On the Way to a Trisanionic {Cu3 O2 } Core for Oxidase Catalysis: Evidence of an Asymmetric Trinuclear Precursor Stabilized by Perfluoropinacolate Ligands.

No abstract is available for this paper.

• Publication year

  2017

• Venue

  Chemistry

• Publication date

  2017-06-16

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1002/chem.201605926PMID 28236333
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• Small-molecule models of tyrosinase: From ligand hydroxylation to catalytic monooxygenation of external substrates

  2017cited by this paper
• Simplest Monodentate Imidazole Stabilization of the oxy-Tyrosinase Cu2 O2 Core: Phenolate Hydroxylation through a Cu(III) Intermediate.

  2016cited by this paper
• Dioxygen Binding, Activation, and Reduction to H2O by Cu Enzymes.

  2016cited by this paper
• Donor-driven conformational flexibility in a real-life catalytic dicopper(ii) peroxo complex.

  2016cited by this paper
• Catechol oxidase and phenoxazinone synthase: Biomimetic functional models and mechanistic studies

  2016cited by this paper
• LCu(μ-X)2CuL compounds: An induced cuprophilic interaction

  2016cited by this paper
• Hand in Hand: Experimental and Theoretical Investigations into the Reactions of Copper(I) Mono‐ and Bis(guanidine) Complexes with Dioxygen

  2016cited by this paper
• Direct Copper(III) Formation from O2 and Copper(I) with Histamine Ligation.

  2016cited by this paper
• Biomimetic Hydroxylation Catalysis Through Self-Assembly of a Bis(pyrazolyl)methane Copper–Peroxo Complex

  2015cited by this paper
• Selective Aromatic Hydroxylation with Dioxygen and Simple Copper Imine Complexes.

  2015cited by this paper
• The Cu2O2 torture track for a real‐life system: [Cu2(btmgp)2O2]2+ oxo and peroxo species in density functional calculations†

  2015cited by this paper
• Structural and reactivity models for copper oxygenases: cooperative effects and novel reactivities.

  2015cited by this paper
• Efficient Biomimetic Hydroxylation Catalysis with a Bis(pyrazolyl)imidazolylmethane Copper Peroxide Complex.

  2015cited by this paper
• Catalytic oxygenation of various monophenols by copper(I) complexes with bis(pyrazolyl)methane ligands: differences in reactivity

  2015cited by this paper
• Low temperature syntheses and reactivity of Cu2O2 active-site models.

  2015cited by this paper
• Molecular Cu(II)-O-Cu(II) complexes: still waters run deep.

  2014cited by this paper
• Copper active sites in biology.

  2014cited by this paper
• Geometric control of nuclearity in copper(I)/dioxygen chemistry.

  2014cited by this paper
• Methane Activation by Heterogeneous Catalysis

  2014cited by this paper
• Molekulare CuII‐O‐CuII‐Komplexe: Stille Wasser sind tief

  2014cited by this paper
• BOX Ligands in Biomimetic Copper‐Mediated Dioxygen Activation: A Hemocyanin Model

  2014cited by this paper
• Development of the Tricopper Cluster as a Catalyst for the Efficient Conversion of Methane into MeOH

  2014cited by this paper
• Room Temperature Stable Organocuprate Copper(III) Complex

  2013cited by this paper
• Access to a Cu(II)-O-Cu(II) motif: spectroscopic properties, solution structure, and reactivity.

  2013cited by this paper
• K⋅⋅⋅F/O interactions bridge copper(I) fluorinated alkoxide complexes and facilitate dioxygen activation.

  2013cited by this paper
• Back Cover: Catalytic Phenol Hydroxylation with Dioxygen: Extension of the Tyrosinase Mechanism beyond the Protein Matrix (Angew. Chem. Int. Ed. 20/2013)

  2013cited by this paper
• Structural and electronic properties of old and new A2[M(pin(F))2] complexes.

  2013cited by this paper
• Rücktitelbild: Katalytische Phenolhydroxylierung mit Sauerstoff: Substratvielfalt jenseits der Proteinmatrix von Tyrosinase (Angew. Chem. 20/2013)

  2013cited by this paper
• Efficient oxidation of methane to methanol by dioxygen mediated by tricopper clusters.

  2013cited by this paper
• High-spin square-planar Co(II) and Fe(II) complexes and reasons for their electronic structure.

  2012cited by this paper
• Synthesis, magnetostructural correlation, and catalytic promiscuity of unsymmetric dinuclear copper(II) complexes: models for catechol oxidases and hydrolases.

  2012cited by this paper
• Dioxygen activation of a trinuclear Cu(I)Cu(I)Cu(I) cluster capable of mediating facile oxidation of organic substrates: competition between O-atom transfer and abortive intercomplex reduction.

  2012cited by this paper
• Cu(I)/O2 chemistry using a β-diketiminate supporting ligand derived from N,N-dimethylhydrazine: a [Cu3O2]3+ complex with novel reactivity.

  2012cited by this paper
• Copper-Oxygen Chemistry: Karlin/Copper-Oxygen Chemistry

  2011cited by this paper
• Copper dioxygen (bio)inorganic chemistry.

  2011cited by this paper
• Synthesis with structural and electronic characterization of homoleptic Fe(II)- and Fe(III)-fluorinated phenolate complexes.

  2011cited by this paper
• A thorough benchmark of density functional methods for general main group thermochemistry, kinetics, and noncovalent interactions.

  2011cited by this paper
• Copper-O2 reactivity of tyrosinase models towards external monophenolic substrates: molecular mechanism and comparison with the enzyme.

  2011cited by this paper
• Effect of the damping function in dispersion corrected density functional theory

  2011cited by this paper
• Three-coordinate late transition metal fluorinated alkoxide complexes.

  2010cited by this paper
• Das erste katalytische Tyrosinasemodell basierend auf einem einkernigen Kupfer(I)‐Komplex: Kinetik und Mechanismus

  2010cited by this paper
• The first catalytic tyrosinase model system based on a mononuclear copper(I) complex: kinetics and mechanism.

  2010cited by this paper
• Bis(μ-oxo) dicopper(III) species of the simplest peralkylated diamine: enhanced reactivity toward exogenous substrates.

  2010cited by this paper
• Synthesis and electronic spectra of fluorinated aryloxide and alkoxide [NiX(4)](2-) anions.

  2009cited by this paper
• A [Cu2O]2+ core in Cu-ZSM-5, the active site in the oxidation of methane to methanol

  2009cited by this paper
• Catechol oxidase activity of a series of new dinuclear copper(II) complexes with 3,5-DTBC and TCC as substrates: syntheses, X-ray crystal structures, spectroscopic characterization of the adducts and kinetic studies.

  2008cited by this paper
• A short history of SHELX.

  2008cited by this paper
• Effect of water on the catalytic oxidation of catechols.

  2008cited by this paper
• Controlled oxidation of hydrocarbons by the membrane-bound methane monooxygenase: the case for a tricopper cluster.

  2008cited by this paper
• Electronic structure of the peroxy intermediate and its correlation to the native intermediate in the multicopper oxidases: insights into the reductive cleavage of the o-o bond.

  2007cited by this paper
• Facile O-atom insertion into CC and CH bonds by a trinuclear copper complex designed to harness a singlet oxene

  2007cited by this paper
• Mononuclear Cu-O2 complexes: geometries, spectroscopic properties, electronic structures, and reactivity.

  2007cited by this paper
• Oxidation of phenol and hydroquinone catalysed by copper(II) and oxovanadium(IV) complexes of N,N′-bis(salicyledene)diethylenetriamine (H2saldien) covalently bonded to chloromethylated polystyrene

  2007cited by this paper
• Copper-dioxygen adducts and the side-on peroxo dicopper(II)/bis(mu-oxo) dicopper(III) equilibrium: Significant ligand electronic effects.

  2006cited by this paper
• Ligand Influences in Copper-Dioxygen Complex-Formation and Substrate Oxidations

  2006cited by this paper
• Thallophilic interactions in aryloxide compounds: the [Tl2(mu2-OAr)4] structural motif in (TlOAr)4 and Tl2Cu(OAr)4 compounds.

  2006cited by this paper
• Selective oxidation of methane by the bis(mu-oxo)dicopper core stabilized on ZSM-5 and mordenite zeolites.

  2005cited by this paper
• Bis(mu-oxo)dicopper(III) complexes of a homologous series of simple peralkylated 1,2-diamines: steric modulation of structure, stability, and reactivity.

  2005cited by this paper
• Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy.

  2005cited by this paper
• Tyrosinase Reactivity in a Model Complex: An Alternative Hydroxylation Mechanism

  2005cited by this paper
• Reactivity of dioxygen-copper systems.

  2004cited by this paper
• Structure and spectroscopy of copper-dioxygen complexes.

  2004cited by this paper
• Homoleptic cobalt and copper phenolate A2[M(OAr)4] compounds: the effect of phenoxide fluorination.

  2004cited by this paper
• Complexity with simplicity: a steric continuum of chelating diamines with copper(I) and dioxygen

  2003cited by this paper
• Climbing the density functional ladder: nonempirical meta-generalized gradient approximation designed for molecules and solids.

  2003cited by this paper
• Snapshots of dioxygen activation by copper: the structure of a 1:1 Cu/O(2) adduct and its use in syntheses of asymmetric Bis(mu-oxo) complexes.

  2002cited by this paper
• The EPR spectrum of a Cu(II/II/III) cluster: anisotropic exchange in a bent Cu(II)2O2 core

  2002cited by this paper
• Fine-tuning of copper(I)-dioxygen reactivity by 2-(2-pyridyl)ethylamine bidentate ligands.

  2002cited by this paper
• Resonance Raman spectroscopy as a probe of the bis(μ-oxo)dicopper core

  2000cited by this paper
• Reactivity of Copper(I) Complexes Towards Dioxygen

  2000cited by this paper
• Exogenous Substrate Reactivity with a [Cu(III)2O2]2+ Core: Structural Implications

  1999cited by this paper
• Electronic and Geometric Structure of a Trinuclear Mixed-Valence Copper(II,II,III) Cluster

  1998cited by this paper
• Tuning the Structure and Reactivity of the [Cu2(μ‐O)2]2+ Core: Characterization of a New Bis(μ‐oxo)dicopper Complex Stabilized by a Sterically Hindered Dinucleating Bis(triazacylononane) Ligand

  1997cited by this paper
• Struktur und Stabilität der [Cu2(μ‐O)2]2+‐Einheit: Stabilisierung einer neuen Bis(μ‐oxo)‐dikupfer‐Struktur durch einen sterisch gehinderten, zweikernige Komplexe bildenden Bis(triazacyclononan)‐Liganden

  1997cited by this paper
• Mechanisms Whereby Mononuclear Copper Proteins Functionalize Organic Substrates.

  1996cited by this paper
• Structural, Spectroscopic, and Theoretical Characterization of Bis(μ-oxo)dicopper Complexes, Novel Intermediates in Copper-Mediated Dioxygen Activation

  1996cited by this paper
• Reversible Cleavage and Formation of the Dioxygen O-O Bond Within a Dicopper Complex

  1996cited by this paper
• Mechanistic Study of the Oxidative N-Dealkylation Reactions of Bis(μ-oxo)dicopper Complexes

  1996cited by this paper
• Multicopper Oxidases and Oxygenases.

  1996cited by this paper
• A Trinuclear Intermediate in the Copper-Mediated Reduction of O2: Four Electrons from Three Coppers

  1996cited by this paper
• A Monomeric Side-On Superoxocopper(II) Complex: Cu(O2)(HB(3-tBu-5-iPrpz)3)

  1994cited by this paper
• Copper-Dioxygen Complexes. Inorganic and Bioinorganic Perspectives

  1994cited by this paper
• The stoichiometric and catalytic oxidation of various substrates with a novel macrocyclic binuclear copper(I) dioxygen complex as an intermediate

  1992cited by this paper
• X-ray crystal structure of the blue oxidase ascorbate oxidase from zucchini. Analysis of the polypeptide fold and a model of the copper sites and ligands.

  1989cited by this paper
• A Cu2-O2 Complex. Crystal Structure and Characterization of a Reversible Dioxygen Binding System

  1988cited by this paper
• Preparation of thermally stable and soluble mesitylcopper(I) and its application in organic synthesis

  1981cited by this paper

• 93Nb NMR Characterization of Nb(V) Perfluoropinacolate Complexes and Their Reactivity

  2025cites this paper
• Copper–oxygen adducts: new trends in characterization and properties towards C–H activation

  2024cites this paper
• Synthesis, Structure, and Reactivity of Ruthenium Perfluoropinacolate Complexes#

  2024cites this paper
• Synthesis, Characterization, and the Effect of Lewis Bases on the Nuclearity of Iron Alkoxide Complexes

  2024cites this paper
• Synthesis and structure of a new bulky bis(alkoxide) ligand on a terphenyl platform

  2022cites this paper
• From Gas Phase Observations to Solid State Reality: The Identification and Isolation of Trinuclear Salicylaldoximato Copper Complexes

  2022cites this paper
• Luminescence of Lanthanide Complexes with Perfluorinated Alkoxide Ligands.

  2020cites this paper
• Phosphine ligands as protecting groups for 3d complexes in oxidation by O2

  2020cites this paper
• Formation of monomeric Sn(II) and Sn(IV) perfluoropinacolate complexes and their characterization by 119Sn Mössbauer and 119Sn NMR spectroscopies.

  2020cites this paper
• Group-transfer chemistry at transition metal centers in bulky alkoxide ligand environments

  2019cites this paper
• Tyrosinase Models: Synthesis, Spectroscopy, Theory and Catalysis

  2019cites this paper
• Dual oxidase/oxygenase reactivity and resonance Raman spectra of {Cu3O2} moiety with perfluoro-t-butoxide ligands.

  2019cites this paper
• Cu(i)-O2 oxidation reactions in a fluorinated all-O-donor ligand environment.

  2019cites this paper
• Description of Disperse Multiphase Processes: Quo Vadis?

  2018cites this paper
• Synthesis of a new highly-fluorinated cis-1,2-cyclopentanediol and its application for fluorinated oligoesters

  2018cites this paper
• Relativistic effects at the Cu2O2 core - a density functional theory study.

  2017cites this paper