Nonlocal Hamiltonians are used widely in first-principles quantum calculations; the nonlocality stems from eliminating undesired degrees of freedom, e.g., core electrons. To date, attempts to couple nonlocal systems to external electromagnetic (EM) fields have been heuristic or limited to weak or long wavelength fields. Using Feynman path integrals, we derive an exact, closed-form coupling of arbitrary EM fields to nonlocal systems. Our results justify and clarify the couplings used to date and are essential for systematic computation of linear and especially nonlinear responses.
Coupling of nonlocal potentials to electromagnetic fields.
S. Ismail‐Beigi,E. Chang,S. Louie
Published 2001 in Physical Review Letters
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- Publication year
2001
- Venue
Physical Review Letters
- Publication date
2001-01-24
- Fields of study
Medicine, Physics
- Identifiers
- External record
- Source metadata
Semantic Scholar, PubMed
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