An efficient mechanochemical synthesis of alpha-aluminum hydride: Synergistic effect of TiF3 on the crystallization rate and selective formation of alpha-aluminum hydride polymorph.

α-AlH3 is one of the most promising hydrogen storage materials due to its high gravimetric hydrogen capacity and low dehydriding temperature. In present work, a convenient and cost-efficient solid-state mechanochemical reaction is proposed to obtain α-AlH3 nano-composite. With the addition of TiF3, α-AlH3 nano-composite was formed in a short period by milling of LiH and AlCl3. Based on XRD and NMR results, the average grain size of the α-AlH3 in the nano-composite was 45 nm. The reaction pathway as well as the synergistic effect of TiF3 on the solid state reaction between LiH and AlCl3 were confirmed. In the α-AlH3/LiCl nano-composite, TiF3 reduced the temperature of dehydriding reaction and improved dehydrogenation rate of α-AlH3. Within the temperature range between 80 and 160 °C, dehydrogenation of the as-milled α-AlH3 nano-composite showed fast kinetics. At 160 °C, a maximum hydrogen desorption of 9.92 wt% was obtained within 750 s, very close to the theoretical hydrogen capacity of α-AlH3.

• Publication year

  2019

• Venue

  Journal of Hazardous Materials

• Publication date

  2019-07-01

• Fields of study

  Medicine, Materials Science, Chemistry

• Identifiers
  DOI 10.1016/j.jhazmat.2019.03.064PMID 30909139
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• Femtosecond laser fabrication of shape-gradient platform: Underwater bubbles continuous self-driven and unidirectional transportation

  2019cited by this paper
• Percarbonate promoted antibiotic decomposition in dielectric barrier discharge plasma.

  2019cited by this paper
• Synergistic effect of TiF3 on the dehydriding property of α-AlH3 nano-composite

  2019cited by this paper
• High-performance piezoelectric wind energy harvester with Y-shaped attachments

  2019cited by this paper
• Synthesis of hydrophobic carbon nanotubes/reduced graphene oxide composite films by flash light irradiation

  2018cited by this paper
• Doping effect of Nb species on hydrogen desorption properties of AlH3

  2018cited by this paper
• Improved dye removal and simultaneous electricity production in a photocatalytic fuel cell coupling with persulfate activation

  2018cited by this paper
• The heat and mass transfer characteristics of superheated steam coupled with non-condensing gases in horizontal wells with multi-point injection technique

  2018cited by this paper
• Ionic liquids as an efficient medium for the mechanochemical synthesis of α-AlH3 nano-composites

  2018cited by this paper
• Densification and microstructure of magnesium aluminate spinel for adding method of Sc 2 O 3

  2018cited by this paper
• A novel design concept for fabricating 3D graphene with the assistant of anti-solvent precipitated sulphates and its Li-ion storage properties

  2018cited by this paper
• Oxygen Reduction Reaction on Classically Immiscible Bimetallics: A Case Study of RhAu

  2018cited by this paper
• Ultrafast room-temperature synthesis of hierarchically porous metal–organic frameworks by a versatile cooperative template strategy

  2018cited by this paper
• Robust laser-structured asymmetrical PTFE mesh for underwater directional transportation and continuous collection of gas bubbles

  2018cited by this paper
• Degradation of 2,4-dichlorophenol by activating persulfate and peroxomonosulfate using micron or nanoscale zero-valent copper.

  2018cited by this paper
• Concise Chemistry Modulation of the SMM Behavior within a Family of Mononuclear Dy(III) Complexes.

  2018cited by this paper
• Advanced Monoethanolamine Absorption Using Sulfolane as a Phase Splitter for CO2 Capture.

  2018cited by this paper
• Synthesis of Porous Carbon by Activation Method and its Electrochemical Performance

  2018cited by this paper
• CO2 removal in tray tower by using AAILs activated MDEA aqueous solution

  2018cited by this paper
• Borophene as a promising anode material for sodium-ion batteries with high capacity and high rate capability using DFT

  2018cited by this paper
• Study on electronic properties of α-, β- and γ-AlH 3 – The theoretical approach

  2017cited by this paper
• A NaAlH4-Ca(BH4)2 composite system for hydrogen storage

  2017cited by this paper
• Coligand modifications fine-tuned the structure and magnetic properties of two triple-bridged azido-Cu(ii) chain compounds exhibiting ferromagnetic ordering and slow relaxation.

  2017cited by this paper
• Dehydrogenation Selectivity of Ethanol on Close-Packed Transition Metal Surfaces: A Computational Study of Monometallic, Pd/Au, and Rh/Au Catalysts

  2017cited by this paper
• Gas-Solid Chemisorption/Adsorption and Mechanochemical Selectivity in Dynamic Nonporous Hybrid Metal Organic Materials.

  2017cited by this paper
• Study on the dehydrogenation properties and reversibility of Mg(BH4)2AlH3 composite under moderate conditions

  2017cited by this paper
• Surface passivation of aluminum hydride particles via atomic layer deposition

  2017influential reference
• Hydrogenation/Dehydrogenation Kinetics Study of Reacted Ball Milled (MgH2)100-x/(Ni)y/(Nb2O5)z)x Nanocomposite Powders

  2016cited by this paper
• Experimental determination of dust cloud combustion parameters of α-AlH3 powder in its charged and fully discharged states for H2 storage applications

  2016cited by this paper
• An insight into the process and mechanism of a mechanically activated reaction for synthesizing AlH3 nano-composites.

  2015cited by this paper
• Nano-scale AlN powders and AlN/Al composites by full and partial direct nitridation of aluminum in solid-state

  2015cited by this paper
• Solid state synthesis of nano-sized AlH3 and its dehydriding behaviour

  2015cited by this paper
• Reaction kinetics for the solid state synthesis of the AlH3/MgCl2 nano-composite by mechanical milling.

  2015cited by this paper
• Efficient Synthesis of an Aluminum Amidoborane Ammoniate

  2015cited by this paper
• Single-ion-magnet behavior in a two-dimensional coordination polymer constructed from Co(II) nodes and a pyridylhydrazone derivative.

  2015cited by this paper
• Highly crystalline Fe2GeS4 nanocrystals: green synthesis and their structural and optical characterization

  2015cited by this paper
• Dry mechanochemical synthesis of alane from LiH and AlCl3.

  2014influential reference
• Solvent-free mechanochemical synthesis of alane, AlH3: effect of pressure on the reaction pathway

  2014cited by this paper
• Hydrazine borane-induced destabilization of ammonia borane, and vice versa.

  2014cited by this paper
• Effects of Ti-based catalysts and synergistic effect of SWCNTs-TiF3 on hydrogen uptake and release from MgH2

  2014cited by this paper
• Metal hydride material requirements for automotive hydrogen storage systems

  2013cited by this paper
• Dehydriding properties of γ-AlH3

  2013cited by this paper
• Dehydrogenation process of AlH3 observed by TEM

  2013cited by this paper
• Mechanochemical synthesis of hydrogen storage materials

  2013cited by this paper
• NMR spectroscopic and thermodynamic studies of the etherate and the α, α′, and γ phases of AlH3

  2013cited by this paper
• Improved hydrogen storage performance of MgH2-NaAlH4 composite by addition of TiF3

  2012influential reference
• Effect of several metal chlorides on the thermal decomposition behaviour of α-Mg(BH4)2

  2011cited by this paper
• Kinetics of dehydrogenation of MgH2 and AlH3

  2011cited by this paper
• Aluminum hydride as a hydrogen and energy storage material: Past, present and future

  2011cited by this paper
• Experimental and computational investigations on the AlH3/AlF3 system

  2011cited by this paper
• The Mechanochemical synthesis of magnesium hydride nanoparticles

  2010influential reference
• Hydrogenation of passivated aluminum with hydrogen fluid

  2009cited by this paper
• Mechanochemical synthesis of alane

  2009influential reference
• Characterisation of mechanochemically synthesised alane (AlH3) nanoparticles

  2009influential reference
• Aluminium hydride: a reversible material for hydrogen storage.

  2009cited by this paper
• New approaches to hydrogen storage.

  2009cited by this paper
• Experimental studies of α-AlD3 and α′-AlD3versus first-principles modelling of the alane isomorphs

  2008cited by this paper
• Inherent safety key performance indicators for hydrogen storage systems.

  2008cited by this paper
• “Direct” synthesis of unsolvated aluminum hydride involving Lewis and Bronsted acids

  2008cited by this paper
• Formation and decomposition of AlH3 in the aluminum-hydrogen system

  2008cited by this paper
• Synthesis and Crystal Structure of -AlD3.

  2007cited by this paper
• Double-Bridge Bonding of Aluminium and Hydrogen in the Crystal Structure of γ-AlH3

  2007cited by this paper
• Mechanical and thermal decomposition of LiAlH4 with metal halides

  2007influential reference
• Complex hydrides for hydrogen storage.

  2007cited by this paper
• Closo-alanes (Al4H4, AlnHn+2, 4 <or= n <or= 8): a new chapter in aluminum hydride chemistry.

  2007cited by this paper
• On the Oxidation and Combustion of AlH3 a Potential Fuel for Rocket Propellants and Gas Generators

  2007cited by this paper
• Improving hydrogen sorption kinetics of MgH2 by mechanical milling with TiF3

  2007influential reference
• Double-bridge bonding of aluminium and hydrogen in the crystal structure of gamma-AlH3.

  2007cited by this paper
• NMR studies of the aluminum hydride phases and their stabilities

  2007cited by this paper
• Kinetics and thermodynamics of the aluminum hydride polymorphs

  2007cited by this paper
• Mechano-chemical activation synthesis (MCAS) of nanocrystalline magnesium alanate hydride [Mg(AlH4)2] and its hydrogen desorption properties

  2007cited by this paper
• Non-solvated aluminum hydride. Crystallization from diethyl ether-benzene solutions

  2007cited by this paper
• Mechanochemical synthesis and crystal structure of alpha'-AlD3 and alpha-AlD3.

  2006cited by this paper
• Mechanochemical synthesis and thermal decomposition of Mg(AlH4)2

  2006cited by this paper
• Alkali metal hydride doping of α-AlH3 for enhanced H2 desorption kinetics

  2006cited by this paper
• Mechanochemical synthesis and crystal structure of alpha'-AlD3 and alpha-AlD3.

  2006cited by this paper
• Decomposition kinetics of the AlH3 polymorphs.

  2005cited by this paper
• Cubic and orthorhombic structures off aluminum hydride AlH3 predicted by a first-principles study

  2005cited by this paper
• Hydrogen absorption properties of Li-Mg-N-H system

  2005cited by this paper
• Combustion Characteristics of Aluminum Hydride at Elevated Pressure and Temperature

  2004cited by this paper
• Hydrogen in aluminum: First-principles calculations of structure and thermodynamics

  2004cited by this paper
• Mechanochemical reductive dehalogenation of hazardous polyhalogenated contaminants

  2004cited by this paper
• Rapid solid-state transformation of tetrahedral [AlH4]− into octahedral [AlH6]3− in lithium aluminohydride

  2000cited by this paper
• Solid State Phase Transformations in LiAlH4 During High-Energy Ball-Milling

  2000cited by this paper
• Preparation and properties of aluminum hydride

  1976cited by this paper
• Crystal structure of aluminum hydride

  1969cited by this paper
• The composition of ''mixed hydride'' reagents - A study of the Schlesinger reaction.

  1966cited by this paper
• The Direct Synthesis of Amine Alanes

  1964cited by this paper
• NON-SOLVATED ALUMINUM HYDRIDE

  1955cited by this paper
• Lithium Aluminum Hydrideによる有機化合物の還元

  1950cited by this paper
• Lithium Aluminum Hydride, Aluminum Hydride and Lithium Gallium Hydride, and Some of their Applications in Organic and Inorganic Chemistry1

  1947cited by this paper
• Über einen nichtflüchtigen, polymeren Aluminiumwasserstoff (AlH3)x und einige flüchtige Verbindungen des monomeren AlH3

  1942cited by this paper

• Combinatorial synthesis of solid-state hydrogen storage materials using a modified planetary ball mill

  2025cites this paper
• Transition metal-free Me3SiCl synthesis of α-AlH3 with enhanced thermal stability via dual lithium hydride templating

  2025cites this paper
• Reversible hydrogen storage in AlH3−LiNH2 system

  2025cites this paper
• A Probabilistic Framework for Multicriteria Assessment of 2D Materials for Hydrogen Storage

  2025cites this paper
• AlH3 as High-Energy Fuels for Solid Propellants: Synthesis, Thermodynamics, Kinetics, and Stabilization

  2024cites this paper
• MXenes as catalysts for lightweight hydrogen storage materials: a review

  2024cites this paper
• Meeting the UN Sustainable Development Goals with Mechanochemistry

  2024cites this paper
• 2D materials for enabling hydrogen as an energy vector

  2024cites this paper
• Superior catalytic effect of Bi@C on dehydrogenation performance of α-AlH3

  2023cites this paper
• Reduction of agglomeration effect by aluminum trihydride in solid propellant combustion

  2023cites this paper
• Highly selective and sensitive fluorescent “TURN-ON” furan-based Schiff base for zinc(ii) ion probing: chemical synthesis, DFT studies, and X-ray crystal structure

  2023cites this paper
• High-Energy Composite Fuels with Improved Combustion Efficiency by Using AlH3 Embedded with Al Particles.

  2023cites this paper
• An integrated computational and experimental method for predicting hydrogen plateau pressures of TiFe1-xMx-based room temperature hydrides

  2022cites this paper
• Achieving both high hydrogen capacity and low decomposition temperature of the metastable AlH3 by proper ball milling with TiB2

  2022cites this paper
• Recent Development in Nanoconfined Hydrides for Energy Storage

  2022cites this paper
• Stability, reactivity and decomposition kinetics of surface passivated α-AlH3 crystals

  2022cites this paper
• Superior Dehydrogenation Performance of α-AlH3 Catalyzed by Li3 N: Realizing 8.0 wt.% Capacity at 100 °C.

  2022cites this paper
• Unraveling the Synergistic Catalytic Effects of TiO2 and Pr6O11 on Superior Dehydrogenation Performances of α-AlH3.

  2021cites this paper
• Preparation of plasmonic CoS/Ag2WO4 nanocomposites: Efficient visible light driven photocatalysts and enhanced anti-microbial activity

  2021cites this paper
• AlH3 as a hydrogen storage material: recent advances, prospects and challenges

  2021cites this paper
• Excellent catalytic effect of LaNi5 on hydrogen storage properties for aluminium hydride at mild temperature

  2021cites this paper
• On the long-term cyclic stability of near-eutectic Mg–Mg2Ni alloys

  2021cites this paper
• Aluminum hydride for solid-state hydrogen storage: Structure, synthesis, thermodynamics, kinetics, and regeneration

  2021cites this paper
• Advanced preparation and processing techniques for high energy fuel AlH3

  2021cites this paper
• Novel core–shell structured MgH2/AlH3@CNT nanocomposites with extremely high dehydriding–rehydriding properties derived from nanoconfinement

  2021cites this paper
• Crystal Structure of a Co(II)-Coordination Polymer Based on the 4,4′-Bis(Imidazol-1-YL)-Biphenyl Ligand and Application of its Nanoparticles to Inhibit the Prostatic Cancer Cell Growth

  2020cites this paper
• STRUCTURAL INSIGHTS AND ANTI-COLON CANCER ACTIVITY OF TWO Zn(II)-BASED COORDINATION POLYMERS BASED ON CARBOXYLATE AND IMIDAZOLE CO-LIGANDS

  2020cites this paper
• RETRACTED ARTICLE: TWO MIXED-LIGAND Cu(II)-BASED COORDINATION POLYMERS: CRYSTAL STRUCTURES AND TREATMENT ACTIVITY ON CHILD ACUTE PANCREATITIS WITH PERITONITIS BY INHIBITING THE BACTERIAL SURVIVAL

  2020cites this paper
• TWO NEW Co(II)-BASED COORDINATION POLYMERS: CRYSTAL STRUCTURES AND THE LOCAL ANALGESIA ACTIVITY DUE TO REDUCING LOCAL ACETYLCHOLINE CONTENTS

  2020cites this paper
• RETRACTED ARTICLE: TWO Yb(III)-CONTAINING COORDINATION POLYMERS: STRUCTURAL INSIGHTS AND SYNERGY EFFECT WITH SEVENTY-FLAVOR PEARL PILLS ON CEREBRAL ISCHEMIA BY REGULATING MONOAMINE NEUROTRANSMITTERS

  2020cites this paper
• Synthesis of core-shell α-AlH3@Al(OH)3 nanocomposite with improved low-temperature dehydriding properties by mechanochemical mixing and ionic liquid treatment

  2020cites this paper
• Introducing Ta2O5 nanoparticles into Ca3Co4O9 matrix for increased thermoelectric property through phonon scattering

  2020cites this paper
• Enhancing the Hydrogen Storage Properties of AxBy Intermetallic Compounds by Partial Substitution: A Short Review

  2020cites this paper
• Kinetics and thermodynamics of near eutectic Mg-Mg2Ni composites produced by casting process

  2020cites this paper
• Synthesis and growth mechanism of monodispersed BiFeO3 nanorods with controllable aspect ratio and magnetic/optical properties

  2020cites this paper
• The phenomena and mechanism for the enhanced adsorption and photocatalytic decomposition of organic dyes with Ag3PO4/graphene oxide aerogel composites

  2020cites this paper
• All-solid-state BiVO4/ZnIn2S4 Z-scheme composite with efficient charge separations for improved visible light photocatalytic organics degradation

  2020cites this paper
• Efficient CO2 to CO conversion at moderate temperatures enabled by the cobalt and copper co-doped ferrite oxygen carrier

  2020cites this paper
• Construction of a Zn(II)-containing MOF for highly selective detection of picric acid and inhibition of human glioma cell growth

  2020cites this paper
• Under-oil self-driven and directional transport of water on a femtosecond laser-processed superhydrophilic geometry-gradient structure.

  2020cites this paper
• A Novel Synthesis of Fe3O4@SiO2@Au@Porous SiO2 Structure for NIR Irradiation-Induced DOX Release and Cancer Treatment

  2020cites this paper
• Two New Crystalline Nanoscale In(III)-Coordination Polymers: Crystal Structures and Glioma Cell Growth Inhibition

  2020cites this paper
• RETRACTED ARTICLE: A new Ni(II)-based coordination complex: crystal structure and anti-biofilm activity against P. gingivalis during periodontal diseases

  2020cites this paper
• Stable Ln-MOFs as multi-responsive photoluminescence sensors for the sensitive sensing of Fe3+, Cr2O72−, and nitrofuran

  2020cites this paper
• A porous Cu(II)-based metal-organic framework with one-dimensional hexagonal channels for solvent-free cyanosilylation and anti-ovarian cancer activity

  2020cites this paper
• Atomic layer deposition of Rh nanoparticles on WO3 thin film for CH4 gas sensing with enhanced detection characteristics

  2020cites this paper
• Tb(III)‐based coordination polymer for detection of Cu(II) ion and treatment effect on Alzheimer's disease by reducing inflammatory response and inflammatory cytokines release

  2020cites this paper
• RETRACTED ARTICLE: Crystal structure of a Mn(II)-based complex and application of its nanoparticles for treatment activity on peri-implantitis by reducing inflammatory responses

  2020cites this paper
• RETRACTED ARTICLE: A fluorescent Zn(II)-organic framework for selective detection of Pb2+ and a protective effect in osteoarthritis treatment by reducing ROS accumulation and apoptosis in chondrocytes

  2020cites this paper
• Atomic layer deposition of γ-Fe2O3 nanoparticles on modified MWCNT for efficient adsorption of Cr(VI) ions from aqueous solution

  2020cites this paper
• RETRACTED ARTICLE: Two Cu(II) and Co(II)-based coordination polymers based on the N,S-mixed donor ligand: structural characterization and anti-endometrial cancer activity

  2020cites this paper
• CdS nanoparticles decorated Ag2WO4 nanorods for increased photocatalytic performance and stability under visible light irradiation

  2020cites this paper
• Synthesis and post-annealing of Ag nanoparticles decorated urchin-like SrTiO3 particles for enhanced electron/hole separation and photocatalytic activity

  2020cites this paper
• Facile synthesis of F-doped g-C3N4/Bi2Fe4O9 heterostructure with Z-scheme for enhanced photocatalytic performance in NO oxidation

  2020cites this paper
• Novel Surface Modification of ZnO QDs for Paclitaxel-Targeted Drug Delivery for Lung Cancer Treatment

  2020cites this paper
• Femtosecond laser manipulating underoil surface wettability for water removal from oil

  2020cites this paper
• Self-organization behavior tuning nanophase separation morphology of sulfonated nonfluoroniated aromatic polymer membrane and its mechanism

  2020cites this paper
• Effect of partial pressure on CO2 absorption performance in piperazine promoted 2-diethylaminoethanol and 1-dimethylamino-2-propanol aqueous solutions

  2020cites this paper
• Fluorescence-sensitive adsorbent based on cellulose using for mercury detection and removal from aqueous solution with selective "on-off" response.

  2019cites this paper
• Modulating magnetic dynamics through tailoring the terminal ligands in Dy2 single-molecule magnets.

  2019cites this paper
• A Porous Ni(II)-MOF for CO2 Cycloaddition and Protective Effect on Type-II Diabetes via Reducing Cell ROS Production and Cell Apoptosis

  2019cites this paper
• RETRACTED ARTICLE: A Highly Porous Co-MOF for Cyanosilylation Reaction and Inhibition on P. gingivalis Growth and rgp and kgp Expression for Periodontal Treatment

  2019cites this paper
• Ultrafast nano-structuring of superwetting Ti foam with robust antifouling and stability towards efficient oil-in-water emulsion separation.

  2019cites this paper
• A facile synthesis of hierarchically porous Cu-BTC for efficient removal of uranium(VI)

  2019cites this paper
• The Effects of Pore Size on Electrical Performance in Lithium-Thionyl Chloride Batteries

  2019cites this paper
• Dispersing Bi2Mo2O9 nanoparticles into Bi0.5Sb1.5Te3 alloys for enhanced thermoelectric figure of merit (ZT) through phonon scattering

  2019cites this paper
• The role of Fe particle size and oxide distribution on the hydrogenation properties of ball-milled nano-crystalline powder mixtures of Fe and Mg

  2019cites this paper
• Mechanochemical synthesis of the α-AlH3/LiCl nano-composites by reaction of LiH and AlCl3: Kinetics modeling and reaction mechanism

  2019cites this paper
• Synergistic effects of binary oxygen carriers during chemical looping hydrogen production

  2019cites this paper
• Solvent-induced single-crystal-to-single-crystal transformation and tunable magnetic properties of 1D azido-Cu(ii) chains with a carboxylate bridge.

  2019cites this paper
• Comparative study of persulfate oxidants promoted photocatalytic fuel cell performance: Simultaneous dye removal and electricity generation.

  2019cites this paper
• Improved efficient queue resource reallocation strategy for traffic dynamics on scale-free networks

  2019cites this paper
• A new architecture of super-hydrophilic β-SiAlON/graphene oxide ceramic membrane for enhanced anti-fouling and separation of water/oil emulsion

  2019cites this paper