Crystallization and phase separation in nonadditive binary hard-sphere mixtures

We calculate for the first time the full phase diagram of an asymmetric nonadditivehard-sphere mixture. The nonadditivity strongly affects the crystallization and the fluid-fluid phase separation. The global topology of the phase diagram is controlled by an effective size ratio y(eff), while the fluid-solid coexistence scales with the depth of the effective potential well.

• Publication year

  1999

• Venue

  Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

• Publication date

  1999-11-23

• Fields of study

  Medicine, Materials Science, Physics

• Identifiers
  DOI 10.1103/PhysRevE.61.R1028arXiv cond-mat/9911384PMID 11046530
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

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