Entropy of Mixing and the Glass Transition of Amorphous Mixtures

No abstract is available for this paper.

• Publication year

  2008

• Venue

  Entropy

• Publication date

  2008-08-26

• Fields of study

  Materials Science, Physics, Computer Science

• Identifiers
  DOI 10.3390/entropy-e10030207
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• Calorimetric study and modeling of molecular mobility in amorphous organic pharmaceutical compounds using a modified Adam-Gibbs approach.

  2007cited by this paper
• Ideal copolymers and the second‐order transitions of synthetic rubbers. i. non‐crystalline copolymers

  2007cited by this paper
• Metastable liquids

  2002cited by this paper
• Supercooled liquids and the glass transition

  2001cited by this paper
• The glass transition temperature of random copolymers: 2. Extension of the Gordon-Taylor equation for asymmetric Tg vs composition curves

  1997cited by this paper
• Conformational Entropy Contributions to the Glass Temperature of Blends of Miscible Polymers

  1997cited by this paper
• Configurational Entropy Approach to the Kinetics of Glasses

  1997cited by this paper
• Metastable Liquids: Concepts and Principles

  1996cited by this paper
• Relationship between the glass transition temperature and the interaction parameter of miscible binary polymer blends

  1992cited by this paper
• Viscous liquids and glass transitions: the linear response regime

  1991cited by this paper
• Effect of hydrogen bonding on the enthalpy of mixing and the composition dependence of the glass transition temperature in polymer blends

  1991cited by this paper
• Aspects of the glass transition behaviour of mixtures of carbohydrates of low molecular weight.

  1990cited by this paper
• On the physical meaning of the Kwei equation for the glass transition temperature of polymer blends

  1989cited by this paper
• Glass temperature mixing relations and thermodynamics

  1985cited by this paper
• The effect of hydrogen bonding on the glass transition temperatures of polymer mixtures

  1984cited by this paper
• Polymer-Polymer Miscibility

  1979cited by this paper
• Contribution of the Conformational Specific Heat of Polymer Chains to the Specific Heat Difference between Liquid and Glass

  1978cited by this paper
• Glass transition temperatures for simple molecular liquids and their binary solutions

  1978cited by this paper
• A Classical Thermodynamic Discussion of the Effect of Composition on Glass-Transition Temperatures

  1978influential reference
• The composition dependence of glass transition properties

  1977cited by this paper
• Viscous liquids and the glass transition. VII. Molecular mechanisms for a thermodynamic second order transition

  1977cited by this paper
• Effect of association complexes on the glass transition in organic halide mixtures

  1976influential reference
• On the glass transition in organic halide–alcohol mixtures

  1975cited by this paper
• On the Temperature Dependence of Cooperative Relaxation Properties in Glass‐Forming Liquids

  1965cited by this paper
• On a General Relation Involving the Glass Temperature and Coefficients of Expansion of Polymers

  1962cited by this paper
• Influence of Diluent and of Copolymer Composition on the Glass Temperature of a Poly-mer System

  1956cited by this paper
• Die Erniedrigung der Einfriertemperatur organischer Gläser durch Lösungsmittel

  1953cited by this paper
• The Nature of the Glassy State and the Behavior of Liquids at Low Temperatures.

  1948cited by this paper

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• Research progress of amorphous micro-nano structured materials

  2025cites this paper
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• Nanoscale partitioning of carbon black in styrene butadiene rubber and butadiene rubber miscible blends and its effect on physico-mechanical properties

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• Prediction of the Synergistic Glass Transition Temperature of Coamorphous Molecular Glasses Using Activity Coefficient Models.

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• Poly(vinylidenefluoride) polymers and copolymers as versatile hosts for luminescent solar concentrators: compositional tuning for enhanced performance

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• Thermal and mechanical properties of glass fibre reinforced polyphenylene ether/polystyrene/nylon-6 ternary blends

  2020cites this paper
• Coarse-graining strategy for modeling effective, highly diffusive fluids with reduced polydispersity: A dynamical study.

  2020cites this paper
• The impact of various azole antifungals on the liquid crystalline ordering in itraconazole

  2020cites this paper
• Anticrystal Engineering of Ketoprofen and Ester Local Anesthetics: Ionic Liquids or Deep Eutectic Mixtures?

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  2020cites this paper
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  2020cites this paper
• Application of a mixture DOE for the prediction of formulation critical temperatures during lyophilisation process optimisation.

  2019cites this paper
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  2019cites this paper
• 4D printing and stimuli-responsive materials in biomedical aspects.

  2019cites this paper
• The production and characterisation of itraconazole multicomponent systems

  2019cites this paper
• Impact of Plasticizer Addition on Molecular Properties of Polybutadiene Rubber and its Manifestations to Glass Transition Temperature

  2019cites this paper
• The Cooling Rate and Volatility Dependent Glass Forming Properties of Organic Aerosols Measured by Broadband Dielectric Spectroscopy.

  2019cites this paper
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  2018cites this paper
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  2018cites this paper
• Investigation of Ethylene Oxide-co-propylene Oxide for Dissolution Enhancement of Hot-Melt Extruded Solid Dispersions.

  2018cites this paper
• Dispositivos micromecânicos para caracterização de materiais: instrumentação e análise térmica de polí­meros.

  2018cites this paper
• Formulation and characterisation of dissolving microneedles for the transdermal delivery of therapeutic peptides.

  2017cites this paper
• Glass transition prediction strategies based on the Couchman-Karasz equation in model confectionary systems

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• Development of Novel Transdermal Drug Delivery Technologies for Therapeutic Peptides

  2017cites this paper
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  2017cites this paper
• Introduction to Non-Equilibrium States and Glass Transitions—The Fundamentals Applied to Foods Systems

  2017cites this paper
• Phosphorescent properties of riboflavin and its potential applications in food quality and food safety

  2016cites this paper
• Influence of PVP/VA copolymer composition on drug-polymer solubility.

  2016cites this paper
• Application of Glass Transition in Food Processing

  2016cites this paper
• Glass‐Transition Phenomena in Polymer Blends

  2016cites this paper
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• Preparation and characterization of poly(lactic acid)/poly(methyl methacrylate) blend tablets for application in quantitative analysis by micro Raman spectroscopy

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• Polyurethane coatings based on chemically unmodified fractionated lignin

  2015cites this paper
• Unveiling the Dependence of Glass Transitions on Mixing Thermodynamics in Miscible Systems

  2015cites this paper
• The characterization and dissolution performances of spray dried solid dispersion of ketoprofen in hydrophilic carriers

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• Bi-modal polymer networks: Composition-dependent trends in thermal, volumetric and structural properties from molecular dynamics simulation

  2015cites this paper
• Comparative Study of Different Methods for the Prediction of Drug-Polymer Solubility.

  2015cites this paper
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  2015cites this paper
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  2014cites this paper
• Solubility Enhancement and Precipitation Inhibition of Poorly Water Soluble Compounds Utilizing Hot Melt Extrusion Technology

  2014cites this paper
• Frying of Foods

  2014cites this paper
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  2013cites this paper
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  2013cites this paper
• The evaluation of larch arabinogalactan as a new carrier in the formulation of solid dispersions of poorly water- soluble drugs

  2013cites this paper
• Experimental evidence for excess entropy discontinuities in glass-forming solutions.

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  2012cites this paper
• Systematic tailoring of water absorption in photopolymerizable (meth)acrylate networks and its effect on mechanical properties

  2012cites this paper
• Unusual dielectric strength of Debye relaxation in monohydroxy alcohols upon mixing.

  2012cites this paper
• Relating hydrogen-bonding interactions with the phase behavior of naproxen/PVP K 25 solid dispersions: evaluation of solution-cast and quench-cooled films.

  2012cites this paper
• Review: Use of Thermal, Diffraction, and Vibrational Analytical Methods to Determine Mechanisms of Solid Dispersion Stability

  2012cites this paper
• Interfacial interactions between biomolecules and materials

  2012cites this paper
• A comparative study of spray-dried and freeze-dried hydrocortisone/polyvinyl pyrrolidone solid dispersions

  2011cites this paper
• Heat capacity and glass transition in P2O5-H2O solutions: support for Mishima's conjecture on solvent water at low temperature.

  2011cites this paper
• Prediction of the Glass Transition Temperature on Extruded Waxy Maize and Rice Starches in Presence of Glycerol

  2010cites this paper
• Influence of Preparation Methods on Solid State Supersaturation of Amorphous Solid Dispersions: A Case Study with Itraconazole and Eudragit E100

  2010cites this paper
• Description and molecular interpretations of anomalous compositional dependences of the glass transition temperatures in binary organic mixtures

  2010cites this paper
• The viscoelastic behavior of polymer/oligomer blends

  2010cites this paper
• Enthalpy relaxation studies of two structurally related amorphous drugs and their binary dispersions

  2010cites this paper
• Review: physical chemistry of solid dispersions.

  2009cites this paper
• Review: physical chemistry of solid dispersions

  2009cites this paper
• The effect of the glass transition temperature on the toughness of photopolymerizable (meth)acrylate networks under physiological conditions.

  2009cites this paper
• Transition vitreuse et hétérogénéités dynamiques dans les liquides moléculaires et les polymères

  2009cites this paper
• A Review on Methods and Theories to Describe the Glass Transition Phenomenon: Applications in Food and Pharmaceutical Products

  2009influential citation
• Consequence of excess configurational entropy on fragility: the case of a polymer-oligomer blend.

  2009cites this paper
• Probing chemical disorder in glasses using silicon-29 NMR spectral editing.

  2009cites this paper
• Gibbs Paradox and Similarity Principle

  2008cites this paper