Free radical reaction promoted by ionic liquid: a route for metal-free oxidation depolymerization of lignin model compound and lignin.

No abstract is available for this paper.

• Publication year

  2015

• Venue

  Chemical Communications

• Publication date

  2015-02-19

• Fields of study

  Medicine, Materials Science, Chemistry, Environmental Science

• Identifiers
  DOI 10.1039/c4cc10394gPMID 25661479
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• Large-scale production of high-quality graphene using glucose and ferric chloride

  2014cited by this paper
• A Mechanistic Investigation of Acid-Catalyzed Cleavage of Aryl-Ether Linkages: Implications for Lignin Depolymerization in Acidic Environments

  2014cited by this paper
• Titanium nitride-nickel nanocomposite as heterogeneous catalyst for the hydrogenolysis of aryl ethers.

  2014cited by this paper
• A photochemical strategy for lignin degradation at room temperature.

  2014cited by this paper
• One-step synthesis of highly efficient nanocatalysts on the supports with hierarchical pores using porous ionic liquid-water gel.

  2014cited by this paper
• Lignin Valorization: Improving Lignin Processing in the Biorefinery

  2014cited by this paper
• Gas solubility in ionic liquids.

  2014cited by this paper
• Unprecedented organocatalytic reduction of lignin model compounds to phenols and primary alcohols using hydrosilanes.

  2014cited by this paper
• Plant biomass fractionation meets catalysis.

  2014cited by this paper
• Review: Oxidation of Lignin Using Ionic Liquids—An Innovative Strategy To Produce Renewable Chemicals

  2014cited by this paper
• An efficient cleavage of the aryl ether C-O bond in supercritical carbon dioxide-water.

  2013cited by this paper
• The pyrolysis chemistry of a β-O-4 type oligomeric lignin model compound

  2013cited by this paper
• Green carbon science: scientific basis for integrating carbon resource processing, utilization, and recycling.

  2013cited by this paper
• Catalytic cleavage of lignin β-O-4 link mimics using copper on alumina and magnesia–alumina

  2013cited by this paper
• Aerobic Oxidation of β-1 Lignin Model Compounds with Copper and Oxovanadium Catalysts

  2013cited by this paper
• Aqueous Phase Hydroalkylation and Hydrodeoxygenation of Phenol by Dual Functional Catalysts Comprised of Pd/C and H/La-BEA

  2012cited by this paper
• Synthesis of palladium nanoparticles supported on mesoporous N-doped carbon and their catalytic ability for biofuel upgrade.

  2012cited by this paper
• C-C or C-O bond cleavage in a phenolic lignin model compound: selectivity depends on vanadium catalyst.

  2012cited by this paper
• Hydrogenolysis of lignosulfonate into phenols over heterogeneous nickel catalysts.

  2012cited by this paper
• Ni-catalyzed cleavage of aryl ethers in the aqueous phase.

  2012cited by this paper
• Electro-catalytic oxidative cleavage of lignin in a protic ionic liquid.

  2012cited by this paper
• Hydrolytic Cleavage of β-O-4 Ether Bonds of Lignin Model Compounds in an Ionic Liquid with Metal Chlorides

  2011cited by this paper
• Hydrodeoxygenation of phenols as lignin models under acid-free conditions with carbon-supported platinum catalysts.

  2011cited by this paper
• In situ spectroscopic investigation of the cobalt-catalyzed oxidation of lignin model compounds in ionic liquids

  2011cited by this paper
• Comparison of Copper and Vanadium Homogeneous Catalysts for Aerobic Oxidation of Lignin Models

  2011cited by this paper
• Selective, Nickel-Catalyzed Hydrogenolysis of Aryl Ethers

  2011cited by this paper
• The catalytic valorization of lignin for the production of renewable chemicals.

  2010cited by this paper
• Catalytic C-O bond cleavage of 2-aryloxy-1-arylethanols and its application to the depolymerization of lignin-related polymers.

  2010cited by this paper
• Non-oxidative vanadium-catalyzed C-O bond cleavage: application to degradation of lignin model compounds.

  2010cited by this paper
• Reaction of singlet oxygen with thioanisole in ionic liquid-acetonitrile binary mixtures.

  2010cited by this paper
• Transition metal catalyzed oxidation of Alcell lignin, soda lignin, and lignin model compounds in ionic liquids

  2010cited by this paper
• Single step synthesis of 4-hydroxybenzophenone via esterification and Fries rearrangement: Novelty of cesium substituted heteropoly acid supported on clay

  2008cited by this paper
• Theoretical Study on the Dark Oxidation Reaction Mechanism of Ethers

  2006cited by this paper
• Methyltrioxorhenium: a new catalyst for the activation of hydrogen peroxide to the oxidation of lignin and lignin model compounds.

  2005cited by this paper
• Review of current and future softwood kraft lignin process chemistry

  2004cited by this paper
• Ionic Liquids-New "Solutions" for Transition Metal Catalysis.

  2000cited by this paper
• Room-temperature ionic liquids: solvents for synthesis and catalysis. 2.

  1999cited by this paper
• Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis.

  1999cited by this paper
• Diels-Alder reactions in room-temperature ionic liquids

  1999cited by this paper
• Hydrous pyrolysis of polycyclic aromatic hydrocarbons and implications for the origin of PAH in hydrothermal petroleum.

  1999cited by this paper
• Steam-assisted biomass fractionation. I. Process considerations and economic evaluation

  1998cited by this paper
• Quantitative measurement of superoxide generation using the spin trap 5-(diethoxyphosphoryl)-5-methyl-1-pyrroline-N-oxide.

  1997cited by this paper
• Supporting Information for Chemoselective Metal-free Aerobic Alcohol Oxidation in Lignin Synthesis of Lignin Model Compounds S1 Iii. Catalyst Screening and Optimization Data S3 1-oxidation with Traditional Chemical Oxidants S3 2-catalytic Aerobic Oxidation of Model Compound S6 A) Metal-catalyzed Aer

  year unknowncited by this paper

• Chemistry of lignin and condensed tannins as aromatic biopolymers.

  2025cites this paper
• Strategies Toward Synthesis and Conversion of Lignin Model Compounds

  2025cites this paper
• Recent Advances in the Use of Ionic Liquids and Deep Eutectic Solvents for Lignocellulosic Biorefineries and Biobased Chemical and Material Production

  2025cites this paper
• Recent advances, challenges, and opportunities in lignin valorization for value-Added chemicals, biofuels, and polymeric materials

  2024cites this paper
• Electrocatalytic Cleavage of C–C Bonds in Lignin Models Using Nonmetallic Catalysts at Ambient Conditions

  2024cites this paper
• Oxidative Cleavage of α-O-4, β-O-4, and 4-O-5 Linkages in Lignin Model Compounds over P, N Co-doped Carbon Catalyst: A Metal-free Approach.

  2024cites this paper
• Catalytic Strategies and Mechanism Analysis Orbiting the Center of Critical Intermediates in Lignin Depolymerization.

  2023cites this paper
• Enhanced oxidative depolymerization of lignin in cooperative imidazolium-based ionic liquid binary mixtures.

  2022cites this paper
• Capitalizing on lignin and tannin value

  2021cites this paper
• Palladium-catalyzed synthesis of 4-cyclohexylmorpholines from reductive coupling of aryl ethers and lignin model compounds with morpholines

  2021cites this paper
• Transformations of Less-Activated Phenols and Phenol Derivatives via C-O Cleavage.

  2020cites this paper
• Cleavage of aryl–ether bonds in lignin model compounds using a Co–Zn-beta catalyst

  2020cites this paper
• Downstream processing of lignin derived feedstock into end products.

  2020cites this paper
• Two Heads are Better than One：Weak Bonds Joint Effects Catalyze the Cleavage of Strong C-C Bond of Lignin-Inspired Compounds and Lignin in Air by Ionic Liquids.

  2020cites this paper
• Hydrogen bond promoted thermal stability enhancement of acetate based ionic liquid

  2020cites this paper
• Green and sustainable route for oxidative depolymerization of lignin: New platform for fine chemicals and fuels

  2020cites this paper
• Ionic liquid catalysed aerobic oxidative amidation and thioamidation of benzylic amines under neat conditions

  2019cites this paper
• Aerobic conversion of benzylic sp3 C–H in diphenylmethanes and benzyl ethers to CO bonds under catalyst-, additive- and light-free conditions

  2019cites this paper
• Metal-Free Photochemical Degradation of Lignin-Derived Aryl Ethers and Lignin by Autologous Radicals via Ionic Liquids Induction.

  2019cites this paper
• Whole utilization of lignocellulose upon ionic liquid POMs in one-pot three-step conversion.

  2019cites this paper
• Aerobic Oxidative C(CO)–C Bond Cleavage under Catalyst‐Free and Additive‐Free Conditions

  2019cites this paper
• Depolymerization of Lignin by Catalytic Oxidation in Ionic Liquids

  2019cites this paper
• Cleavage of lignin model compounds and ligninox using aqueous oxalic acid.

  2019cites this paper
• Recent progress in the thermal and catalytic conversion of lignin

  2019cites this paper
• Transforming technical lignins to structurally defined star-copolymers under ambient conditions

  2019cites this paper
• Gold nanoparticles stabilized by graphene quantum dots as catalysts for C C bond cleavage in β-O-4 lignin model compounds

  2019cites this paper
• Cobalt Nanoparticles Embedded in N‐Doped Porous Carbon Derived from Bimetallic Zeolitic Imidazolate Frameworks for One‐Pot Selective Oxidative Depolymerization of Lignin

  2019cites this paper
• Spectroscopic Investigation of Thermochemical Depolymerization of Lignin Model Compounds in the Presence of Novel Liquidlike Nanoparticle Organic Hybrid Solvents for Efficient Biomass Valorization

  2018cites this paper
• High Catalytic Efficiency of Lignin Depolymerization over Low Pd-Zeolite Y Loading at Mild Temperature

  2018cites this paper
• Depolymerization and activation of lignin: current state of knowledge and perspectives

  2018cites this paper
• Alkaline oxidative cracking for effective depolymerization of biorefining lignin to mono-aromatic compounds and organic acids with molecular oxygen

  2018cites this paper
• Fluorine-functionalized ionic liquids with high oxygen solubility

  2018cites this paper
• Novel Synthesis of Immobilized Brønsted‐ Acidic Ionic Liquid: Application in Lignin Depolymerization

  2018cites this paper
• Transformation of lignin model compounds to N-substituted aromatics via Beckmann rearrangement

  2018cites this paper
• Covalent triazine framework catalytic oxidative cleavage of lignin models and organosolv lignin

  2018cites this paper
• Selective hydrodeoxygenation of lignin β-O-4 model compounds and aromatic ketones promoted by palladium chloride with acidic CO2/MeOH system

  2018cites this paper
• Opportunities of Ionic Liquids for Lignin Utilization from Biorefinery

  2018cites this paper
• A green approach for the synthesis of novel Ag3PO4/SnO2/porcine bone and its exploitation as a catalyst in the photodegradation of lignosulfonate into alkyl acids

  2018cites this paper
• Highly selective catalytic conversion of lignin-derived phenolic compounds to cycloalkanes over a hierarchically structured zeolite catalyst

  2018cites this paper
• Bright Side of Lignin Depolymerization: Toward New Platform Chemicals

  2018cites this paper
• Depolymerization of Lignin to Aromatics by Selectively Oxidizing Cleavage of C–C and C–O Bonds Using CuCl2/Polybenzoxazine Catalysts at Room Temperature

  2017cites this paper
• Acid promoted C–C bond oxidative cleavage of β-O-4 and β-1 lignin models to esters over a copper catalyst

  2017cites this paper
• Ionic liquids: Promising green solvents for lignocellulosic biomass utilization

  2017cites this paper
• Sustainable Electrochemical Depolymerization of Lignin in Reusable Ionic Liquids

  2017cites this paper
• Catalytic Transformation of Lignocellulose into Chemicals and Fuel Products in Ionic Liquids.

  2017cites this paper
• Depolymerization of Lignin with Nanoporous Catalysts

  2017cites this paper
• Ionic liquid [OMIm][OAc] directly inducing oxidation cleavage of the β-O-4 bond of lignin model compounds.

  2017cites this paper
• Syntheses and crystal structures of benzene-sulfonate and -carboxylate copper polymers and their application in the oxidation of cyclohexane in ionic liquid under mild conditions.

  2016cites this paper
• Paving the Way for Lignin Valorisation: Recent Advances in Bioengineering, Biorefining and Catalysis

  2016cites this paper
• Nanoscale Disassembly and Free Radical Reorganization of Polydopamine in Ionic Liquids.

  2016cites this paper
• Conversion of lignin model compounds under mild conditions in pseudo-homogeneous systems

  2016cites this paper
• A comparison of the oxidation of lignin model compounds in conventional and ionic liquid solvents and application to the oxidation of lignin

  2016cites this paper
• Wege zur Verwertung von Lignin: Fortschritte in der Biotechnik, der Bioraffination und der Katalyse

  2016cites this paper
• Biomass-Derived γ-Valerolactone-Based Solvent Systems for Highly Efficient Dissolution of Various Lignins: Dissolution Behavior and Mechanism Study

  2016cites this paper
• Ionic liquids catalyzed lignin liquefaction: mechanistic studies using TPO-MS, FT-IR, RAMAN and 1D, 2D-HSQC/NOSEY NMR

  2016cites this paper
• Ionic liquids and supercritical carbon dioxide: green and alternative reaction media for chemical processes

  2016cites this paper