Highly Stereoselective Kinetic Enolate Formation: Steric vs Electronic Effects.

No abstract is available for this paper.

• Publication year

  1997

• Venue

  Journal of Organic Chemistry

• Publication date

  1997-10-17

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1021/JO971260APMID 11671880
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• Potentially carcinogenic analogues of the carcinogen hexamethylphosphoramide: evaluation in vitro.

  1978cited by this paper
• Selection of an in vitro carcinogenicity test for derivatives of the carcinogen hexamethylphosphoramide.

  1977cited by this paper
• Hexamethylphosphoric triamide (HMPA).

  1975cited by this paper

• Organocatalytic enantioselective decarboxylative protonation of α-alkyl-α-aryl malonate monoesters.

  2024cites this paper
• Sodium Isopropyl(trimethylsilyl)amide: A Stable and Highly Soluble Lithium Diisopropylamide Mimic.

  2022cites this paper
• A unified approach for divergent synthesis of contiguous stereodiads employing a small boronyl group

  2020cites this paper
• 1,2-Anti aldol methodologies used in natural product synthesis

  2020cites this paper
• Total syntheses of caloundrin B and its putative precursor, and their transformations into siphonarin B, baconipyrone A, and baconipyrone C

  2019cites this paper
• Green Synthetic Methodology of (E)-2-cyano-3-aryl Selective Knoevenagel Adducts Under Microwave Irradiation

  2019cites this paper
• Scalable synthesis of enaminones utilizing Gold's reagents.

  2017cites this paper
• Lithium tert‐Butyl(trimethylsilyl)amide

  2016cites this paper
• Disconnection with Participation of Two Functional Groups

  2016cites this paper
• Kinetic resolution in the [2+2] cycloaddition of ketenes: an experimental and theoretical study.

  2015cites this paper
• General Methods for the Preparation of Enolates

  2015cites this paper
• A systematic study of the effects of relative configuration, protecting group, and enolate type on the diastereoselectivities of aldol reactions of a chiral ethyl ketone with 2-methylpropanal.

  2014cites this paper
• Asymmetric synthesis of chloroisothreonine derivatives via syn-stereoselective Mannich-type additions across N-sulfinyl-α-chloroimines.

  2014cites this paper
• Structures of lithium N-monosubstituted anilides: trisolvated monomer to tetrasolvated dimer.

  2014cites this paper
• Stereoselective synthesis of either (E)- or (Z)-silyl enol ether from the same acyclic α,β-unsaturated ketone using cationic rhodium complex-catalyzed 1,4-hydrosilylation

  2014cites this paper
• Symmetry-Driven Total Synthesis of Merrilactone A and Resolvin E2

  2013cites this paper
• Base-catalyzed Mukaiyama-type aldol additions, a continued quest for stereoselectivity

  2013cites this paper
• Asymmetric induction via short-lived chiral enolates with a chiral C-O axis.

  2013cites this paper
• Organosilicon and Relating Organotin Chemistry

  2013cites this paper
• On the origin of siphonariid polypropionates: total synthesis of caloundrin B and its isomerization to siphonarin B.

  2012cites this paper
• Survey of Synthetic Approaches to Natural (Peyssonenynes) and Unnatural Acetoxyenediynes

  2012cites this paper
• Acid-Base Properties of Enols and Enolates

  2010cites this paper
• Structural Elucidation of tmeda-Solvated Alkali Metal Diphenylamide Complexes

  2009cites this paper
• Aspects of the Synthesis, Structure and Reactivity of Lithium Enolates

  2009cites this paper
• Total synthesis and bioactivity of an unnatural enantiomer of merrilactone a: development of an enantioselective desymmetrization strategy.

  2007cites this paper
• New Domino Silyl Enol Ether Reactions in the Synthesis of a Tetrodecamycin Fragment

  2006cites this paper
• Asymmetric total syntheses of marine cyclic depsipeptide halipeptins A-D.

  2006cites this paper
• Kinetics and mechanism of ketone enolization mediated by magnesium bis(hexamethyldisilazide).

  2006cites this paper
• Potent antagonists of the Kv1.5 potassium channel: synthesis and evaluation of analogous N,N-diisopropyl-2-(pyridine-3-yl)acetamides.

  2006cites this paper
• Highly enantioselective Pd-catalyzed allylic alkylations of acyclic ketones.

  2005cites this paper
• Kinetic enolate formation by lithium arylamide: effects of basicity on selectivity.

  2003cites this paper
• Resurrecting the Cornforth model for carbonyl addition: studies on the origin of 1,2-asymmetric induction in enolate additions to heteroatom-substituted aldehydes.

  2003cites this paper
• Are there concentration effects in enantioselective deprotonation of cyclic ketones

  2002cites this paper
• Magnesium bis(diisopropylamide), a useful reagent for regio- and stereoselective synthesis of kinetic silyl enol ethers

  1999cites this paper
• A Stereocontrolled Synthesis of Monofluoro Ketomethylene Dipeptide Isosteres.

  1998cites this paper
• 1,2-Asymmetric induction in dianionic allylation reactions of amino acid derivatives-synthesis of functionally useful, enantiopure aspartates and constrained scaffolds

  1998cites this paper