Rhodium-catalyzed diarylation of oxalates using arylboron compounds.

Dialkyl oxalates undergo selective diarylation on one of their carbonyl carbons upon treatment with arylboron reagents in the presence of a rhodium catalyst to give the corresponding alpha-hydroxydiarylacetates. Under similar conditions, the arylation of benzoylformate and benzil also proceeds efficiently.

• Publication year

  2007

• Venue

  Journal of Organic Chemistry

• Publication date

  2007-02-20

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1021/JO062628JPMID 17309312
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

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