Electrophilicities of symmetrically substituted 1,3-diarylallyl cations.

No abstract is available for this paper.

• Publication year

  2011

• Venue

  Journal of Organic Chemistry

• Publication date

  2011-10-19

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1021/jo201668wPMID 21939207
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• Reply to T. W. Bentley: Limitations of the s(E+N) and Related Equations

  2011cited by this paper
• Palladium-catalyzed selective heck-type diarylation of allylic esters with aryl halides involving a β-OAc elimination process.

  2011cited by this paper
• Direct Nucleophilic SN1‐Type Reactions of Alcohols

  2011cited by this paper
• Electrophilic Reactivity of the α,α-Dimethylbenzyl (Cumyl) Cation

  2010cited by this paper
• Electrophilicity versus electrofugality of tritylium ions in aqueous acetonitrile.

  2010cited by this paper
• First-principles prediction of nucleophilicity parameters for pi nucleophiles: implications for mechanistic origin of Mayr's equation.

  2010cited by this paper
• Can one predict changes from S(N)1 to S(N)2 mechanisms?

  2009cited by this paper
• Nucleophilic Reactivities of Primary and Secondary Amines in Acetonitrile

  2009cited by this paper
• How to predict changes in solvolysis mechanisms

  2009cited by this paper
• The syntheses, structures and nonlinear optical and related properties of salts with julolidinyl electron donor groups

  2009cited by this paper
• Assessment of theoretical methods for the calculation of methyl cation affinities

  2008cited by this paper
• Chapter 9 The electrophilicity index in organic chemistry

  2007cited by this paper
• The influence of tetrahydroquinoline rings in dicyanomethylenedihydrofuran (DCDHF) single-molecule fluorophores

  2007cited by this paper
• Brønsted Acid‐Catalyzed Nucleophilic Substitution of Alcohols

  2006cited by this paper
• Kinetics of the reactions of halide anions with carbocations: quantitative energy profiles for s(n)1 reactions.

  2005cited by this paper
• Solvent nucleophilicity.

  2004cited by this paper
• Pi-nucleophilicity in carbon-carbon bond-forming reactions.

  2003cited by this paper
• Dissertation zur Erlangung des Doktorgrades der Fakultät für Chemie und Pharmazie der Ludwig-Maximilians-Universität München Construction and Application of Reference Scales for the Characterization of Cationic Electrophiles and Neutral Nucleophiles

  2003cited by this paper
• Nucleophilic reactivities of carbanions in water: the unique behavior of the malodinitrile anion.

  2003cited by this paper
• An efficient palladium-catalyzed synthesis of cinnamaldehydes from acrolein diethyl acetal and aryl iodides and bromides.

  2003cited by this paper
• Asymmetric transition-metal-catalyzed allylic alkylations: applications in total synthesis.

  2003cited by this paper
• π-Nucleophilicity in Carbon−Carbon Bond-Forming Reactions

  2003cited by this paper
• Synthesis and Pharmacological Investigations of Some 4‐Hydroxycoumarin Derivatives

  2003cited by this paper
• Determination of the electrophilic reactivities of 1,1,3-triarylallyl cations

  2002cited by this paper
• Relationships between carbocation stabilities and electrophilic reactivity parameters, E: quantum mechanical studies of benzhydryl cation structures and stabilities.

  2002cited by this paper
• Kinetic studies of carbocation-carbanion combinations: key to a general concept of polar organic reactivity.

  2002cited by this paper
• Pd asymmetric allylic alkylation (AAA). A powerful synthetic tool.

  2002cited by this paper
• Tandem Addition -Lithiation-Alkylation Sequence on a,-Unsaturated Aldehydes

  2001cited by this paper
• Tandem addition beta-lithiation-alkylation sequence on alpha,beta-unsaturated aldehydes.

  2001cited by this paper
• COMPARISON OF THE ELECTROPHILICITIES OF THE FREE AND THE (TRICARBONYL)IRON-COORDINATED TROPYLIUM ION

  1999cited by this paper
• Flash Photolysis of 1,3-Dichloro-1,3-diphenylpropane in Polar Solvents: Generation of a Stabilized γ-Chloropropyl Cation, Subsequent Formation of a Propenyl Cation, and Nucleophilic Trapping of Both Cations

  1998cited by this paper
• Asymmetric Transition Metal-Catalyzed Allylic Alkylations.

  1996cited by this paper
• A survey of Hammett substituent constants and resonance and field parameters

  1991cited by this paper
• Kinetics of the reactions of allylsilanes, allylgermanes, and allylstannanes with carbenium ions

  1991cited by this paper
• Addition reactions of diarylcarbenium ions to 2-methyl-1-pentene: kinetic method and reaction mechanism

  1990cited by this paper
• A novel probe for free radicals featuring epoxide cleavage

  1990cited by this paper
• SN2' Additions of organocopper reagents to vinyloxiranes

  1989cited by this paper
• Asymmetric synthesis catalyzed by chiral ferrocenylphosphine - transition-metal complexes. 8. Palladium-catalyzed asymmetric allylic amination

  1989cited by this paper
• Totalsynthese des Pseudoguaianolids (+)‐Confertin

  1988cited by this paper
• Relative Reaktivität Alkyl-substituierter Alkene und Cycloalkene gegenüber Diarylcarbenium-Ionen

  1986cited by this paper
• Synthetic Methods and Reactions; Part 109. Improved Preparation of Aldehydes and Ketones from N,N-Dimethylamides and Grignard Reagents

  1984cited by this paper
• Nucleophilic and organometallic displacement reactions of allylic compounds: stereo-and regiochemistry

  1980cited by this paper
• Para products from m-arylcadmium reagents: a cine substitution

  1979cited by this paper
• Stereochemistry of allylic rearrangements. 16. Ion-pair return associated with solvolysis of exo- and endo-bicyclo[3.2.1]oct-3-en-2-yl p-nitrobenzoate in aqueous acetone

  1978cited by this paper
• PMR spectra and transmission of the influence of substituents in diphenyl-carbonium ions and their vinylogs

  1976cited by this paper
• Disguised chemical selectivities

  1976cited by this paper
• Geometric representation of equilibrium thermodynamics

  1976cited by this paper
• Addition-elimination and rearrangement reactions in allylic systems

  1972cited by this paper
• Nucleophilic substitutions in allylic systems. Further evidence against the existence of the concerted SN2' mechanism

  1972cited by this paper
• Are nucleophilic bimolecular concerted reactions involving four or more bonds a myth

  1970cited by this paper
• Chemismus der Farbreaktion zwischen höheren Alkoholen und aromatischen Aldehyden in schwefelsaurem Medium

  1970cited by this paper
• Mechanistic classification of the abnormal allylic substitution (S(sub N)2') reactions

  1968cited by this paper
• Substitution And Rearrangement Reactions Of Allylic Compounds

  1956cited by this paper

• Quantifying the enamine-type nucleophilic reactivity of α-aryl vinyl azides.

  2026cites this paper
• Synthesis and catalytic properties of palladium(II) complexes with P,π-chelating ferrocene phosphinoallyl ligands and their non-tethered analogues.

  2024cites this paper
• Reactivity of Diethyl Benzylidenemalonates with Secondary Cyclic Amine Dimers in Acetonitrile: Structure-Reactivity Relationships and mechanism

  2024cites this paper
• Electrophile-Arene Affinity: An Energy Scale for Evaluating the Thermodynamics of Electrophilic Dearomatization Reactions.

  2024cites this paper
• Methide Affinity Scale: Key Thermodynamic Data Underpinning Catalysis, Organic Synthesis, and Organometallic and Polymer Chemistry.

  2024cites this paper
• When Does Hammond's Postulate Predict Stabilities of Carbocations?

  2023cites this paper
• Electrophilicity index revisited

  2022cites this paper
• Solvent effect, quantification and correlation analysis of the nucleophilicities of cyclic secondary amines

  2022cites this paper
• Dynamics of the dimethyl sulfide exchange of (1,3‐diphenylallyl)dimethylsulfonium ions

  2021cites this paper
• Structure-Property Relationships in Benzofurazan Derivatives: A Combined Experimental and DFT/TD-DFT Investigation

  2021cites this paper
• Quantum Mechanics and Machine Learning Synergies: Graph Attention Neural Networks to Predict Chemical Reactivity

  2021cites this paper
• Quantification of the Electrophilic Reactivities of Benzotriazoles and Structure‐Reactivity Relationships

  2021cites this paper
• Methyl Anion Affinities of the Canonical Organic Functional Groups.

  2020cites this paper
• Three Heterocyclic Rings Fused (6-6-6)

  2020cites this paper
• Electrophilic Reactivities of Vinyl p-Quinone Methides

  2020cites this paper
• Catalytic Stereoselective SN 1-Type Reactions Promoted by Chiral Phosphoric Acids as Brønsted Acid Catalysts

  2018cites this paper
• Water promoted allylic nucleophilic substitution reactions of (E)-1,3 diphenylallyl acetate

  2018cites this paper
• Catalytic activity of chiral chelating N-heterocyclic carbene palladium complexes towards asymmetric allylic alkylation

  2018cites this paper
• Copper‐Catalyzed Asymmetric Allylic Alkylation of β‐Keto Esters with Allylic Alcohols

  2017cites this paper
• A Photo-Triggered Traceless Staudinger-Bertozzi Ligation Reaction.

  2016cites this paper
• Organocatalytic α-Allylation of α-Branched Aldehydes by Synergistic Catalysis of Brønsted Acids and Amines

  2016cites this paper
• Synthesis of chiral S,N-thioimidazoline ligands for palladium-catalyzed asymmetric allylic alkylations

  2016cites this paper
• Biimidazoline ligands for palladium-catalyzed asymmetric allylic alkylation

  2015cites this paper
• Gold(I)-Assisted α-Allylation of Enals and Enones with Alcohols.

  2015cites this paper
• Reaction mechanisms: polar reactions

  2015cites this paper
• Investigation of the photoinduced dynamics of allyl systems by transient absorption spectrocopy

  2014cites this paper
• Direct Synthesis of Allylic Thioethers Under Greener Conditions: A Solvent- and Catalyst-Free Approach

  2014cites this paper
• Synergy, compatibility, and innovation: merging Lewis acids with stereoselective enamine catalysis.

  2014cites this paper
• δ-Deuterium Isotope Effects as Probes for Transition-State Structures of Isoprenoid Substrates

  2014cites this paper
• Contemporary carbocation chemistry: applications in organic synthesis.

  2013cites this paper
• Electrofugalities of 1,3-diarylallyl cations.

  2013cites this paper
• Photogeneration of carbocations: applications in physical organic chemistry and the design of suitable precursors

  2013cites this paper
• Electrophilic Addition of Allylic Carbocations to 2‐Cyclopropylidene‐2‐arylethanols: A Strategy to 3‐Oxabicyclo[3.2.0]heptanes

  2013cites this paper
• Ion pair dynamics: solvolyses of chiral 1,3-diarylallyl carboxylates as a case study.

  2013cites this paper
• How Does Palladium Coordination Affect the Electrophilicities of Allyl Cations? Development of a Robust Kinetic Method for Following Reactions of [(η3-Diarylallyl)Pd(PPh3)2]+ with Nucleophiles

  2012cites this paper
• Photolytic generation of benzhydryl cations and radicals from quaternary phosphonium salts: how highly reactive carbocations survive their first nanoseconds.

  2012cites this paper
• Photogeneration of benzhydryl cations by near-UV laser flash photolysis of pyridinium salts.

  2012cites this paper
• (R,E)-3-(4-Chlorophenyl)-1-phenylallyl 4-nitrobenzoate

  2012influential citation
• Free energy relationships for reactions of substituted benzhydrylium ions: from enthalpy over entropy to diffusion control.

  2012cites this paper