Preparation of Functionalized Diaryl- and Diheteroaryllanthanum Reagents by Fast Halogen-Lanthanum Exchange.

No abstract is available for this paper.

• Publication year

  2017

• Venue

  Angewandte Chemie

• Publication date

  2017-12-18

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1002/anie.201709553PMID 29052932
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• The Evolution of the Total Synthesis of Rocaglamide.

  2016cited by this paper
• Chemoselective Ketone Synthesis by the Addition of Organometallics to N-Acylazetidines.

  2016cited by this paper
• Atom-economical preparation of aryl- and heteroaryl-lanthanum reagents by directed ortho-metalation by using tmp3[La].

  2010cited by this paper
• Kinetics of bromine-magnesium exchange reactions in heteroaryl bromides.

  2009cited by this paper
• Relative rates of bromine-magnesium exchange reactions in substituted bromobenzene derivatives.

  2008cited by this paper
• Relative Geschwindigkeiten der Brom-Magnesium-Austauschreaktionen an substituierten Brombenzolderivaten†

  2008cited by this paper
• Lösliche Lanthanoid‐Salze (LnCl3⋅2 LiCl) für die verbesserte Addition magnesiumorganischer Reagentien an Carbonylverbindungen

  2006cited by this paper
• Mild iodine-magnesium exchange of iodoaromatics bearing a pyrimidine ring with isopropylmagnesium chloride.

  2006cited by this paper
• Stereoselective functionalization of beta-iodo-alpha,beta-unsaturated ketones via an iodine-copper exchange reaction.

  2006cited by this paper
• Highly efficient reagents for Br/Mg exchange.

  2006cited by this paper
• Soluble lanthanide salts (LnCl3.2LiCl) for the improved addition of organomagnesium reagents to carbonyl compounds.

  2006cited by this paper
• Hocheffiziente Reagentien für den Brom-Magnesium-Austausch†

  2006cited by this paper
• Preparation of cyclic alkenylmagnesium reagents via an iodine/magnesium exchange.

  2005cited by this paper
• Nucleophile Katalyse der Iod‐Zink‐Austauschreaktion: Synthese von hochfunktionalisierten Diarylzinkverbindungen

  2004cited by this paper
• Stereoselective S N 2-substitutions using polyfunctional lithium arylcuprates prepared by an iodine-copper exchange.

  2004cited by this paper
• Nucleophilic catalysis of the iodine-zinc exchange reaction: preparation of highly functionalized diaryl zinc compounds.

  2004cited by this paper
• Lanthanide-promoted ethylation of Schiff bases by triethylaluminum.

  2004cited by this paper
• A LiCl-mediated Br/Mg exchange reaction for the preparation of functionalized aryl- and heteroarylmagnesium compounds from organic bromides.

  2004cited by this paper
• Neutral and cationic alkyl and alkynyl complexes of lanthanum: Synthesis, stability, and cis-selective linear alkyne dimerization

  2004cited by this paper
• Eine LiCl‐vermittelte Br/Mg‐Austauschreaktion zur Herstellung funktionalisierter Aryl‐ und Heteroarylmagnesium‐Verbindungen ausgehend von organischen Bromiden

  2004cited by this paper
• Stereoselective preparation of functionalized acyclic alkenylmagnesium reagents using i-PrMgCl.LiCl.

  2004cited by this paper
• Highly functionalized organomagnesium reagents prepared through halogen-metal exchange.

  2003cited by this paper
• Synthese hoch funktionalisierter Organomagnesiumreagentien durch Halogen-Metall-Austausch

  2003cited by this paper
• Lanthanide assisted cross-coupling of aryl bromides with triethylaluminum

  2003cited by this paper
• Successive iodine-magnesium or -copper exchange reactions for the selective functionalization of polyhalogenated aromatics.

  2003cited by this paper
• Chapter 3 - Regioselective Synthesis of Organolithiums by X-Li Exchange

  2002cited by this paper
• Development of novel Lewis acid catalysts for selective organic reactions in aqueous media.

  2002cited by this paper
• Selective halogen-magnesium exchange reaction via organomagnesium ate complex.

  2001cited by this paper
• Preparation of organoytterbium reagent from ytterbium trichloride and organomagnesium

  2001cited by this paper
• Diastereoselective Ce(OiPr)(3)-Catalyzed Pinacol Couplings of Aldehydes.

  2000cited by this paper
• Preparation of new polyfunctional magnesiated heterocycles using a chlorine-, bromine-, or iodine-magnesium exchange

  2000cited by this paper
• Halogen-Magnesium Exchange via Trialkylmagnesates for the Preparation of Aryl- and Alkenylmagnesium Reagents This work was supported by a Grant-in-Aid for Scientific Research from the Ministry of Education, Science, Sports, and Culture, Japan.

  2000cited by this paper
• Halogen‐Magnesium‐Austausch mit Trialkylmagnesaten zur Herstellung von Aryl‐ und Alkenylmagnesium‐Reagentien

  2000cited by this paper
• Diastereoselektive Ce(OiPr)3‐katalysierte Pinakolkupplung von Aldehyden

  2000cited by this paper
• Coupling of Organic Halides with Carbonyl Compounds Promoted by SmI(2), the Kagan Reagent.

  1999cited by this paper
• Sequencing Reactions with Samarium(II) Iodide.

  1996cited by this paper
• Anhydrous cerium(III) chloride — Effect of the drying process on activity and efficiency

  1996cited by this paper
• Enolate free α-alkoxyvinyllithium reagents: Improved preparation and reaction with N,N-dialkylcarboxamides

  1994cited by this paper
• Application of lanthanide reagents in organic synthesis

  1992cited by this paper
• The atom economy--a search for synthetic efficiency.

  1991cited by this paper
• Additions of alkyllathanum triflates to carbonyl compounds: reactive organometallic nucleophiles

  1990cited by this paper
• Four-co-ordinate lanthanide metal(III) chloro(alkyl)s: synthesis and X-ray structure of [LaR3(µ-Cl)Li(pmdeta)][R = CH(SiMe3)2, pmdeta =N,N,N′,N″,N″-pentamethyldiethylenetriamine]

  1988cited by this paper
• Alkyl and aryllanthanum triflates: New reagents for the conversion of tertiary amides to ketones

  1987cited by this paper
• Über die aldehydselektivität von alkylkomplexen von scandium, yttrium, lanthan und lanthaniden aldehyd/keton-konkurrenzversuchen

  1985cited by this paper
• Synthetic Methods and Reactions; Part 109. Improved Preparation of Aldehydes and Ketones from N,N-Dimethylamides and Grignard Reagents

  1984cited by this paper
• Carbon-carbon bond-forming reactions using cerium metal or organocerium(III) reagents

  1984cited by this paper
• Model studies on the synthesis of pseudomonic acids

  1982cited by this paper
• Dichloro(triphenylmethyl)(2,2,2-cryptate)lanthanum(III), an organolathanide cryptate complex

  1982cited by this paper
• N-methoxy-n-methylamides as effective acylating agents

  1982cited by this paper
• The Preparation of Aldehydes and Ketones via the in situ Reaction of Organolithium Compounds with Carboxamides or Carbamates

  1973cited by this paper
• The pharmacology of penfluridol (R 16341) a new potent and orally long-acting neuroleptic drug.

  1970cited by this paper

• Preparation and Reactivity of Organometallic Reagents Leading to Functionalized N-Heteroaromatics.

  2026cites this paper
• Discovery and Optimization of LATS1 and LATS2 Kinase Inhibitors for Use in Regenerative Medicine

  2025cites this paper
• Asymmetric Total Synthesis of (-)-Crotonine G and (-)-Crotonolide D.

  2025cites this paper
• Recent Advances in Halogen-Metal Exchange Reactions.

  2024cites this paper
• Recent synthetic strategies for the functionalization of fused bicyclic heteroaromatics using organo-Li, -Mg and -Zn reagents.

  2024cites this paper
• Homoleptic Organolanthanum-Catalyzed Carbohalogenation.

  2024cites this paper
• Heterogeneous gold-catalyzed Sandmeyer coupling of aryldiazonium salts with sodium bromide or thiols for constructing C-Br and C-S bonds.

  2023cites this paper
• Highly Regioselective Propargylation/Allenylation of Organolanthanum Reagents with Aldehydes.

  2023cites this paper
• CeCl3/n‐BuLi: Unraveling Imamoto's Organocerium Reagent

  2021cites this paper
• Preparation and reactions of polyfunctional magnesium and zinc organometallics in organic synthesis

  2021cites this paper
• CeCl 3 / n ‐BuLi: Enträtselung von Imamotos Organocer‐Reagenz

  2021cites this paper
• Continuous Flow Acylation of (Hetero)aryllithiums with Polyfunctional N,N‐Dimethylamides and Tetramethylurea in Toluene

  2021cites this paper
• Recent Developments in Transition-Metal-Free Functionalization and Derivatization Reactions of Pyridines

  2020cites this paper
• Tandem Mn–I Exchange and Homocoupling Processes Mediated by a Synergistically Operative Lithium Manganate

  2020cites this paper
• Tandem Mn-I exchange and homocoupling processes mediated by a synergistically operative lithium manganate.

  2020cites this paper
• Chemoselective Ketone Synthesis by the Strontium‐mediated Alkylation or Arylation of N , N ‐Dimethylamides or Urea

  2020cites this paper
• Trapping of Transient Organolithium Compounds

  2020cites this paper
• Catalyst-Free Enantiospecific Olefination with In Situ Generated Organocerium Species.

  2019cites this paper
• Alkyl yttrium complexes of doubly cyclometallated xanthene- and naphthalene-backbone bis(phosphinimine) ligands

  2019cites this paper
• Herstellung von polyfunktionellen Biarylderivaten durch Cyclolanthanierung von 2‐Bromobiarylen und heterocyclischen Analoga unter Verwendung von n Bu 2 LaCl⋅4 LiCl

  2019cites this paper
• Preparation of Polyfunctional Biaryl Derivatives by Cyclolanthanation of 2‐Bromobiaryls and Heterocyclic Analogues Using nBu2LaCl⋅4 LiCl

  2019cites this paper
• Die Halogen‐Samarium‐Austauschreaktion: Synthetische Anwendungen und Kinetik

  2019cites this paper
• The Halogen-Samarium Exchange Reaction: Synthetic Applications and Kinetics.

  2019cites this paper
• Regioselective C–H Activation of Substituted Pyridines and other Azines using Mg- and Zn-TMP-Bases

  2018cites this paper
• Katalysatorfreie enantiospezifische Olefinierung mithilfe von in situ generierten Organocer‐Spezies

  2018cites this paper
• Synthesis of Polyfunctionalized Triaryllanthanum Reagents by Using Ph3 La and Related Species as Exchange Reagents.

  2018cites this paper