Aminopyridine-Borane Complexes as Hydrogen Atom Donor Reagents: Reaction Mechanism and Substrate Selectivity.

No abstract is available for this paper.

• Publication year

  2017

• Venue

  Chemistry

• Publication date

  2017-09-27

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1002/chem.201702469PMID 28699670
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• On the synthesis, characterization and reactivity of N-heteroaryl-boryl radicals, a new radical class based on five-membered ring ligands.

  2014cited by this paper
• Polarity reversal catalysis in radical reductions of halides by N-heterocyclic carbene boranes.

  2012cited by this paper
• Synthesis and reactions of N-heterocyclic carbene boranes.

  2011cited by this paper
• Komplexe von N‐heterocyclischen Carbenen mit Boranen: Synthese und Reaktionen

  2011cited by this paper
• NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist

  2010cited by this paper
• Tin-free radical cyclization reactions initiated by visible light photoredox catalysis.

  2010cited by this paper
• N-Heterocyclic Carbenes−Borane Complexes: A New Class of Initiators for Radical Photopolymerization

  2010cited by this paper
• Corrigendum: Borane–Lewis Base Complexes as Homolytic Hydrogen Atom Donors

  2010cited by this paper
• Borane-lewis base complexes as homolytic hydrogen atom donors.

  2010cited by this paper
• Estimated rate constants for hydrogen abstraction from N-heterocyclic carbene-borane complexes by an alkyl radical.

  2010cited by this paper
• Electron-transfer photoredox catalysis: development of a tin-free reductive dehalogenation reaction.

  2009cited by this paper
• The performance of computational techniques in locating the charge separated intermediates in organocatalytic transformations

  2009cited by this paper
• Complexes of borane and N-heterocyclic carbenes: a new class of radical hydrogen atom donor.

  2008cited by this paper
• Tin, Silicon and Related Reducing Agents

  2008cited by this paper
• (Me3Si)3SiH: twenty years after its discovery as a radical-based reducing agent.

  2008cited by this paper
• Comprehensive handbook of chemical bond energies

  2007influential reference
• Removal, recovery, and recycling of triarylphosphonium-supported tin reagents for various organic transformations.

  2007cited by this paper
• Tin-free and catalytic radical cyclizations.

  2007cited by this paper
• Evolution of functional cyclohexadiene-based synthetic reagents: the importance of becoming aromatic.

  2005cited by this paper
• Design of polyaromatic hydrocarbon-supported tin reagents: a new family of tin reagents easily removable from reaction mixtures.

  2004cited by this paper
• G3-RAD and G3X-RAD: Modified Gaussian-3 (G3) and Gaussian-3X (G3X) procedures for radical thermochemistry

  2003cited by this paper
• Tin Hydride Substitutes in Reductive Radical Chain Reactions

  2002cited by this paper
• An Assessment of the Performance of High-Level Theoretical Procedures in the Computation of the Heats of Formation of Small Open-Shell Molecules

  2002cited by this paper
• The mechanism of polarity-reversal catalysis as involved in the radical-chain reduction of alkyl halides using the silane–thiol couple

  2002cited by this paper
• A tin hydride designed to facilitate removal of tin species from products of stannane-mediated radical reactions.

  2002cited by this paper
• Absolute rate constants for some reactions of the triethylamine-boryl radical and the borane radical anion

  2001cited by this paper
• Triethylborane‐Induced Radical Reaction with Schwartz Reagent.

  2001cited by this paper
• Hydrogen Donor Abilities of the Group 14 Hydrides

  1999cited by this paper
• Fluorous tin hydrides: A new family of reagents for use and reuse in radical reactions

  1999cited by this paper
• Polarity-reversal catalysis of hydrogen-atom abstraction reactions: concepts and applications in organic chemistry

  1999cited by this paper
• Convenient Catalytic Free Radical Reductions of Alkyl Halides Using an Organotin Reagent on Non-Cross-Linked Polystyrene Support

  1999cited by this paper
• Determination of Bond Dissociation Enthalpies in Solution by Photoacoustic Calorimetry

  1999cited by this paper
• Phosphine-boranes as selective reagents for the radical deoxygenation of a hindered secondary alcohol

  1998cited by this paper
• Flight from the Tyranny of Tin: The Quest for Practical Radical Sources Free from Metal Encumbrances.

  1998cited by this paper
• Flucht vor der Tyrannei des Zinns: auf der Suche nach metallfreien Radikalquellen

  1998cited by this paper
• Homolytic Reactivity of Ligated Boranes toward Alkyl, Alkoxyl, and Peroxyl Radicals

  1996cited by this paper
• Organotin Hydride-Catalyzed Conjugate Reduction of alpha,beta-Unsaturated Ketones.

  1996cited by this paper
• Homolytic reactions of ligated boranes. Part 9. Overall addition of alkanes to electron-deficient alkenes by a radical chain mechanism

  1988cited by this paper
• Tri-n-butyltin Hydride as Reagent in Organic Synthesis

  1988cited by this paper
• Homolytic reactions of ligated boranes. Part 5. Spin-trapping and other addition reactions of ligated boryl radicals

  1987cited by this paper
• A catalytic tin system for trapping of radicals from cyclization reactions. Regio- and stereocontrolled formation of two adjacent chiral centers

  1986cited by this paper
• Homolytic reactions of ligated boranes. Part 4. Electron spin resonance studies of radicals derived from secondary phosphine–boranes

  1986cited by this paper
• An electron spin resonance study of phosphine-boryl radicals; their structures and reactions with alkyl halides

  1984cited by this paper
• The lewis acid catalyzed reaction of trans-hyponitrite ion with alkyl halides

  1983cited by this paper

• Deconstructive Alkylation of Unstrained Cyclic Amines via Lewis Base-Boryl Radical-Enabled Spin-Center Shift.

  2026cites this paper
• Remote Spin-Center Shift Enables Activation of Distal Benzylic C-O and C-N Bonds.

  2025cites this paper
• Boryls, their compounds and reactivity: a structure and bonding perspective

  2024cites this paper
• Quenching Rate Constants of Lewis Base-Boryl Radical by Substrates: a Laser Flash Photolysis Study.

  2024cites this paper
• C(sp3)-F Bond Activation by Lewis Base-Boryl Radicals via Concerted Electron-Fluoride Transfer.

  2024cites this paper
• Controllable Hydrodebromination of Tribromomethyl Groups via Lewis Base–Borane-Mediated Ionic and Radical Pathways

  2024cites this paper
• Photoinduced Intermolecular Radical Hydroalkylation of Olefins via Ligated Boryl Radicals-Mediated Halogen Atom Transfer

  2024cites this paper
• Photoinduced Borylation of the Inert C(sp3)-O Bond of Alkyl Heteroaryl Ethers.

  2023cites this paper
• Boryl Radical-Promoted Dehydroxylative Alkylation of 3-Hydroxyoxindole Derivatives.

  2023cites this paper
• Visible-light Enabled Dehydroxylative Alkylation of α-Hydroxy Carboxylic Acid Derivatives via C-O Bond Cleavage.

  2023cites this paper
• Stereoselective hydrogen atom transfer to acyclic radicals: a switch enabling diastereodivergent borylative radical cascades

  2022cites this paper
• Boryl Radicals Enabled a Three-Step Sequence to Assemble All-Carbon Quaternary Centers from Activated Trichloromethyl Groups.

  2022cites this paper
• One‐pot sulfa‐Michael addition reactions of disulfides using a pyridine‐borane complex under blue light irradiation

  2022cites this paper
• Stereoselective hydrogen atom transfer to acyclic radicals: a switch enabling diastereodivergent borylative radical cascades

  2022cites this paper
• Di‐ Tert ‐Butyl Hyponitrite

  2021cites this paper
• DFT investigation of hydrogen atom-abstraction reactions of NHC-boranes by various carbon-centered radicals: barriers and correlation analyses

  2020cites this paper