Determination of polyolefin additives by reversed-phase liquid chromatography

AbstractThis article examines the contribution of liquid chromatography to the study of polyolefin additives commonly used to obtain improved environmental resistance (antioxidants, ultraviolet light stabilizers, antistatics, and so on) and appearance enhancements (e.g. colorants). Several reversed-phase liquid chromatographic methods are summarized, and a detailed description of different detectors is provided. In addition, ways of applying these methods to analyse food contact materials and plastic toys are emphasized. Finally, the potential use of these methods is addressed which complies with European health safety regulations.

• Publication year

  2012

• Venue

  Central European Journal of Chemistry

• Publication date

  2012-03-08

• Fields of study

  Chemistry, Environmental Science

• Identifiers
  DOI 10.2478/s11532-012-0001-x
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• A fast method to assess the composition of a polyolefin: an application to compliance testing of food contact materials

  2011cited by this paper
• Effect of modified atmosphere and active packaging on the shelf-life of fresh bluefin tuna fillets

  2011cited by this paper
• DETERMINATION OF 7 ANTIOXIDANTS, 8 ULTRAVIOLET ABSORBENTS, AND 2 FIRE RETARDANTS IN PLASTIC FOOD PACKAGE BY ULTRASONIC EXTRACTION AND ULTRA PERFORMANCE LIQUID CHROMATOGRAPHY

  2011cited by this paper
• Experimental and theoretical study of LDPE versus different concentrations of Irganox 1076 and different thickness

  2011cited by this paper
• Liquid chromatographic methods to analyze hindered amines light stabilizers (HALS) levels to improve safety in polyolefins.

  2010cited by this paper
• Determination of antioxidants in polyolefins using total dissolution methodology followed by RPLC.

  2010cited by this paper
• Identification of degradation products of antioxidants in polyolefins by liquid chromatography combined with atmospheric pressure photoionisation mass spectrometry

  2010cited by this paper
• Type of Polypropylene Material Significantly Influences the Migration of Antioxidants from Polymer Packaging to Food Simulants During Microwave Heating

  2010cited by this paper
• Application of liquid chromatography in polymer non-ionic antistatic additives analysis.

  2010cited by this paper
• Study of the high temperature reactions of a hindered aryl phosphite (Hostanox PAR 24) used as a processing stabiliser in polyolefins

  2010cited by this paper
• Migration of α-tocopherol from LDPE films to corn oil and its effect on the oxidative stability

  2010cited by this paper
• Effect of natural antioxidants on the stability of polypropylene films

  2009cited by this paper
• Migration of α-tocopherol from an active multilayer film into whole milk powder

  2009cited by this paper
• Plastics Additives Handbook

  2009cited by this paper
• Determination of polymer additives by liquid chromatography coupled with mass spectrometry. A comparison of atmospheric pressure photoionization (APPI), atmospheric pressure chemical ionization (APCI), and electrospray ionization (ESI)

  2009cited by this paper
• Fast supercritical fluid extraction of low- and high-density polyethylene additives: Comparison with conventional reflux and automatic Soxhlet extraction

  2009cited by this paper
• Quality of minimally processed red chicory (Cichorium intybus L.) evaluated by anthocyanin content, radical scavenging activity, sensory descriptors and microbial indices.

  2009cited by this paper
• Release of antioxidants from co-extruded active packaging developed for whole milk powder.

  2009cited by this paper
• High-performance liquid chromatography analysis of ten dyes for control of safety of commercial articles.

  2008cited by this paper
• Behaviour of a new antioxidant active film versus oxidizable model compounds

  2008cited by this paper
• Natural extracts as potential source of antioxidants to stabilize polyolefins

  2008cited by this paper
• Effect of organic mobile phase composition on signal responses for selected polyalkene additive compounds by liquid chromatography-mass spectrometry.

  2008cited by this paper
• Olefin polymer technologies—History and recent progress at The Dow Chemical Company

  2008cited by this paper
• Antioxidant content of and migration from commercial polyethylene, polypropylene, and polyvinyl chloride packages.

  2007cited by this paper
• Microwave-assisted oxidation of phosphite-type antioxidant additives in polyethylene film extracts.

  2007cited by this paper
• Development of an ultraperformance liquid chromatography method for improved determination of additives in polymeric materials.

  2007cited by this paper
• Solvent exchange using hollow fiber prior to separation and determination of some antioxidants by high performance liquid chromatography.

  2007cited by this paper
• Identification of polymer additives by liquid chromatography–mass spectrometry

  2006cited by this paper
• Release of alpha-tocopherol from antioxidative low-density polyethylene film into fatty food simulant: Influence of complexation in beta-cyclodextrin

  2006cited by this paper
• Improvement of α‐tocopherols long‐term efficiency by modeling its heterogeneous natural environment in polyethylene

  2006cited by this paper
• Determination of α-tocopherol in low-density polyethylene (LDPE) films by diffuse reflectance Fourier transform infrared (DRIFT-IR) spectroscopy compared to high performance liquid chromatography (HPLC)

  2006cited by this paper
• An Alternative Method for Determination of Additives in Polypropylene Using Supercritical Fluid Extraction and Enhanced Solvent Extraction

  2006cited by this paper
• Loss of stability by migration and chemical reaction of Santonox® R in branched polyethylene under anaerobic and aerobic conditions

  2006cited by this paper
• Molecular Composition of Nonionic Vesicles Prepared from Span 80 or Span 85 by a Two‐Step Emulsification Method

  2006cited by this paper
• How will additives shape the future of plastics

  2006cited by this paper
• Experimental design approach for the optimisation of pressurised fluid extraction of additives from polyethylene films.

  2005cited by this paper
• Evaluation of long‐term performance of antioxidants using prooxidants instead of thermal acceleration

  2005cited by this paper
• Interlaboratory test on polymers: determination of antioxidants in polyolefins

  2005cited by this paper
• 6 Catheter ablation effect on inflammation in atrial flutter patients

  2005cited by this paper
• Process efficiency and long‐term performance of α‐tocopherol in film‐blown linear low‐density polyethylene

  2005cited by this paper
• Determination of banned azo dyes in consumer goods

  2005cited by this paper
• Identification and quantification of (polymeric) hindered-amine light stabilizers in polymers using pyrolysis-gas chromatography-mass spectrometry and liquid chromatography-ultraviolet absorbance detection-evaporative light scattering detection.

  2005cited by this paper
• Aromatic amines from azo dye reduction: status review with emphasis on direct UV spectrophotometric detection in textile industry wastewaters

  2004cited by this paper
• Temperature-programmed packed capillary liquid chromatography coupled to evaporative light-scattering detection and electrospray ionization time-of-flight mass spectrometry for characterization of high-molecular-mass hindered amine light stabilizers.

  2004cited by this paper
• Detection of tinuvin 770, a light stabilizer of plastic materials from dialysis membranes, by high-performance liquid chromatographic analysis.

  2004cited by this paper
• Extraction and quantification of antioxidants from low-density polyethylene by microwave energy and liquid chromatography

  2004cited by this paper
• Two-stage synthesis of sorbitan esters, and physical properties of the products

  2004cited by this paper
• Water extraction and degradation of a sterically hindered phenolic antioxidant in polypropylene films

  2004cited by this paper
• Migration of lubricants from food packagings. Screening for lipid classes and quantitative estimation using normal-phase liquid chromatographic separation with evaporative light scattering detection.

  2003cited by this paper
• Antioxidant properties of lignin in polypropylene

  2003cited by this paper
• New approaches to the melt stabilization of polyolefins

  2002cited by this paper
• Temperature-promoted large-volume solute enrichment in column-switching miniaturized liquid chromatography: determination of an antioxidant.

  2002cited by this paper
• Reversed-phase HPLC of polymer additives with multiple on-line spectroscopic analysis (UV, IR, 1H NMR and MS)

  2002cited by this paper
• Optimization of the extraction of azo colorants used in toy products.

  2002cited by this paper
• The antioxidant role of vitamin E in polymers. IV. Reaction products of dl-α-tocopherol with lead dioxide and with polyolefins

  2001cited by this paper
• Light stabilization of metallocene polyolefins

  2001cited by this paper
• The antioxidant role of vitamin E in polymers V. Separation of stereoisomers and characterisation of other oxidation products of dl-α-tocopherol formed in polyolefins during melt processing

  2001cited by this paper
• Study of electron beam irradiation effects on 2,4,6-trichloroanisole as a contaminant of cork by gas chromatography-mass spectrometry

  2001cited by this paper
• Temperature-programmed packed capillary liquid chromatography coupled to fourier-transform infrared spectroscopy

  2000cited by this paper
• Kinetic effects of photoexposed isotactic polypropylene in the presence of some hindered-amine light stabilisers

  2000cited by this paper
• Influence of trace metals, acids and ethanol in food-simulating liquids on the retention of α-tocopherol in low-density polyethylene film

  2000cited by this paper
• Hindered amine stabilizers investigated by the use of packed capillary temperature-programmed liquid chromatography. I. Poly((6-((1,1,3,3-tetramethylbutyl)-amino)-1,3,5-triazine-2,4- diyl)(2,2 ,6,6-tetramethyl-4-piperidyl)imino)-1,6-hexanediyl ((2,2,6,6-tetramethyl-4-piperidyl)imino)).

  2000cited by this paper
• Thermo-oxidative degradation of isotactic polypropylene at high temperatures: phenolic antioxidants versus HAS

  2000cited by this paper
• The antioxidant role of α-tocopherol in polymers II. Melt stabilising effect in polypropylene

  1999cited by this paper
• Determination of low levels of an antioxidant in polyolefins by large-volume injection temperature-programmed packed capillary liquid chromatography.

  1999cited by this paper
• Analytical monitoring of the production of biodiesel by high-performance liquid chromatography with various detection methods.

  1999cited by this paper
• A rapid ultrasonic extraction technique to identify and quantify additives in poly(ethylene)

  1999cited by this paper
• Supercritical Fluid Extraction (SFE) Optimization by Full‐Factorial Design for the Determination of Irganox 1076, Irgafos 168, and Chimassorb 81 in Virgin and Recycled Polyolefins

  1999cited by this paper
• The antioxidant role of α-tocopherol in polymers. III. Nature of transformation products during polyolefins extrusion

  1999cited by this paper
• Extraction of polypropylene additives and their analysis by HPLC

  1998cited by this paper
• Safety evaluation of an ionized multilayer plastic film used for vacuum cooking and meat preservation.

  1998cited by this paper
• Factors affecting high-pressure solvent extraction (accelerated solvent extraction) of additives from polymers.

  1998cited by this paper
• Evolution of a method for quantitative supercritical fluid extraction of Ethanox 330 antioxidant from high-density polyethylene

  1998cited by this paper
• Analysis of antioxidants extracted from polypropylene by supercritical fluid extraction.

  1998cited by this paper
• Critical Review: Analytical Extraction of Additives From Polymers

  1997cited by this paper
• Process for Preparing Nonionic Surfactant Sorbitan Fatty Acid Esters with and without Previous Sorbitol Cyclization

  1996cited by this paper
• Analysis of Photostabilizer in High Density Polyethylene by Reverse-and Normal-Phase HPLC

  1996cited by this paper
• Mechanism of action of phosphites in polyolefin stabilisation

  1995cited by this paper
• Characterisation of electron beam generated transformation products of irganox 1010 by particle beam liquid chromatography-mass spectrometry with on-line diode array detection

  1994cited by this paper
• The antioxidant role of α‐tocopherol in polymers. I. The nature of transformation products of α‐tocopherol formed during melt processing of LDPE

  1994cited by this paper
• Recent Advances in Polyolefin Additive Analysis

  1993cited by this paper
• Identification by particle-beam liquid chromatography—mass spectrometry of transformation products of the antioxidant Irganox 1330 in food-contact polymers subjected to electron-beam irradiation

  1993cited by this paper
• Characterisation of solvent-extractable transformation products of high molecular weight hindered phenols in polypropylene subjected to ionising radiation in air or to thermal ageing

  1993cited by this paper
• Sulfur‐free lignins as composites of polypropylene films

  1993cited by this paper
• On-line monitoring of fermentation processes by ultrafiltration and column liquid chromatography

  1992cited by this paper
• Determination of the polymeric light stabilizer Chimassorb 944 in polyolefins by isocratic high-performance liquid chromatography

  1992cited by this paper
• Extraction and Quantitation of Polyolefin Additives

  1991cited by this paper
• Determination of polymeric hindered amine light stabilizers in polyolefins by high-performance liquid chromatography

  1991cited by this paper
• Fast separation of stabilizers from polyolefins by microwave heating

  1990cited by this paper
• Supercritical fluid extraction combined with microcolumn liquid chromatography for the analysis of polymer additives

  1989cited by this paper
• Determination of the polymeric light stabilizer Chimassorb 944 in polyolefins by reversed-phase high-performance liquid chromatography

  1988cited by this paper
• Determination of the hindered amine additive Chimassorb 944 in polyethylene by high-performance liquid chromatography

  1987cited by this paper
• Sugar cane bagasse lignin as a stabilizer for rubbers: Part II—Butadiene rubber

  1985cited by this paper
• Chromatographic determination of some hindered amine light stabilizers in polyolefins

  1983cited by this paper
• Quantitative determination of antioxidants and ultraviolet stabilizers in polymers by high performance liquid chromatography

  1983cited by this paper
• Analysis of sorbitan fatty acid esters by HPLC

  1983cited by this paper
• Determination of UV Absorbing Polyolefin Additives by Gradient and Isocratic Normal-Phase High Performance Liquid Chromatography

  1982cited by this paper
• A Reversed-Phase High Pressure Liquid Chromatographic Method for Analysis of Additives in Polyolefins

  1980cited by this paper
• Estimation of toxic hazard--a decision tree approach.

  1978cited by this paper
• Some aspects of stabilization of polymers against light

  1973cited by this paper

• Recent advances in functional additives for polyolefins: chemistry, applications, and sustainable approaches – a review

  2026cites this paper
• Determination of 60 Migrant Substances in Plastic Food Contact Materials by Vortex-Assisted Liquid-Liquid Extraction and GC-Q-Orbitrap HRMS

  2021cites this paper
• Determination of the Contents of Antioxidants and Their Degradation Products in Sodium Chloride Injection for Blood Transfusion

  2020cites this paper
• Porous graphite as stationary phase for the chromatographic separation of polymer additives - determination of adsorption capability by Raman spectroscopy and physisorption.

  2020cites this paper
• Challenges and opportunities of solvent-based additive extraction methods for plastic recycling.

  2020cites this paper
• Migration of Plastic Bag Additives in Attiéké (A Fermented Cassava-based Couscous in Côte d'Ivoire)

  2019cites this paper
• Comparative Extractables Study of Autoclavable Polyethersulfone Filter Cartridges for Sterile Filtration

  2018cites this paper
• Micro- and macroscopic approaches to polymer stabilizer analysis for solar thermal systems

  2017cites this paper
• Migration of Stabilizers from Polypropylene into Simulated Food

  2017cites this paper
• Packaging: A Noteworthy Feature in Food Safety

  2016cites this paper
• Advances in the determination of hindered amine light stabilizers - A review.

  2016cites this paper
• Monitoring the extraction of additives and additive degradation products from polymer packaging into solutions by multi-residue method including solid phase extraction and ultra-high performance liquid chromatography-tandem mass spectrometry analysis

  2014cites this paper
• Determination of stabilisers in polymeric materials used as encapsulants in photovoltaic modules

  2014cites this paper
• Miniaturised method for the quantitation of stabilisers in microtome cuts of polymer materials by HPLC with UV, MS or MS2 detection

  2013cites this paper
• Mass spectrometry as a useful tool for the analysis of stabilizers in polymer materials

  2013cites this paper
• Quantitation of hindered amine light stabilizers in plastic materials by high performance liquid chromatography and mass spectrometric detection using electrospray ionization and atmospheric pressure photoionization.

  2013cites this paper
• Monitoring the degradation of stabilization systems in polypropylene during accelerated aging tests by liquid chromatography combined with atmospheric pressure chemical ionization mass spectrometry

  2013cites this paper
• Evaluation of a microwave assisted extraction prior to high performance liquid chromatography for the determination of additives in polyolefins

  2013cites this paper