Influence of electrostatic fields on molecular electronic structure: insights for interfacial charge transfer.

No abstract is available for this paper.

• Publication year

  2010

• Venue

  Physical Chemistry, Chemical Physics - PCCP

• Publication date

  2010-09-29

• Fields of study

  Medicine, Physics, Chemistry

• Identifiers
  DOI 10.1039/c0cp01039aPMID 20714606
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• Ionization potentials of crystalline organic thin films: Position dependence due to molecular shape and charge redistribution

  2010cited by this paper
• On the interface dipole at the pentacene-fullerene heterojunction : A theoretical study

  2010cited by this paper
• Experimental Determination of the Excited-State Polarizability and Dipole Moment in a Thin Organic Semiconductor Film

  2010cited by this paper
• Time- and energy resolved photoemission electron microscopy-imaging of photoelectron time-of-flight analysis by means of pulsed excitations

  2010cited by this paper
• Influence of intramolecular polar bonds on interface energetics in perfluoro-pentacene on Ag(111)

  2010cited by this paper
• Near- and far-field effects on molecular energy level alignment at an organic/electrode interface

  2010cited by this paper
• Interfacial electronic structure of vanadyl naphthalocyanine on highly ordered pyrolytic graphite

  2010cited by this paper
• Effect of electrostatic screening on apparent shifts in photoemission spectra near metal/organic interfaces

  2010cited by this paper
• Dipole assisted exciton dissociation at conjugated polymer/fullerene photovoltaic interfaces: A molecular study using density functional theory calculations

  2010cited by this paper
• Self-assembled monolayers of polar molecules on Au(111) surfaces: distributing the dipoles.

  2010cited by this paper
• Controlling energy level offsets in organic/organic heterostructures using intramolecular polar bonds

  2009cited by this paper
• Intrinsic Surface Dipoles Control the Energy Levels of Conjugated Polymers

  2009cited by this paper
• Energy‐Level Alignment at Organic/Metal and Organic/Organic Interfaces

  2009cited by this paper
• Quantum‐Chemical Characterization of the Origin of Dipole Formation at Molecular Organic/Organic Interfaces

  2009cited by this paper
• Electronic Structure and Geminate Pair Energetics at Organic–Organic Interfaces: The Case of Pentacene/C60 Heterojunctions

  2009cited by this paper
• Energetics of metal–organic interfaces: New experiments and assessment of the field

  2009cited by this paper
• Orientation-controlled charge transfer at CuPc/F16CuPc interfaces

  2009cited by this paper
• Stark realities.

  2009cited by this paper
• Charge carrier formation in polythiophene/fullerene blend films studied by transient absorption spectroscopy.

  2008cited by this paper
• Molecular Orientation-Dependent Ionization Potential of Organic Thin Films

  2008cited by this paper
• Tuning the ionization energy of organic semiconductor films: the role of intramolecular polar bonds.

  2008cited by this paper
• Polarization energies in oligoacene semiconductor crystals.

  2008cited by this paper
• Orientation-dependent ionization energies and interface dipoles in ordered molecular assemblies.

  2008cited by this paper
• Electronic structures of interfacial states formed at polymeric semiconductor heterojunctions.

  2008cited by this paper
• The Dielectric Constant of Self‐Assembled Monolayers

  2008cited by this paper
• Electrostatic Properties of Ideal and Non‐ideal Polar Organic Monolayers: Implications for Electronic Devices

  2007cited by this paper
• Electrostatic properties of adsorbed polar molecules: opposite behavior of a single molecule and a molecular monolayer.

  2007cited by this paper
• Toward control of the metal-organic interfacial electronic structure in molecular electronics: a first-principles study on self-assembled monolayers of pi-conjugated molecules on noble metals.

  2007cited by this paper
• Molecular microelectrostatic view on electronic states near pentacene grain boundaries

  2007cited by this paper
• On validity of the Schottky-Mott rule in organic semiconductors: Sexithiophene on various substrates

  2007cited by this paper
• Insights on interfacial charge transfer across P3HT/fullerene photovoltaic heterojunction from Ab initio calculations.

  2007cited by this paper
• Depolarization Effects in Self‐Assembled Monolayers: A Quantum‐Chemical Insight

  2007cited by this paper
• Experimental estimation of the electric dipole moment and polarizability of titanyl phthalocyanine using ultraviolet photoelectron spectroscopy

  2006cited by this paper
• External electric field effects on absorption and fluorescence spectra of a fullerene derivative and its mixture with zinc-tetraphenylporphyrin doped in a PMMA film.

  2006cited by this paper
• Imaging nanostructures with scanning photoionization microscopy.

  2006cited by this paper
• Electronic and geometric structure of electro-optically active organic films and associated interfaces

  2006cited by this paper
• Interface energetics and level alignment at covalent metal-molecule junctions: pi-conjugated thiols on gold.

  2006cited by this paper
• Electronic structure of Si(111)-bound alkyl monolayers : Theory and experiment

  2006cited by this paper
• Renormalization of molecular electronic levels at metal-molecule interfaces.

  2006cited by this paper
• Does the molecular orientation induce an electric dipole in Cu-phthalocyanine thin films?

  2006cited by this paper
• Origin of the highest occupied band position in pentacene films from ultraviolet photoelectron spectroscopy: Hole stabilization versus band dispersion

  2006cited by this paper
• Cooperative effects and dipole formation at semiconductor and self-assembled-monolayer interfaces

  2006cited by this paper
• Tuning of Metal Work Functions with Self‐Assembled Monolayers

  2005cited by this paper
• Laser-based photoemission micro-spectroscopy for occupied and unoccupied states of inhomogeneous surfaces

  2005cited by this paper
• High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends

  2005cited by this paper
• Exciton trapping at heterojunctions in polymer blends.

  2005cited by this paper
• Vacuum level alignment at organic/metal junctions: “Cushion” effect and the interface dipole

  2005cited by this paper
• Photoemission time-of-flight spectromicroscopy of Ag nanoparticle films on Si(111)

  2004cited by this paper
• Charge-transfer and energy-transfer processes in pi-conjugated oligomers and polymers: a molecular picture.

  2004cited by this paper
• Electronic structure of S-C6H5 self-assembled monolayers on Cu(111) and Au(111) substrates

  2004cited by this paper
• Hybrid interfaces of conjugate polymers: Band edge alignment studied by ultraviolet photoelectron spectroscopy

  2004cited by this paper
• Cooperative effect in electron transfer between metal substrate and organized organic layers

  2003cited by this paper
• Interface Dipoles Arising from Self-Assembled Monolayers on Gold: UV−Photoemission Studies of Alkanethiols and Partially Fluorinated Alkanethiols

  2003cited by this paper
• Electron Energetics at Surfaces and Interfaces: Concepts and Experiments

  2003cited by this paper
• Metal–organic interface and charge injection in organic electronic devices

  2003cited by this paper
• Substrate‐Mediated Electronic Structure and Properties of Sexiphenyl Films

  2003cited by this paper
• Exchangelike effects for closed-shell adsorbates: interface dipole and work function.

  2002cited by this paper
• Fine tuning work function of indium tin oxide by surface molecular design: Enhanced hole injection in organic electroluminescent devices

  2001cited by this paper
• Tracing photoinduced electron transfer process in conjugated polymer/fullerene bulk heterojunctions in real time

  2001cited by this paper
• Chemical characterization of surfaces and interfaces with submicron spatial resolution

  2000cited by this paper
• Nonadiabatic Electron Transfer at Metal Surfaces

  2000cited by this paper
• ENERGY LEVEL ALIGNMENT AND INTERFACIAL ELECTRONIC STRUCTURES AT ORGANIC/METAL AND ORGANIC/ORGANIC INTERFACES

  1999cited by this paper
• Tuning the Work Function of Gold with Self-Assembled Monolayers Derived from X−[C6H4−C⋮C−]nC6H4−SH (n = 0, 1, 2; X = H, F, CH3, CF3, and OCH3)

  1999cited by this paper
• Probing Excited-State Electron Transfer by Resonance Stark Spectroscopy. 1. Experimental Results for Photosynthetic Reaction Centers

  1998cited by this paper
• CONTROLLING CHARGE INJECTION IN ORGANIC ELECTRONIC DEVICES USING SELF-ASSEMBLED MONOLAYERS

  1997cited by this paper
• External Electric Field Effects on Fluorescence in an Electron Donor and Acceptor System: Ethylcarbazole and Dimethyl Terephthalate in PMMA Polymer Films

  1996cited by this paper
• Controlling Schottky energy barriers in organic electronic devices using self-assembled monolayers.

  1996cited by this paper
• Calculating the surface potential of unionized monolayers.

  1994cited by this paper
• Ultrafast spectroscopic studies of photoinduced electron transfer from semiconducting polymers to C60.

  1994cited by this paper
• Image states and local work function for Ag/Pd(111).

  1993cited by this paper
• Photoinduced Electron Transfer from a Conducting Polymer to Buckminsterfullerene

  1992cited by this paper
• Quantitative aspects of ultraviolet photoemission of adsorbed xenon—a review

  1991cited by this paper
• Electric field modulation of the fluorescence from Rhodobacter sphaeroides reaction centers

  1988cited by this paper
• Reevaluation of electronic polarization energies in organic molecular crystals

  1987cited by this paper
• Quantum Corrections to the Polarization Energy in Linear Acene Series

  1980cited by this paper
• Theory of Metal Surfaces: Charge Density and Surface Energy

  1970cited by this paper
• On the Theory of Electron-Transfer Reactions. VI. Unified Treatment for Homogeneous and Electrode Reactions

  1965cited by this paper
• Theory of the Electronic Polaron and Ionization of a Trapped Electron by an Exciton

  1954cited by this paper
• Conduction in polar crystals. I. Electrolytic conduction in solid salts

  1938cited by this paper
• The structure of surface films XXI—Surface potentials of dibasic esters, alcohols, aldoximes, and ketones

  1934cited by this paper
• On the mutual potential energy of a plane network of doublets

  1927cited by this paper
• Supporting Online Material Materials and Methods Figs. S1 and S2 References Efficient Tandem Polymer Solar Cells Fabricated by All-solution Processing

  year unknowncited by this paper

• Binding Energies of Molecules Grafted onto Calcium Surfaces: A Periodic DFT Investigation

  2025cites this paper
• Surface Magnetic Stabilization and the Photoemission Chiral-Induced Spin-Selectivity Effect.

  2024cites this paper
• The Interplay of Collective Electrostatic Effects and Level Alignment Dictates the Tunneling Rates across Halogenated Aromatic Monolayer Junctions.

  2019cites this paper
• Energy level alignment of blended organic semiconductors and electrodes at the interface

  2018cites this paper
• van der Waals Interaction Activated Strong Electronic Coupling at the Interface between Chloro Boron-Subphthalocyanine and Cu(111)

  2018cites this paper
• Fast optical work-function tuning at an organic/metal interface

  2017cites this paper
• Energy Level Shifts at the Silica/Ru(0001) Heterojunction Driven by Surface and Interface Dipoles

  2017cites this paper
• Computational investigations of electronic structure modifications of ferrocene-terminated self-assembled monolayers: effects of electron donating/withdrawing functional groups attached on the ferrocene moiety.

  2017cites this paper
• Selective Cooperative Self-Assembly between an Organic Semiconductor and Native Adatoms on Cu(110)

  2015cites this paper
• Theoretical description of structural and electronic properties of organic photovoltaic materials.

  2015cites this paper
• Integer Charge Transfer and Hybridization at an Organic Semiconductor/Conductive Oxide Interface

  2015cites this paper
• Understanding the Adsorption of CuPc and ZnPc on Noble Metal Surfaces by Combining Quantum-Mechanical Modelling and Photoelectron Spectroscopy

  2014cites this paper
• Electronic Polarization at Pentacene/Polymer Dielectric Interfaces: Imaging Surface Potentials and Contact Potential Differences as a Function of Substrate Type, Growth Temperature, and Pentacene Microstructure

  2014cites this paper
• Interfacial composition of the oxide-donor interface: Probing morphology and charge injection/extraction in organic photovoltaics.

  2014cites this paper
• Surface Dipoles and Electron Transfer at the Metal Oxide–Metal Interface: A 2PPE Study of Size-Selected Metal Oxide Clusters Supported on Cu(111)

  2014cites this paper
• Electronic structure and dynamics of quasi-2D states of vanadyl naphthalocyanine on Au(111)†

  2013cites this paper
• Distance Dependence of Exciton Dissociation at a Phthalocyanine–C60 Interface

  2013cites this paper
• Tuning zinc oxide/organic energy level alignment using mixed triethoxysilane monolayers

  2013cites this paper
• Effect of geometrical orientation on the charge-transfer energetics of supramolecular (tetraphenyl)-porphyrin∕C60 dyads.

  2013cites this paper
• Interfacial dipole formation and surface-electron confinement in low-coverage self-assembled thiol layers: thiophenol and p-fluorothiophenol on Cu(111).

  2012cites this paper
• Theoretical investigation of molecular excited states in polar organic monolayers via an efficient embedding approach

  2012cites this paper
• Polarity Switching of Charge Transport and Thermoelectricity in Self‐Assembled Monolayer Devices

  2012cites this paper
• Coarse-grained kinetic modelling of bilayer heterojunction organic solar cells

  2012cites this paper
• Interfacial Electronic Structure of the Dipolar Vanadyl Naphthalocyanine on Au(111): “Push-Back” vs Dipolar Effects

  2011cites this paper
• Resonance and localization effects at a dipolar organic semiconductor interface.

  2011cites this paper
• Collectively Induced Quantum-Confined Stark Effect in Monolayers of Molecules Consisting of Polar Repeating Units

  2011cites this paper
• A calorimetric and spectroscopic comparison of the effects of lathosterol and cholesterol on the thermotropic phase behavior and organization of dipalmitoylphosphatidylcholine bilayer membranes.

  2011cites this paper
• Transport properties of orbitally hybridized organic semiconductors

  2011cites this paper