyl-2-pyrroline with planar chiral diphosphine-oxazoline ferrocenyl ligands.

  2003cited by this paper
• Ring-closing metathesis of chiral allylamines. Enantioselective synthesis of (2S,3R,4S)-3,4-dihydroxyproline.

  2002cited by this paper
• Entropy-controlled selectivity in the vinylation of a cyclic chiral nitrone. An efficient route to enantiopure polyhydroxylated pyrrolidines.

  2001cited by this paper
• Regioselective Rh-catalyzed allylic amination/ring-closing metathesis approach to monocyclic azacycles: diastereospecific construction of 2,5-disubstituted pyrrolines.

  1999cited by this paper
• Enantiospecific and Stereoselective Synthesis of Polyhydroxylated Pyrrolidines and Indolizidines from trans-4-Hydroxy-L-proline.

  1996cited by this paper

• Asymmetric Iodoaminocyclization for the Synthesis of Chiral 2-Heteroaryl Pyrrolidines.

  2026cites this paper
• Advances in Stereoselective Haloamination of Alkenes

  2025cites this paper
• Progress in Stereoselective Haloamination of Olefins

  2025cites this paper
• Bioinspired Total Synthesis of (+)-α-Tocopherol.

  2025cites this paper
• Chiral Nonaromatic Nitrogen-Heterocycles by Asymmetric Intramolecular Haloamination and Haloamidation

  2024influential citation
• Asymmetric Photoaerobic Lactonization and Aza-Wacker Cyclization of Alkenes Enabled by Ternary Selenium–Sulfur Multicatalysis

  2023cites this paper
• Catalytic Enantioselective 5-Endo-Bromocycloetherification of Unactivated Cyclic Alkenes

  2022cites this paper
• Asymmetric Bromoaminocyclization and Desymmetrization of Cyclohexa-1,4-dienes through Anion Phase-Transfer Catalysis.

  2021cites this paper
• Enantioselective Halofunctionalization of Alkenes

  2021cites this paper
• Recent Developments in Enantioselective Organocatalytic Cascade Reactions for the Construction of Halogenated Ring Systems

  2021cites this paper
• Metal-Free, NIS-Induced Regioselective Iodophosphoryloxylation of Alkenes with P(O)-OH bonds.

  2020cites this paper
• Catalytic Enantioselective Bromoaminocyclization and Bromocycloetherification

  2020cites this paper
• Enantioselective Halolactonizations Using Amino-Acid-Derived Phthalazine Catalysts.

  2019cites this paper
• Enantioselective Syntheses of α‐ exo ‐Methylene‐Lactones via Organocatalytic Halolactonization

  2019cites this paper
• Metal-free intermolecular aminochlorination of unactivated alkenes

  2018cites this paper
• Enantioselective Bromolactonization of Deactivated Olefinic Acids.

  2018cites this paper
• Iron-catalyzed or iodine-induced intramolecular halocyclization of N-vinyl-tethered methylenecyclopropanes: facile access to halogenated 1,2-dihydroquinolines

  2017cites this paper
• Lewis Base Catalyzed Stereo- and Regioselective Bromocyclization.

  2017cites this paper
• Cinchona alkaloid derivatives

  2017cites this paper
• Catalytic Asymmetric Chlorocyclization of 2-Vinylphenylcarbamates for Synthesis of 1,4-Dihydro-2H-3,1-benzoxazin-2-one Derivatives.

  2017cites this paper
• Synthesis of 2-Aryl- and 2-Vinylpyrrolidines via Copper-Catalyzed Coupling of Styrenes and Dienes with Potassium β-Aminoethyl Trifluoroborates.

  2016cites this paper
• Lewis Base Catalysis: A Platform for Enantioselective Addition to Alkenes Using Group 16 and 17 Lewis Acids (n → σ*)

  2016cites this paper
• Squaramide catalyzed enantioselective iodolactonization of allenoic acids

  2016cites this paper
• Cinchona-Alkaloids Based Isoselenazolones: Synthesis and Their Catalytic Reactivity in Asymmetric Bromolactonization of Alkenoic Acid

  2016cites this paper
• X-ray, conformation and electronic structures of 1-nitropyrrolidine

  2016cites this paper
• Exploration of the Bis(thio)urea‐Catalyzed Atropselective Synthesis of Marinopyrrole A

  2016cites this paper
• A convenient method for the synthesis of α-carboxylate ester bromolactones via bromolactonization of alkenoic diesters.

  2016cites this paper
• Use of Bromine and Bromo‐Organic Compounds in Organic Synthesis

  2016cites this paper
• Use of Bromine and Bromo-Organic Compounds in Organic Synthesis.

  2016cites this paper
• Phosphine Oxide-Sc(OTf)3 Catalyzed Highly Regio- and Enantioselective Bromoaminocyclization of (E)-Cinnamyl Tosylcarbamates. An Approach to a Class of Synthetically Versatile Functionalized Molecules.

  2016cites this paper
• Cinchona-Alkaloids Based Isoselenazolones: Synthesis and Their Catalytic Reactivity in Asymmetric Bromolactonization of Alkenoic Acid

  2016cites this paper
• Enantioselective halogenative semi-pinacol rearrangement: extension of substrate scope and mechanistic investigations.

  2015cites this paper
• Catalytic Asymmetric Bromination of Unfunctionalized Olefins with H2O as a Nucleophile.

  2015cites this paper
• Stereoselective Electrophilic Cyclization.

  2015cites this paper
• Highly Stereoselective Intermolecular Haloetherification and Haloesterification of Allyl Amides.

  2015cites this paper
• Enantioselective 6-exo-Bromoaminocyclization of Homoallylic N-Tosylcarbamates Catalyzed by a Novel Monophosphine-Sc(OTf)3 Complex.

  2015cites this paper
• Enantioselective 6-endo bromoaminocyclization of 2,4-dienyl N-tosylcarbamates catalyzed by a chiral phosphine oxide-Sc(OTf)3 complex. A dramatic additive effect.

  2015cites this paper
• Diastereoselectively switchable asymmetric haloaminocyclization for the synthesis of cyclic sulfamates.

  2015cites this paper
• Chiral Phosphine Oxide-Sc(OTf)3 Complex Catalyzed Enantioselective Bromoaminocyclization of 2-Benzofuranylmethyl N-Tosylcarbamates. Approach to a Novel Class of Optically Active Spiro Compounds.

  2015cites this paper
• 7.21 Addition Reactions with Formation of CarbonHalogen Bonds

  2014cites this paper
• One‐Pot Preparation of Enantiopure Fluorinated β‐Amino Acid Precursors

  2014cites this paper
• Cooperative activation with chiral nucleophilic catalysts and N-haloimides: enantioselective iodolactonization of 4-arylmethyl-4-pentenoic acids.

  2014cites this paper
• Desymmetrization of diolefinic diols by enantioselective amino-thiocarbamate-catalyzed bromoetherification: synthesis of chiral spirocycles.

  2014cites this paper
• Cinchona Alkaloids as Organocatalysts in Enantioselective Halofunctionalization of Alkenes and Alkynes

  2014cites this paper
• Recent advances in organocatalytic asymmetric synthesis of polysubstituted pyrrolidines

  2014cites this paper
• Recent advances in asymmetric intra- and intermolecular halofunctionalizations of alkenes.

  2014cites this paper
• Synthesis of chiral butenolides using amino-thiocarbamate-catalyzed asymmetric bromolactonization

  2014cites this paper
• Stereoselective bromofunctionalization of alkenes.

  2014cites this paper
• 3-isothiocyanato oxindoles serving as powerful and versatile precursors to structurally diverse dispirocyclic thiopyrrolidineoxindoles through a cascade Michael/cyclization process with amino-thiocarbamate catalysts.

  2013cites this paper
• Asymmetric Synthesis of 1,3-Oxazolidines via Intramolecular Aza-Michael Addition by Bifunctional Organocatalysts

  2013cites this paper
• Catalytic enantioselective iodoetherification of oximes.

  2013cites this paper
• Asymmetric 5-endo chloroetherification of homoallylic alcohols toward the synthesis of chiral β-chlorotetrahydrofurans.

  2013cites this paper
• Recent Progress in Organocatalytic Asymmetric Halocyclization

  2013cites this paper
• Catalytic Aminohalogenation of Alkenes and Alkynes.

  2013cites this paper
• Catalytic asymmetric bromolactonization reactions using (DHQD)2PHAL-benzoic acid combinations

  2013cites this paper
• Enantioselective, desymmetrizing bromolactonization of alkynes.

  2013cites this paper
• Catalytic, enantioselective, and highly chemoselective bromocyclization of olefinic dicarbonyl compounds.

  2013cites this paper
• Solvent-dependent enantiodivergence in the chlorocyclization of unsaturated carbamates.

  2013cites this paper
• Recent advances in stereoselective bromofunctionalization of alkenes using N-bromoamide reagents.

  2013cites this paper
• Enantioselective synthesis of 2-substituted and 3-substituted piperidines through a bromoaminocyclization process.

  2013cites this paper
• 2-[1′-(Benzyloxy)spiro[indane-1,2′-pyrrolidine]-5′-yl]acetonitrile

  2013cites this paper
• Iron-catalyzed asymmetric haloamination reactions.

  2013cites this paper
• Kinetic resolution of unsaturated amides in a chlorocyclization reaction: concomitant enantiomer differentiation and face selective alkene chlorination by a single catalyst.

  2013cites this paper
• Lewis basic selenium catalyzed chloroamidation of olefins using nitriles as the nucleophiles.

  2013cites this paper
• Enantioselective chlorocyclization of indole derived benzamides for the synthesis of spiro-indolines.

  2013cites this paper
• Enantioselective organocatalytic iodination-initiated Wagner-Meerwein rearrangement.

  2013cites this paper
• C2-symmetric cyclic selenium-catalyzed enantioselective bromoaminocyclization.

  2013cites this paper
• Catalytic, asymmetric halofunctionalization of alkenes--a critical perspective.

  2012cites this paper
• Efficient medium ring size bromolactonization using a sulfur-based zwitterionic organocatalyst.

  2012cites this paper
• Katalytische asymmetrische Halogenfunktionalisierung von Alkenen – eine kritische Betrachtung

  2012cites this paper
• Enantioselective bromolactonization using an S-alkyl thiocarbamate catalyst.

  2012cites this paper
• Opioids as enantioselective organocatalysts

  2012cites this paper
• Enantioselective halocyclization using reagents tailored for chiral anion phase-transfer catalysis.

  2012cites this paper