Drying suspensions often leave behind complex patterns of particulates, as might be seen in the coffee stains on a table. Here, we consider the dynamics of periodic band or uniform solid film formation on a vertical plate suspended partially in a drying colloidal solution. Direct observations allow us to visualize the dynamics of band and film deposition, where both are made of multiple layers of close packed particles. We further see that there is a transition between banding and filming when the colloidal concentration is varied. A minimal theory of the liquid meniscus motion along the plate reveals the dynamics of the banding and its transition to the filming as a function of the ratio of deposition and evaporation rates. We also provide a complementary multiphase model of colloids dissolved in the liquid, which couples the inhomogeneous evaporation at the evolving meniscus to the fluid and particulate flows and the transition from a dilute suspension to a porous plug. This allows us to determine the c...
Dynamics of evaporative colloidal patterning
C. N. Kaplan,Ning Wu,S. Mandre,J. Aizenberg,L. Mahadevan
Published 2014 in Physics of Fluids
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- Publication year
2014
- Venue
Physics of Fluids
- Publication date
2014-11-23
- Fields of study
Materials Science, Physics
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