Ru-catalyzed dehydrogenative coupling of carboxylic acids and silanes - a new method for the preparation of silyl ester

Ru3(CO)12/EtI has been found to be an efficient catalyst system for the dehydrosilylation of carboxylic acids with silanes. In the presence of 1 mol% Ru3(CO)12 and 4 mol% EtI, dehydrosilylation reactions in toluene afforded the corresponding silyl esters at 100 °C in good and high yields.

• Publication year

  2008

• Venue

  Beilstein Journal of Organic Chemistry

• Publication date

  2008-07-30

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.3762/bjoc.4.27PMID 18941497PMCID 2511026
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

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