Spin-alignment echo NMR: probing Li+ hopping motion in the solid electrolyte Li7La3Zr2O12 with garnet-type tetragonal structure

No abstract is available for this paper.

• Publication year

  2012

• Venue

  Journal of Physics: Condensed Matter

• Publication date

  2012-01-25

• Fields of study

  Physics, Medicine, Materials Science, Chemistry

• Identifiers
  DOI 10.1088/0953-8984/24/3/035901PMID 22179497
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• Diffusion in Condensed Matter: Methods, Materials, Models

  2012cited by this paper
• Li ion diffusion in the anode material Li12Si7: ultrafast quasi-1D diffusion and two distinct fast 3D jump processes separately revealed by 7Li NMR relaxometry.

  2011cited by this paper
• Li self-diffusion in garnet-type Li7La3Zr2O12as probed directly by diffusion-inducedLi7spin-lattice relaxation NMR spectroscopy

  2011cited by this paper
• Instability of the Lithium Garnet Li7La3Sn2O12: Li+/H+ Exchange and Structural Study

  2011cited by this paper
• Synthesis, Crystal Structure and Lithium Motion of Li8SeN2 and Li8TeN2

  2010cited by this paper
• Synthesis of Li4V(PO4)2F2 and 6,7Li NMR studies of its lithium ion dynamics

  2010cited by this paper
• Time-Resolved and Site-Specific Insights into Migration Pathways of Li+ in α-Li3VF6 by 6Li 2D Exchange MAS NMR

  2010cited by this paper
• Ultra-slow Li ion dynamics in Li2C2—on the similarities of results from 7Li spin-alignment echo NMR and impedance spectroscopy

  2010cited by this paper
• Tailor-made development of fast Li ion conducting garnet-like solid electrolytes.

  2010cited by this paper
• Nitrides with Inverse K2[NiF4] Structure: (R1-xCa3+xN1-x/3)Bi2 with R=Rare Earth Metal

  2010cited by this paper
• Reaction mechanisms of Li(0.30)La(0.57)TiO3 powder with ambient air: H+/Li+ exchange with water and Li2CO3 formation.

  2010cited by this paper
• NMR Multi-Time Correlation Functions of Ion Dynamics in Solids

  2010cited by this paper
• Study of Lithium Dynamics in Monoclinic Li3Fe2(PO4)3 using 6Li VT and 2D Exchange MAS NMR Spectroscopy

  2010cited by this paper
• Structure and ionic conductivity in lithium garnets

  2010cited by this paper
• Diffusion in Confined Dimensions : Li+ Transport in Mixed Conducting TiO2-B Nanowires

  2009cited by this paper
• Li diffusion properties of mixed conducting TiO2 -B nanowires

  2009cited by this paper
• Synthesis and structure analysis of tetragonal Li7La3Zr2O12 with the garnet-related type structure

  2009cited by this paper
• Diffusion parameters in single-crystalline Li3N as probed by 6Li and 7Li spin-alignment echo NMR spectroscopy in comparison with results from 8Li β-radiation detected NMR

  2008cited by this paper
• Li jump process in h- Li0.7 Ti S2 studied by two-time Li7 spin-alignment echo NMR and comparison with results on two-dimensional diffusion from nuclear magnetic relaxation

  2008cited by this paper
• Mistimed stimulated echoes and distorted spin-alignment spectra of powdered solids.

  2008cited by this paper
• Switching on fast lithium ion conductivity in garnets : the structure and transport properties of Li3+xNd3Te2-xSbxO12

  2008cited by this paper
• Nanomaterials for rechargeable lithium batteries.

  2008cited by this paper
• Structure and lithium ion conductivity of garnet-like Li5La3Sb2O12 and Li6SrLa2Sb2O12

  2008cited by this paper
• Lithium ionic jump motion in the fast solid ion conductor Li(5)La(3)Nb(2)O(12).

  2008cited by this paper
• Atomic-scale measurement of ultraslow Li motions in glassyLiAlSi2O6by two-timeL6ispin-alignment echo NMR correlation spectroscopy

  2008cited by this paper
• Li 6 and Li 7 NMR line-shape and stimulated-echo studies of lithium ionic hopping in Li P O 3 glass

  2008cited by this paper
• Ultraslow Li diffusion in spinel-type structured Li4Ti5O12 - a comparison of results from solid state NMR and impedance spectroscopy.

  2007cited by this paper
• The mechanism of Li-ion transport in the garnet Li5La3Nb2O12.

  2007cited by this paper
• Spin relaxation and ultra-slow Li motion in an aluminosilicate glass ceramic.

  2007cited by this paper
• Microscopic access to long-range diffusion parameters of the fast lithium ion conductor Li7BiO6 by solid state 7Li stimulated echo NMR.

  2007cited by this paper
• Diffusion in solids : fundamentals, methods, materials, diffusion-controlled processes

  2007cited by this paper
• Solid-State Li NMR with Applications to the Translational Dynamics in Ion Conductors

  2007cited by this paper
• 7Li NMR and Two-Dimensional Exchange Study of Lithium Dynamics in Monoclinic Li3V2(PO4)3

  2006cited by this paper
• (7)Li NMR and two-dimensional exchange study of lithium dynamics in monoclinic Li(3)V(2)(PO(4))(3).

  2006cited by this paper
• Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries

  2006cited by this paper
• From ultraslow to fast lithium diffusion in the 2D ion conductor Li0.7TiS2 probed directly by stimulated-echo NMR and nuclear magnetic relaxation.

  2006cited by this paper
• Extremely slow cation exchange processes in Li4SiO4 probed directly by two-time 7Li stimulated-echo nuclear magnetic resonance spectroscopy

  2006cited by this paper
• Spin relaxation and ultra-slow Li transport in an aluminosilicate glass ceramic

  2006cited by this paper
• Investigations on electrical conductivity and chemical compatibility between fast lithium ion conducting garnet-like Li6BaLa2Ta2O12 and lithium battery cathodes

  2005cited by this paper
• Nanostructured materials for advanced energy conversion and storage devices

  2005cited by this paper
• Ex situ nmr and neutron diffraction study of structure and lithium motion in Li7MnN4

  2005cited by this paper
• Simple modeling of dipolar coupled 7Li spins and stimulated-echo spectroscopy of single-crystalline beta-eucryptite.

  2004cited by this paper
• Lithium Storage in Nanostructured TiO2 Made by Hydrothermal Growth

  2004cited by this paper
• Lithium batteries and cathode materials.

  2004cited by this paper
• Stimulated-echo NMR spectroscopy of 9Be and 7Li in solids

  2002cited by this paper
• On the structure of Li3Ti2(PO4)3

  2002cited by this paper
• Stimulated-echo NMR spectroscopy of 9Be and 7Li in solids: method and application to ion conductors.

  2002cited by this paper
• Lithium dynamics in LiMn2O4 probed directly by two-dimensional (7)Li NMR.

  2001cited by this paper
• Issues and challenges facing rechargeable lithium batteries

  2001cited by this paper
• 7 Li MAS NMR study of electrochemically deintercalated LixNi0.30Co0.70O2 phases: evidence of electronic and ionic mobility, and redox processes

  2001cited by this paper
• Multiple-time correlation functions in spin-3/2 solid-state NMR spectroscopy

  2000cited by this paper
• Multiple-time correlation functions in spin-3/2 solid-state NMR spectroscopy

  2000cited by this paper
• Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries

  2000cited by this paper
• Stimulated 7Li echo NMR spectroscopy of slow ionic motions in a solid electrolyte

  2000cited by this paper
• Diffusion mechanisms in metallic supercooled liquids and glasses

  1999cited by this paper
• Electrochemical lithiation of tin and tin-based intermetallics and composites

  1999cited by this paper
• Alignment echo of spin-3/2 9Be nuclei: detection of ultraslow motion

  1998cited by this paper
• Slow Atomic Motion in Zr-Ti-Cu-Ni-Be Metallic Glasses Studied by NMR

  1998cited by this paper
• Cation Dynamics and Diffusion in Lithium Orthosilicate: Two-Dimensional Lithium-6 NMR

  1995cited by this paper
• NMR studies of superionic conductors

  1992cited by this paper
• E. Fukushima, St. B. W. Roeder: Experimental Pulse NMR. A Nuts and Bolts Approach. Addison‐Wesley Publ. Comp., Inc., Reading, Massachusetts 1981. 539 Seiten, Preis: US $ 34.50

  1983cited by this paper
• Nuclear Magnetic Resonance in Solids: Thermodynamic Effects of a Pair of rf Pulses

  1967cited by this paper

• Simulating quadrupolar NMR dynamics in solid electrolyte Li10GeP2S12.

  2026cites this paper
• Predicting solid electrolyte fracture by stress-mediated dendrite penetration in cracks

  2025cites this paper
• Solid-state nuclear magnetic resonance for garnet-type based solid lithium electrolytes

  2025cites this paper
• Revealing the Local Structure and Dynamics of the Solid Li Ion Conductor Li3P5O14

  2024cites this paper
• Clarifying the Dopant Local Structure and Effect on Ionic Conductivity in Garnet Solid-State Electrolytes for Lithium-Ion Batteries

  2023cites this paper
• Dynamics of Interlayer Na-Ions in Ga-Substituted Na2Zn2TeO6 (NZTO) Studied by Variable-Temperature Solid-State 23Na NMR Spectroscopy and DFT Modeling

  2023cites this paper
• Phase transformation and grain-boundary segregation in Al-Doped Li7La3Zr2O12 ceramics

  2021cites this paper
• Na9In(MoO4)6: synthesis, crystal structure, and Na+ ion diffusion

  2021cites this paper
• Tracking Ions the Direct Way: Long-Range Li+ Dynamics in the Thio-LISICON Family Li4MCh4 (M = Sn, Ge; Ch = S, Se) as Probed by 7Li NMR Relaxometry and 7Li Spin-Alignment Echo NMR

  2021cites this paper
• NMR Investigations of Crystalline and Glassy Solid Electrolytes for Lithium Batteries: A Brief Review

  2020cites this paper
• NMR studies of Li mobility in NASICON-type glass-ceramic ionic conductors with optimized microstructure

  2019cites this paper
• Magnetic resonance spectroscopy approaches for electrochemical research

  2018cites this paper
• Diffusion coefficient of lithium ions in garnet-type Li6.5La3Zr1.5Ta0.5O12 single crystal probed by 7Li pulsed field gradient-NMR spectroscopy

  2018cites this paper
• Lattice-geometry effects in garnet solid electrolytes: a lattice-gas Monte Carlo simulation study

  2017cites this paper
• Recent advances in all-solid-state rechargeable lithium batteries

  2017cites this paper
• Stability of low-temperature Li7La3Zr2O12 cubic phase: The role of temperature and atmosphere

  2017cites this paper
• Observing different modes of mobility in lithium titanate spinel by nuclear magnetic resonance

  2017cites this paper
• Lithium ion micrometer diffusion in a garnet-type cubic Li7La3Zr2O12 (LLZO) studied using 7Li NMR spectroscopy.

  2017cites this paper
• Dielectric characteristics of fast Li ion conducting garnet-type Li5+2xLa3Nb2-xYxO12 (x = 0.25, 0.5 and 0.75).

  2016cites this paper
• Coexistence of Two Types of Lithium Motion in Monoclinic Li2HfO3: 6,7Li NMR and Ab Initio Calculation Results

  2016cites this paper
• Solid-State NMR Studies of Lithium Ion Dynamics Across Materials Classes

  2016cites this paper
• Diffusion-induced 7Li NMR spin-lattice relaxation of fully lithiated, mixed-conducting Li7Ti5O12

  2016cites this paper
• NMR study of Li distribution in Li7−xHxLa3Zr2O12 garnets

  2015cites this paper
• Ion Dynamics in Solid Electrolytes: NMR Reveals the Elementary Steps of Li+ Hopping in the Garnet Li6.5La3Zr1.75Mo0.25O12

  2015cites this paper
• Quadrupolar transients, cosine correlation functions, and two-dimensional exchange spectra of non-selectively excited spin-3/2 nuclei: A (7)Li NMR study of the superionic conductor lithium indium phosphate.

  2015cites this paper
• Lithium ion diffusion measurements on a garnet-type solid conductor Li6.6La3Zr1.6Ta0.4O12 by using a pulsed-gradient spin-echo NMR method.

  2015cites this paper
• The use of 6Li{7Li}-REDOR NMR spectroscopy to compare the ionic conductivities of solid-state lithium ion electrolytes.

  2014cites this paper
• Anomalous lithium ion migration in the solid electrolyte (Li2S)7(P2S5)3; fast ion transfer at short time intervals studied by PGSE NMR spectroscopy

  2014cites this paper
• DFT Study of the Role of Al3+ in the Fast Ion-Conductor Li7–3xAl3+xLa3Zr2O12 Garnet

  2014cites this paper
• Chemometric methods in NMR spectroscopic analysis of food products

  2013cites this paper
• Lithium ion diffusion in solid electrolyte (Li2S)7(P2S5)3 measured by pulsed-gradient spin-echo 7Li NMR spectroscopy

  2013cites this paper
• Studying Li Dynamics in a Gas-Phase Synthesized Amorphous Oxide by NMR and Impedance Spectroscopy

  2012cites this paper
• NA

  2006cites this paper