Determination of polycyclic aromatic hydrocarbons in water samples by gas chromatography coupled to triple quadrupole tandem mass spectrometry using macroporous resin solid-phase extraction.

A method for the determination of 16 polycyclic aromatic hydrocarbons in water has been developed. First, we made a solid-phase extraction column. After this, the parameters affecting the efficacy of the experimental method were optimized, including appropriate selection of a solid-phase extraction column and cleanup conditions on columns. The separation was achieved by gas chromatography and detection with triple quadrupole tandem mass spectrometry. The method showed satisfactory linearity (R2  > 0.999) over the range assayed (0.01-1 μg/mL), and limits of quantification ranging from 0.0011 to 0.0199 μg/L. The recoveries ranged from 83 to 113%. The relative standard deviation is in the range 0.86-3.1%. The results indicated that this method had high selectivity and precision that was suitable for the simultaneous determination of 16 polycyclic aromatic hydrocarbons in water.

• Publication year

  2018

• Venue

  Journal of Separation Science

• Publication date

  2018-06-01

• Fields of study

  Medicine, Chemistry, Environmental Science

• Identifiers
  DOI 10.1002/jssc.201700873PMID 29542250
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

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