Synthesis and Properties of Networks Based on Thiol-ene Chemistry Using a CO2 -Based δ-Lactone.

3-Ethylidene-6-vinyltetrahydro-2H-pyran-2-one, a divinyl δ-lactone derived from CO2 and 1,3-butadiene, is used for the synthesis of networks with various compositions through the thiol-ene click reaction with di- and tri-thiol compounds. Thermal, mechanical, and optical properties of the networks are characterized. The networks have sharp and uniform glass transitions and show good thermal stability with T d from 287 to 332 °C. Mechanical properties of the networks can be adjusted by the cross-link density; 6.18 MPa of tensile strength, 574% break elongation and 1.84 of tan δ at maximum are reached. Metal complexation makes the networks tougher due to additional cross-links. The highly homogeneous networks are transparent with average 90% transmittance of visible light, and of decent refractive indices around 1.55. Swelling-induced twist shape transformation and visible QR code under UV light is realized by pattern of the network.

• Publication year

  2018

• Venue

  Macromolecular rapid communications

• Publication date

  2018-08-17

• Fields of study

  Medicine, Materials Science, Chemistry

• Identifiers
  DOI 10.1002/marc.201800395PMID 30118152
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

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