Methodologies to determine b-term coefficients revisited.

No abstract is available for this paper.

• Publication year

  2018

• Venue

  Journal of Chromatography A

• Publication date

  2018-01-12

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1016/j.chroma.2017.11.070PMID 29221865
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• Assessment of intra-particle diffusion in hydrophilic interaction liquid chromatography and reversed-phase liquid chromatography under conditions of identical packing structure.

  2017cited by this paper
• Advances in Ultrahigh-Pressure Liquid Chromatography Technology and System Design.

  2016cited by this paper
• Rationale behind the optimum efficiency of columns packed with new 1.9μm fully porous particles of narrow particle size distribution.

  2016cited by this paper
• Evaluation of the Kinetic Performance Differences between Hydrophilic-Interaction Liquid Chromatography and Reversed-Phase Liquid Chromatography under Conditions of Identical Packing Structure.

  2015cited by this paper
• Rapid development of core-shell column technology: accurate measurements of the intrinsic column efficiency of narrow-bore columns packed with 4.6 down to 1.3 μm superficially porous particles.

  2014cited by this paper
• Practical observations on the performance of bare silica in hydrophilic interaction compared with C18 reversed-phase liquid chromatography.

  2014cited by this paper
• Recent innovations in UHPLC columns and instrumentation

  2014cited by this paper
• Pushing the performance limits of reversed-phase ultra high performance liquid chromatography with 1.3μm core-shell particles.

  2013cited by this paper
• Speed-resolution properties of columns packed with new 4.6 μm Kinetex-C(18) core-shell particles.

  2013cited by this paper
• Mass transfer mechanism in hydrophilic interaction chromatography.

  2013cited by this paper
• Mass transfer kinetics, band broadening and column efficiency.

  2012cited by this paper
• Calculation of the geometrical three-point parameter constant appearing in the second order accurate effective medium theory expression for the B-term diffusion coefficient in fully porous and porous-shell random sphere packings.

  2012cited by this paper
• Shell particles, trials, tribulations and triumphs.

  2011cited by this paper
• Experimental investigation of the difference in B-term dominated band broadening between fully porous and porous-shell particles for liquid chromatography using the Effective Medium Theory.

  2011cited by this paper
• Accurate measurements of peak variances: importance of this accuracy in the determination of the true corrected plate heights of chromatographic columns.

  2011cited by this paper
• 1.1 μm superficially porous particles for liquid chromatography. Part I: synthesis and particle structure characterization.

  2011cited by this paper
• A protocol for the measurement of all the parameters of the mass transfer kinetics in columns used in liquid chromatography.

  2010cited by this paper
• Detailed characterisation of the flow resistance of commercial sub-2 micrometer reversed-phase columns.

  2008cited by this paper
• Detailed characterisation of the flow resistance of commercial sub-2 μm reversed-phase columns

  2008cited by this paper
• Equivalence of the different Cm- and Cs-term expressions used in liquid chromatography and a geometrical model uniting them.

  2008cited by this paper
• Kinetic plot method as a tool to design coupled column systems producing 100,000 theoretical plates in the shortest possible time.

  2008cited by this paper
• Errors involved in the existing B-term expressions for the longitudinal diffusion in fully porous chromatographic media Part I: computational data in ordered pillar arrays and effective medium theory.

  2008cited by this paper
• Peak parking-moment analysis. A strategy for the study of the mass-transfer kinetics in the stationary phase.

  2007cited by this paper
• Effect of the surface coverage of C18-bonded silica particles on the obstructive factor and intraparticle diffusion mechanism

  2006cited by this paper
• Ultra performance liquid chromatography: tomorrow's HPLC technology today

  2004cited by this paper
• Effect of temperature in reversed phase liquid chromatography.

  2004cited by this paper
• Band dispersion in chromatography--a universal expression for the contribution from the mobile zone.

  2002cited by this paper
• HPLC Columns: Theory, Technology, and Practice

  1997cited by this paper
• Accuracy of empirical correlations for estimating diffusion coefficients in aqueous organic mixtures.

  1997cited by this paper
• Study of physico-chemical properties of some packing materials: I. Measurements of the external porosity of packed columns by inverse size-exclusion chromatography

  1996cited by this paper
• B and C terms in the Van Deemter equation for liquid chromatography

  1983cited by this paper
• A New Gas Chromatographic Method for Measuring Gaseous Diffusion Coefficients and Obstructive Factors.

  1964influential reference

• Mechanistic insights into band broadening in MOF-based liquid chromatography: Role of sub-nanopore diffusion and packing heterogeneity.

  2025cites this paper
• Mass transfer resistance in the mobile phase: Theory, data, and strategies to further improve the resolution power in pressure-driven liquid chromatography.

  2025cites this paper
• A Hierarchical Model for Longitudinal and Intraparticle Diffusion Coefficients in Liquid Chromatography

  2025cites this paper
• A logarithmic law for the velocity- and retention-dependency of the eddy dispersion in chromatographic columns.

  2024cites this paper
• Multiscale simulation of liquid chromatography: Effective diffusion in macro-mesoporous beds and the B-term of the plate height equation.

  2024cites this paper
• Novel insights into the dependence of adsorption-desorption kinetics on particle geometry in chiral chromatography

  2024cites this paper
• When van Deemter Goes Upside Down in Chiral Chromatography

  2023cites this paper
• Detailed analysis of the effective and intra-particle diffusion coefficient of proteins at elevated pressure in columns packed with wide-pore core-shell particles.

  2023cites this paper
• Review of recent insights in the measurement and modelling of the B-term dispersion and related mass transfer properties in liquid chromatography.

  2022cites this paper
• On the occurrence of very low intra-particle diffusion rates in zwitterionic hydrophilic interaction liquid chromatography polymer columns.

  2022cites this paper
• Taylor-Aris methodology for the experimental determination of molecular diffusion coefficients: Tutorial with focus on large biomolecules.

  2021cites this paper
• Performance of functionalized monolithic silica capillary columns with different mesopore sizes using radical polymerization of octadecyl methacrylate.

  2021cites this paper
• Detailed numerical analysis of the effect of radial column heterogeneities on peak parking experiments with slowly diffusing analytes.

  2021cites this paper
• Experimental diffusivity of energetic compounds determined by peak parking.

  2021cites this paper
• Experimental investigation of the retention factor dependency of eddy dispersion in packed bed columns and relation to knox's empirical model parameters.

  2020cites this paper
• Measurement and modelling of the intra-particle diffusion and b-term in reversed-phase liquid chromatography.

  2020cites this paper
• A Methodology for the Estimation and Modelling of the Obstruction Factor in the Expression for Mesopore Diffusion in Reversed-Phase Liquid Chromatography Particles.

  2020cites this paper
• The checkerboard model for the Eddy-dispersion in Laminar flows through porous media. Part II: Application to ordered and disordered 2-D flow systems.

  2020cites this paper
• Investigation of mass transfer properties and kinetic performance of high-efficiency columns packed with C18 sub-2μm fully- and superficially porous particles.

  2020cites this paper
• Reduction of the extra-column band dispersion by a slow transport of a sample band from the injector to the column in isocratic reversed-phase liquid chromatography.

  2018cites this paper
• Detailed efficiency analysis of columns with a different packing quality and confirmation via total pore blocking.

  2018cites this paper