Peroxyl Radical Reactions in Water Solution: A Gym for Proton-Coupled Electron-Transfer Theories.

No abstract is available for this paper.

• Publication year

  2016

• Venue

  Chemistry

• Publication date

  2016-06-01

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1002/chem.201504492PMID 27111024
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

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  1997cited by this paper
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  1994cited by this paper
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  1992cited by this paper
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  1992cited by this paper
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  1991cited by this paper
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  1990cited by this paper
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  1990cited by this paper
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  1989cited by this paper
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  1985cited by this paper
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  1981cited by this paper
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  1969cited by this paper
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  1966cited by this paper
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  1961cited by this paper

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